Organic thin film crystal growth for nonlinear optics: present methods and exploratory developments

Sabine Manetta; Marcel Ehrensperger; Christian Bosshard; Peter Günter

doi:10.1016/S1631-0705(02)01338-5

Photonique moleculaire : matériaux, physique et composants/Molecular photonics: materials, physics and devices

Organic thin film crystal growth for nonlinear optics: present methods and exploratory developments

Sabine Manetta ¹ ; Marcel Ehrensperger ¹ ; Christian Bosshard ^1,² ; Peter Günter ¹

¹ Nonlinear Optics Laboratory, Institute of Quantum Electronics, ETH Hönggerberg, CH-8093 Zürich, Switzerland
² CSEM Alpnach, Untere Gründlistrasse 1, CH-6055 Alpnach Dorf, Switzerland

Comptes Rendus. Physique, Volume 3 (2002) no. 4, pp. 449-462.

Résumé

We discuss different methods to grow organic single crystalline thin films from solution. Specifically, we address exploratory developments and apply them on the highly nonlinear material DAST (4′-dimethylamino-N-methyl-4-stilbazolium tosylate) in a DAST/methanol system. We describe the nucleation and growth thermodynamics in solution using a solubility diagram and its Ostwald–Meiers metastable region. The important experimental parameters for bidimensional growth are discussed and first promising results are presented.

Accepté le : 2002-03-01
Publié le : 2002-01-01

DOI : 10.1016/S1631-0705(02)01338-5

Mots-clés : organic single crystals, thin film, growth methods, DAST

Affiliations des auteurs :

Sabine Manetta ¹ ; Marcel Ehrensperger ¹ ; Christian Bosshard ^{1, 2} ; Peter Günter ¹

¹ Nonlinear Optics Laboratory, Institute of Quantum Electronics, ETH Hönggerberg, CH-8093 Zürich, Switzerland
² CSEM Alpnach, Untere Gründlistrasse 1, CH-6055 Alpnach Dorf, Switzerland

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     author = {Sabine Manetta and Marcel Ehrensperger and Christian Bosshard and Peter G\"unter},
     title = {Organic thin film crystal growth for nonlinear optics: present methods and exploratory developments},
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     pages = {449--462},
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     number = {4},
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     doi = {10.1016/S1631-0705(02)01338-5},
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Sabine Manetta; Marcel Ehrensperger; Christian Bosshard; Peter Günter. Organic thin film crystal growth for nonlinear optics: present methods and exploratory developments. Comptes Rendus. Physique, Volume 3 (2002) no. 4, pp. 449-462. doi : 10.1016/S1631-0705(02)01338-5. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/S1631-0705(02)01338-5/

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