Measurement of the Soret coefficients in organic/water mixtures by thermal lens spectrometry

Humberto Cabrera; Flaminio Cordido; Ana Velásquez; Pablo Moreno; Eloy Sira; Santos A. López-Rivera

doi:10.1016/j.crme.2013.01.011

Measurement of the Soret coefficients in organic/water mixtures by thermal lens spectrometry

Humberto Cabrera ^1,² ; Flaminio Cordido ¹; Ana Velásquez ¹; Pablo Moreno ¹; Eloy Sira ³; Santos A. López-Rivera ⁴

¹ Laboratorio de Óptica Aplicada, Instituto Venezolano de Investigaciones Científicas (IVIC), 5101 Mérida, Venezuela
² The Abdus Salam International Centre for Theoretical Physics, 34151 Trieste, Italy
³ Centro de Física, Instituto Venezolano de Investigaciones Científicas (IVIC), 1020-A Caracas, Venezuela
⁴ Laboratorio de Física Aplicada, Universidad de Los Andes (ULA), 5101 Mérida, Venezuela

Comptes Rendus. Mécanique, 10th International Meeting on Thermodiffusion, Volume 341 (2013) no. 4-5, pp. 372-377.

Abstract

In this work we utilize an alternative optical method based on thermal lens spectroscopy for characterizing the thermal diffusion in binary liquid mixtures. In this method, the thermal lens and the Soret signals are separated by a time interval to determine the Soret coefficients. As a demonstrative experiment, the Soret coefficients of isopropanol/water and acetone/water mixtures have been measured using that variant. Our results were compared with the recently published experimental and theoretical calculations and very good agreement was achieved.

Published online: 2013-03-07

DOI: 10.1016/j.crme.2013.01.011

Mots-clés : Thermal lens, Thermal diffusion, Soret coefficient

Author's affiliations:

Humberto Cabrera ^{1, 2}; Flaminio Cordido ¹; Ana Velásquez ¹; Pablo Moreno ¹; Eloy Sira ³; Santos A. López-Rivera ⁴

¹ Laboratorio de Óptica Aplicada, Instituto Venezolano de Investigaciones Científicas (IVIC), 5101 Mérida, Venezuela
² The Abdus Salam International Centre for Theoretical Physics, 34151 Trieste, Italy
³ Centro de Física, Instituto Venezolano de Investigaciones Científicas (IVIC), 1020-A Caracas, Venezuela
⁴ Laboratorio de Física Aplicada, Universidad de Los Andes (ULA), 5101 Mérida, Venezuela

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     author = {Humberto Cabrera and Flaminio Cordido and Ana Vel\'asquez and Pablo Moreno and Eloy Sira and Santos A. L\'opez-Rivera},
     title = {Measurement of the {Soret} coefficients in organic/water mixtures by thermal lens spectrometry},
     journal = {Comptes Rendus. M\'ecanique},
     pages = {372--377},
     publisher = {Elsevier},
     volume = {341},
     number = {4-5},
     year = {2013},
     doi = {10.1016/j.crme.2013.01.011},
     language = {en},
}

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AU  - Ana Velásquez
AU  - Pablo Moreno
AU  - Eloy Sira
AU  - Santos A. López-Rivera
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%A Flaminio Cordido
%A Ana Velásquez
%A Pablo Moreno
%A Eloy Sira
%A Santos A. López-Rivera
%T Measurement of the Soret coefficients in organic/water mixtures by thermal lens spectrometry
%J Comptes Rendus. Mécanique
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%P 372-377
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%N 4-5
%I Elsevier
%R 10.1016/j.crme.2013.01.011
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%F CRMECA_2013__341_4-5_372_0

Humberto Cabrera; Flaminio Cordido; Ana Velásquez; Pablo Moreno; Eloy Sira; Santos A. López-Rivera. Measurement of the Soret coefficients in organic/water mixtures by thermal lens spectrometry. Comptes Rendus. Mécanique, 10th International Meeting on Thermodiffusion, Volume 341 (2013) no. 4-5, pp. 372-377. doi : 10.1016/j.crme.2013.01.011. https://comptes-rendus.academie-sciences.fr/mecanique/articles/10.1016/j.crme.2013.01.011/

References
Cited by

[1] C. Soret Arch. Sci. Phys. Nat., 2 (1879), p. 48

[2] L. Sitzber Akad. Wiss. Wien Math.-Naturwiss. Kl., 20 (1856), p. 539

[3] S.B. Bierlein A phenomenological theory of the Soret diffusion, J. Chem. Phys., Volume 23 (1955), pp. 10-15

[4] H. Tyrell Diffusion and Heat Flow in Liquids, Butterworths, London, 1961

[5] M. Giglio; A. Vendramini Appl. Phys. Lett., 25 (1974), p. 555

[6] J. Whinnery Acc. Chem. Res., 7 (1974), p. 225

[7] M. Long; R. Swofford; A. Albrecht Science, 191 (1976), p. 183

[8] J. Shen; R. Lowe; R. Snook Chem. Phys., 165 (1992), p. 385

[9] A. Marcano; H. Cabrera; M. Guerra; R.A. Cruz; C. Jacinto; T. Catunda J. Opt. Soc. Am. B, 23 (2006), p. 1408

[10] H. Cabrera; A. Marcano; Y. Castellanos Cond. Matt. Phys., 9 (2006), p. 385

[11] J. Gordon; R. Leite; R. Moore; S. Porto; J. Whinnery J. Appl. Phys., 36 (1965), p. 3

[12] N. Arnaud; J. Georges Spectrochim. Acta A, 57 (2001), p. 1295

[13] H. Cabrera; E. Sira; K. Rahn; M. García-Sucre Appl. Phys. Lett., 94 (2009), p. 051103

[14] H. Cabrera; L. Marti-López; E. Sira; K. Rahn; M. García-Sucre J. Chem. Phys., 131 (2009), p. 031106

[15] P. Polyakov; S. Wiegand Phys. Chem. Chem. Phys., 11 (2009), p. 864

[16] A. Mialdun; V. Yasnou; V.M. Shetsova; A. Königer; W. Köhler; D. Alonso de Mezquia; M.M. Bou-Ali J. Chem. Phys., 136 (2012), p. 244512

[17] N. Arnaud; J. Georges Spectrochim. Acta A, 60 (2004), p. 1817

[18] N. Arnaud; J. Georges Spectrochim. Acta A, 69 (2008), p. 1063

[19] A. Mialdun; V.M. Shetsova Int. J. Heat Mass Transf., 51 (2008), p. 3164

[20] P. Poty; J.C. Legros; G. Thomaes Z. Naturforsch., 29A (1974), p. 1915

[21] A. Abbasi; M.Z. Saghir; M. Kawaji J. Chem. Phys., 130 (2009), p. 064506

[22] H. Ning; S. Wiegand J. Chem. Phys., 125 (2006), p. 221102

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