Comptes Rendus
no. 5
Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes
Semen N. Semenov1  ; Martin E. Schimpf2
1 Institute of Biochemical Physics RAS, Kosygin Street 4, 117977 Moscow, Russia
2 Department of Chemistry, Boise State University, Boise, ID 83725, USA
Comptes Rendus. Mécanique, Volume 339 (2011) no. 5, pp. 280-286.

A thermodynamic theory is developed for the thermophoresis of dilute suspensions of charged colloid particles in electrolyte solutions. The calculation of relevant thermodynamic parameters using statistical mechanics is carried out in the Debye–Hueckel approximation. The main experimental features observed for such systems are explained.

Publié le :
DOI : 10.1016/j.crme.2011.03.002
Mots clés : Non-equilibrium thermodynamics, Colloid particles, Electrolyte solution, Thermodiffusion
Semen N. Semenov 1 ; Martin E. Schimpf 2

1 Institute of Biochemical Physics RAS, Kosygin Street 4, 117977 Moscow, Russia
2 Department of Chemistry, Boise State University, Boise, ID 83725, USA 
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Semen N. Semenov; Martin E. Schimpf. Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes. Comptes Rendus. Mécanique, Volume 339 (2011) no. 5, pp. 280-286. doi : 10.1016/j.crme.2011.03.002. https://comptes-rendus.academie-sciences.fr/mecanique/articles/10.1016/j.crme.2011.03.002/

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