Comptes Rendus
Mutual diffusion coefficients in systems containing the nickel ion
Comptes Rendus. Mécanique, Volume 341 (2013) no. 4-5, pp. 417-420.

Mutual diffusion coefficients of nickel chloride in water have been measured at 293.15 K and 303.15 K and at concentrations between 0.020 mol dm−3 and 0.100 mol dm−3, using a conductimetric cell. The experimental mutual diffusion coefficients are discussed on the basis of the Onsager–Fuoss model. The equivalent conductances at infinitesimal concentration of the nickel ion in these solutions at those temperatures have been estimated using these results.

In addition, from these data, we have estimated some transport and structural parameters, such as limiting diffusion coefficient, ionic conductance at infinitesimal concentration, hydrodynamic radii and activation energy, contributing this way to a better understanding of the structure of these systems and of their thermodynamic behavior in aqueous solution at different concentrations.

Published online:
DOI: 10.1016/j.crme.2013.01.017
Keywords: Diffusion, Electrolytes, Nickel chloride solutions, Transport properties

Ana C.F. Ribeiro 1; Luis V.M.M. Veríssimo 1; Joselaine C.S. Gomes 1; Cecilia I.A.V. Santos 1; Marisa C.F. Barros 1; Victor M.M. Lobo 1; Abílio J.F.N. Sobral 1; Miguel A. Esteso 2; Derek G. Leaist 3

1 Department of Chemistry, University of Coimbra, 3004, 535 Coimbra, Portugal
2 Departamento de Química Física, Facultad de Farmacia, Universidad de Alcalá 28871, Alcalá de Henares, Madrid, Spain
3 Department of Chemistry, St. Francis Xavier University, Antigonish, Nova Scotia, B2G 2W5 Canada
@article{CRMECA_2013__341_4-5_417_0,
     author = {Ana C.F. Ribeiro and Luis V.M.M. Ver{\'\i}ssimo and Joselaine C.S. Gomes and Cecilia I.A.V. Santos and Marisa C.F. Barros and Victor M.M. Lobo and Ab{\'\i}lio J.F.N. Sobral and Miguel A. Esteso and Derek G. Leaist},
     title = {Mutual diffusion coefficients in systems containing the nickel ion},
     journal = {Comptes Rendus. M\'ecanique},
     pages = {417--420},
     publisher = {Elsevier},
     volume = {341},
     number = {4-5},
     year = {2013},
     doi = {10.1016/j.crme.2013.01.017},
     language = {en},
}
TY  - JOUR
AU  - Ana C.F. Ribeiro
AU  - Luis V.M.M. Veríssimo
AU  - Joselaine C.S. Gomes
AU  - Cecilia I.A.V. Santos
AU  - Marisa C.F. Barros
AU  - Victor M.M. Lobo
AU  - Abílio J.F.N. Sobral
AU  - Miguel A. Esteso
AU  - Derek G. Leaist
TI  - Mutual diffusion coefficients in systems containing the nickel ion
JO  - Comptes Rendus. Mécanique
PY  - 2013
SP  - 417
EP  - 420
VL  - 341
IS  - 4-5
PB  - Elsevier
DO  - 10.1016/j.crme.2013.01.017
LA  - en
ID  - CRMECA_2013__341_4-5_417_0
ER  - 
%0 Journal Article
%A Ana C.F. Ribeiro
%A Luis V.M.M. Veríssimo
%A Joselaine C.S. Gomes
%A Cecilia I.A.V. Santos
%A Marisa C.F. Barros
%A Victor M.M. Lobo
%A Abílio J.F.N. Sobral
%A Miguel A. Esteso
%A Derek G. Leaist
%T Mutual diffusion coefficients in systems containing the nickel ion
%J Comptes Rendus. Mécanique
%D 2013
%P 417-420
%V 341
%N 4-5
%I Elsevier
%R 10.1016/j.crme.2013.01.017
%G en
%F CRMECA_2013__341_4-5_417_0
Ana C.F. Ribeiro; Luis V.M.M. Veríssimo; Joselaine C.S. Gomes; Cecilia I.A.V. Santos; Marisa C.F. Barros; Victor M.M. Lobo; Abílio J.F.N. Sobral; Miguel A. Esteso; Derek G. Leaist. Mutual diffusion coefficients in systems containing the nickel ion. Comptes Rendus. Mécanique, Volume 341 (2013) no. 4-5, pp. 417-420. doi : 10.1016/j.crme.2013.01.017. https://comptes-rendus.academie-sciences.fr/mecanique/articles/10.1016/j.crme.2013.01.017/

[1] H.J.V. Tyrrell; K.R. Harris Diffusion in Liquids, Butterworths, London, 1984

[2] A.C.F. Ribeiro; V.M.M. Lobo; A.J.M. Valente; A.M.T.D.P.V. Cabral; F.J.B. Veiga; S.I.G. Fangaia; P.M.G. Nicolau; F.A.D.R.A. Guerra; M.A. Esteso Transport properties and their impact on biological systems (J.C. Taylor, ed.), Advances in Chemistry Research, vol. 10, Nova Science Publishers, New York, 2011

[3] A.C.F. Ribeiro; J.C.S. Gomes; M.C.F. Barros; V.M.M. Lobo; M.A. Esteso Diffusion coefficients of nickel chloride in aqueous solutions of lactose at 298.15 K and 310.15 K, J. Chem. Thermodyn., Volume 43 (2011), pp. 270-274

[4] A.C.F. Ribeiro; J.C.S. Gomes; M.B.B.J. Rita; V.M.M. Lobo; M.A. Esteso Ternary diffusion coefficients of nickel chloride plus theophylline plus water at 298.15 K, Food Chem., Volume 128 (2011), pp. 957-960

[5] A.C.F. Ribeiro; J.C.S. Gomes; C.I.A.V. Santos; V.M.M. Lobo; M.A. Esteso; D.G. Leaist Ternary mutual diffusion coefficients of aqueous NiCl2 + NaCl and NiCl2 + HCl solutions at 298.15 K, J. Chem. Eng. Data, Volume 56 (2011), pp. 4696-4699

[6] V.M.M. Lobo; A.C.F. Ribeiro; L.M.P. Veríssimo Diffusion coefficients in aqueous solutions of beryllium sulphate at 298 K, J. Chem. Eng. Data, Volume 39 (1994), pp. 726-728

[7] V.M.M. Lobo; A.C.F. Ribeiro; L.M.P. Veríssimo Diffusion coefficients in aqueous solutions of magnesium nitrate, Ber. Bunsenges. Phys. Chem., Volume 98 (1994), pp. 205-208

[8] A.C.F. Ribeiro; V.M.M. Lobo; J.J.S. Natividade Diffusion coefficients in aqueous solutions of cobalt chloride at 298.15 K, J. Chem. Eng. Data, Volume 47 (2002), pp. 539-541

[9] A.C.F. Ribeiro; V.M.M. Lobo; L.R.C. Oliveira; H.D. Burrows; E.F.G. Azevedo; S.I.G. Fangaia; P.M.G. Nicolau; F.A.D.R.A. Guerra Diffusion coefficients of chromium chloride in aqueous solutions at 298.15 and 303.15 K, J. Chem. Eng. Data, Volume 50 (2005), pp. 1014-1017

[10] A.C.F. Ribeiro; M.A. Esteso; V.M.M. Lobo; A.J.M. Valente; S.M.N. Simões; A.J.F.N. Sobral; H.D. Burrows Diffusion coefficients of copper chloride in aqueous solutions at 298.15 K and 310.15 K, J. Chem. Eng. Data, Volume 50 (2005), pp. 1986-1990

[11] R.A. Robinson; R.H. Stokes Electrolyte Solutions, Butterworths, London, 1959

[12] H.S. Harned; B.B. Owen The Physical Chemistry of Electrolytic Solutions, Reinhold Pub. Corp., New York, 1964

[13] D. Dobos Electrochemical Data. A Handbook for Electrochemists in Industry and Universities, Elsevier, New York, 1975

[14] T. Erdey-Grúz Transport Phenomena in Aqueous Solutions, Adam Hilger, London, 1974

[15] CRC Handbook of Chemistry and Physics (D.R. Lide, ed.), CRC Press, Boca Raton, FL, 1983

Cited by Sources:

Comments - Policy