Comptes Rendus
no. 3
Agrégats comme précurseurs des nano-objets/Clusters as precursors of nano-objects
The amazing phases of small systems
[Les phases surprenantes des petits systèmes]
R. Berry1
1 The University of Chicago, Department of Chemistry, Chicago, IL 60637, USA
Comptes Rendus. Physique, Volume 3 (2002) no. 3, pp. 319-326.

Small systems, notably clusters of tens or hundreds of atoms or molecules, exhibit forms almost precisely analogous to the phases of bulk systems. However their small sizes make these systems behave in ways quite different from their bulk counterparts. These differences can be elucidated and related to the behavior of bulk systems. Understanding these relationships gives us new insights into the traditional, classical bulk phase transitions, and shows us some unique properties of phases and phase equilibrium of nanoscale systems.

Les petits systèmes, et plus particulièrement les agrégats de quelques dizaines ou de quelques centaines d'atomes ou de molécules, présentent des formes sensiblement proches des celles que l'on rencontrent dans les systèmes macroscopiques. Cependant leur petite taille confèrent à ces systèmes des comportements tout à fait différents de ceux du solide massif correspondant. Ces différences peuvent être comprises et reliées au comportement de ce solide. La compréhension de ces liens donne un nouvel éclairage sur les traditionnelles transitions de phase dans les solides et montre bien les propriétés uniques des phases et de l'équilibre entre phases dans ces systèmes nanoscopiques.

Reçu le :
Accepté le :
Publié le :
DOI : 10.1016/S1631-0705(02)01324-5
Keywords: nanoscale systems, phase equilibrium
Mots-clés : systm̀es nanoscopiques, équilibre entre phases

R. Berry 1

1 The University of Chicago, Department of Chemistry, Chicago, IL 60637, USA 
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R. Berry. The amazing phases of small systems. Comptes Rendus. Physique, Volume 3 (2002) no. 3, pp. 319-326. doi : 10.1016/S1631-0705(02)01324-5. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/S1631-0705(02)01324-5/

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