Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes

Semen N. Semenov; Martin E. Schimpf

doi:10.1016/j.crme.2011.03.002

Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes

Semen N. Semenov ¹ ; Martin E. Schimpf ²

¹ Institute of Biochemical Physics RAS, Kosygin Street 4, 117977 Moscow, Russia
² Department of Chemistry, Boise State University, Boise, ID 83725, USA

Comptes Rendus. Mécanique, Thermodiffusion and coupled phenomena, Volume 339 (2011) no. 5, pp. 280-286.

Abstract

A thermodynamic theory is developed for the thermophoresis of dilute suspensions of charged colloid particles in electrolyte solutions. The calculation of relevant thermodynamic parameters using statistical mechanics is carried out in the Debye–Hueckel approximation. The main experimental features observed for such systems are explained.

Published online: 2011-04-19

DOI: 10.1016/j.crme.2011.03.002

Keywords: Non-equilibrium thermodynamics, Colloid particles, Electrolyte solution, Thermodiffusion

Author's affiliations:

Semen N. Semenov ¹; Martin E. Schimpf ²

¹ Institute of Biochemical Physics RAS, Kosygin Street 4, 117977 Moscow, Russia
² Department of Chemistry, Boise State University, Boise, ID 83725, USA

@article{CRMECA_2011__339_5_280_0,
     author = {Semen N. Semenov and Martin E. Schimpf},
     title = {Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes},
     journal = {Comptes Rendus. M\'ecanique},
     pages = {280--286},
     publisher = {Elsevier},
     volume = {339},
     number = {5},
     year = {2011},
     doi = {10.1016/j.crme.2011.03.002},
     language = {en},
}

TY  - JOUR
AU  - Semen N. Semenov
AU  - Martin E. Schimpf
TI  - Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes
JO  - Comptes Rendus. Mécanique
PY  - 2011
SP  - 280
EP  - 286
VL  - 339
IS  - 5
PB  - Elsevier
DO  - 10.1016/j.crme.2011.03.002
LA  - en
ID  - CRMECA_2011__339_5_280_0
ER  -

%0 Journal Article
%A Semen N. Semenov
%A Martin E. Schimpf
%T Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes
%J Comptes Rendus. Mécanique
%D 2011
%P 280-286
%V 339
%N 5
%I Elsevier
%R 10.1016/j.crme.2011.03.002
%G en
%F CRMECA_2011__339_5_280_0

Semen N. Semenov; Martin E. Schimpf. Thermodynamics of mass transport in diluted suspensions of charged particles in non-isothermal liquid electrolytes. Comptes Rendus. Mécanique, Thermodiffusion and coupled phenomena, Volume 339 (2011) no. 5, pp. 280-286. doi : 10.1016/j.crme.2011.03.002. https://comptes-rendus.academie-sciences.fr/mecanique/articles/10.1016/j.crme.2011.03.002/

References
Cited by

[1] S.R. De Groot Thermodynamics of Irreversible Processes, North-Holland Publishing Company, Amsterdam, 1952

[2] S.R. De Groot; P. Mazur Non-Equilibrium Thermodynamics, North-Holland, Amsterdam, 1962

[3] D. Kondepudi; I. Prigogine Modern Thermodynamics, Wiley, New York, 1999

[4] K. Ghoraeb; A. Firoozabadi Molecular, pressure and thermal diffusion in nonideal multicomponent mixtures, AIChE, Volume 46 (2000), p. 883

[5] S. Pan; M.Z. Sahgir; M. Kawaji; C.G. Jiang; Y. Yan Theoretical approach to evaluate thermodiffusion in aqueous alkanol solutions, J. Chem. Phys., Volume 126 (2007), p. 014502

[6] S.N. Semenov; M.E. Schimpf Mass transport thermodynamics in nonisothermal molecular liquid mixtures, Physics – Uspekhi, Volume 52 (2009), p. 1045

[7] L.D. Landau; E.M. Lifshitz Statistical Physics, Part 1, Pergamon Press, 1980 (English translation, E.M. Lifshitz, L.P. Pitaevskii)

[8] V.G. Levich Introduction Into Statistical Physics, Gostechizdat, Moscow, 1954 (in Russian)

[9] S.N. Semenov Statistical thermodynamic expression for the Soret coefficient, EPL, Volume 90 (2010), p. 56002

[10] A. Parola; R. Piazza Particle thermophoresis in liquids, Eur. Phys. J., Volume 15 (2004), p. 255

[11] J.K.G. Dhont Thermodiffusion of interacting colloids. I. A statistical thermodynamics approach, J. Chem. Phys., Volume 120 (2004), p. 1632

[12] I.Z. Fisher Statistical Theory of Liquids, Chicago Univ., 1964

[13] R.J. Hunter Foundations of Colloid Science, vol. 2, Clarendon, London, 1992

[14] S. Ross; I.D. Morrison Colloidal Systems and Interfaces, Wiley, New York, 1988

[15] E. Ruckenstein Can phoretic motions be treated as interfacial tension gradient driven phenomena?, J. Coll. Interf. Sci., Volume 83 (1981), p. 77

[16] J.L. Anderson Colloid transport by interfacial forces, Annu. Rev. Fluid Mech., Volume 21 (1989), p. 61

[17] S.N. Semenov; M.E. Schimpf Thermophoresis of dissolved molecules and polymers: consideration of the temperature-induced macroscopic pressure gradient, Phys. Rev. E, Volume 69 (2004), p. 011201

[18] J.C. Giddings; P.M. Shiundu; S.N. Semenov Thermophoresis of metal particles in a liquid, J. Coll. Interf. Sci., Volume 176 (1995), p. 454

Cited by Sources:

Comments - Policy