Organic nanocrystals grown in sol–gel matrices: a new type of hybrid material for optics

Julien Zaccaro; Nathalie Sanz; Estelle Botzung Appert; Patrice L. Baldeck; Alain Ibanez

doi:10.1016/S1631-0705(02)01330-0

Photonique moleculaire : matériaux, physique et composants/Molecular photonics: materials, physics and devices

Organic nanocrystals grown in sol–gel matrices: a new type of hybrid material for optics
[Nucléation et croissance confinée de nanocristaux organiques en matrices sol–gel : un nouveau type de matériaux organo-minéraux pour l'optique]

Julien Zaccaro ¹ ; Nathalie Sanz ¹ ; Estelle Botzung Appert ¹ ; Patrice L. Baldeck ² ; Alain Ibanez ¹

¹ Laboratoire de cristallographie, CNRS, UPR 5031 associée à l'Université J. Fourier et à l'INPG, BP 166, 38042 Grenoble cedex 9, France
² Laboratoire de spectrométrie physique, Université Joseph Fourier, CNRS (UMR 5588), BP 87, 38402 Saint Martin d'Hères cedex, France

Comptes Rendus. Physique, Volume 3 (2002) no. 4, pp. 463-478.

Résumé
Abstract

Nous avons développé une élaboration simple et générique de nouveaux matériaux hybrides organo-minéraux constitués de nanocristaux organiques inclus dans des matrices sol–gel. Ce procédé est basé sur le contrôle de la nucléation et de la croissance confinée de phases organiques dans les pores de gels denses. Pour les xérogels massifs, nous avons obtenu des distributions de taille de nanocristaux étroites (10–20 nm). Nous avons étendu cette méthode à l'élaboration de couches minces par spin-coating. Dans tous ces matériaux nanocomposites, nous avons stabilisé les phases organiques cristallisées et obtenus des propriétés optiques linéaires et non-linéaires prometteuses.

We have engineered new hybrid organic–inorganic materials through a simple and generic preparation of stable organic nanocrystals grown in gel–glass matrices. This process is based on the confined nucleation and growth of dyes in the pores of dense gels. For bulk samples, narrow size distributions of particles are obtained between 10 and 20 nm in diameter. We have extended this method to the preparation of organic nanocrystals embedded in sol–gel thin films by spin-coating. For all these nanocomposite samples, we have significantly increased the stability of the dye and obtained promising linear and nonlinear optical properties.

Accepté le : 2002-03-01
Publié le : 2002-01-01

DOI : 10.1016/S1631-0705(02)01330-0

Keywords: confined nucleation and growth, hybrid (organic–inorganic) materials, organic nanocrystals, sol–gel, optics
Mot clés : nucléation et croissance confinées, matériaux hybrides organo-minéraux, nanocristaux organiques, sol–gel, optique

Affiliations des auteurs :

Julien Zaccaro ¹ ; Nathalie Sanz ¹ ; Estelle Botzung Appert ¹ ; Patrice L. Baldeck ² ; Alain Ibanez ¹

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     author = {Julien Zaccaro and Nathalie Sanz and Estelle~Botzung Appert and Patrice L. Baldeck and Alain Ibanez},
     title = {Organic nanocrystals grown in sol{\textendash}gel matrices: a~new type of hybrid material for optics},
     journal = {Comptes Rendus. Physique},
     pages = {463--478},
     publisher = {Elsevier},
     volume = {3},
     number = {4},
     year = {2002},
     doi = {10.1016/S1631-0705(02)01330-0},
     language = {en},
}

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Julien Zaccaro; Nathalie Sanz; Estelle Botzung Appert; Patrice L. Baldeck; Alain Ibanez. Organic nanocrystals grown in sol–gel matrices: a new type of hybrid material for optics. Comptes Rendus. Physique, Volume 3 (2002) no. 4, pp. 463-478. doi : 10.1016/S1631-0705(02)01330-0. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/S1631-0705(02)01330-0/

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