Comptes Rendus
Neutron scattering/Diffusion de neutrons
Monitoring molecular motion in nano-porous solids
Comptes Rendus. Physique, Neutron scattering: a comprehensive tool for condensed matter research, Volume 8 (2007) no. 7-8, pp. 777-788.

In this article, the important role of neutron spectroscopy techniques for the study of the dynamics of molecules hosted inside cavities at the nanometer scale is described. Three different complex systems are highlighted: alkanes with variable length inside zeolitic matrices, C60 fullerene chains inside single wall carbon nanotubes, and inert gas (N2, Xe) molecules inside water clathrates.

Cet article illustre le rôle majeur de la spectroscopie neutronique dans l'étude de la dynamique des molécules insérées dans des cavités de taille nanométrique, à travers l'étude de trois systèmes complexes : des alkanes de taille variable confinés à l'intérieur de matrices zéolitiques, des chaînes unidimensionnelles de C60 dans des nanotubes monofeuillets de carbone et des gaz inertes (N2, Xe) dans les clathrates d'eau.

Published online:
DOI: 10.1016/j.crhy.2007.07.007
Keywords: Neutron scattering, Neutron spectroscopy, Zeolites, Nanotubes, Fullerenes, Clathrates, Diffusion, Vibrations, Confinement
Mots-clés : Diffusion neutronique, Spectroscopie neutronique, Zeolites, Nanotubes, Fullerènes, Clathrates, Diffusion, Vibrations, Confinement

Stéphane Rols 1, 2; Hervé Jobic 3; Helmut Schober 1

1 Institut Laue-Langevin, 6, rue Jules-Horowitz, BP 156, 38042 Grenoble cedex 9, France
2 Laboratoire des colloïdes, verres et nanomatériaux, Université de Montpellier, 34095 Montpellier cedex 5, France
3 Institut de recherches sur la catalyse et l'environnement, 2, avenue A. Einstein, 69626 Villeurbanne, France
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Stéphane Rols; Hervé Jobic; Helmut Schober. Monitoring molecular motion in nano-porous solids. Comptes Rendus. Physique, Neutron scattering: a comprehensive tool for condensed matter research, Volume 8 (2007) no. 7-8, pp. 777-788. doi : 10.1016/j.crhy.2007.07.007. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2007.07.007/

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