Comptes Rendus
no. 7
Physique/Solides, fluides : structure
Frittage du phosphate tricalcique

Présenté par : Jacques Villain

Foued Ben Ayed1, 2  ; Kamel Chaari1 ; Jamel Bouaziz1 ; Khaled Bouzouita3
1 Laboratoire de chimie industrielle, École nationale d'ingénieurs de Sfax, BP W, 3038 Sfax, Tunisie
2 Institut préparatoire aux études d'ingénieurs de Sfax, BP 805, 3018 Sfax, Tunisie
3 Unité de chimie inorganique, faculté des sciences de Monastir, Tunisie
Comptes Rendus. Physique, Towards reconfigurable and cognitive communications, Volume 7 (2006) no. 7, pp. 825-835.

Ce travail aborde l'étude du frittage du β phosphate tricalcique obtenu par voie sèche, en vue d'élaborer des matériaux denses. L'évolution de la densité du matériau fritté en fonction du temps et de la température, a été suivie. Le phosphate tricalcique présente une bonne aptitude au frittage dans le domaine de température 1200–1350 °C, ainsi des taux de densification de 92% ont pu être atteints à 1300 °C. A des températures supérieures à 1350 °C, la densification est entravée par le grossissement exagéré des grains et la formation de larges pores. La diffraction des rayons X montre en plus du β phosphate tricalcique, la présence de traces de la phase α du phosphate tricalcique et du phosphate tétracalcique. L'analyse par résonance magnétique nucléaire du solide 31P illustre la présence de trois types de site tétraédrique. L'analyse thermique différentielle montre que les deux transformations allotropiques du phosphate tricalcique se produisent respectivement à 1285 et 1475 °C.

This article investigates the sintering of β tricalcium phosphate obtained by solid state reaction, for elaboration of dense materials. The evolution of the sintered material density as a function to time and temperature has been followed. The tricalcium phosphate presents a good sinterability in the range 1200–1350 °C. Thus, a densification rate of about 92% was reached at 1300 °C. At temperature higher than 1350 °C, the densification was hindered by the grain growth and the formation of large pore. X-ray diffraction showed besides the β tricalcium phosphate, the presence of α phase traces of tricalcium phosphate and the tetracalcium phosphate. The analysis by nuclear magnetic resonance of the solid 31P illustrates the presence of three types of tetrahedral site. Differentially thermal analyse shows that two phase changes of the tricalcium phosphate occurred at 1285 and 1475 °C, respectively.

Reçu le :
Accepté le :
Publié le :
DOI : 10.1016/j.crhy.2006.07.012
Mots-clés : Phosphate tricalcique, Frittage, Microstructure, Densification, Transformation allotropique, Résonance magnétique nucléaire du solide 31P
Keywords: Tricalcium phosphate, Sintering, Microstructure, Densification, Allotropic transformation, Nuclear magnetic resonance of solid 31P

Foued Ben Ayed 1, 2 ; Kamel Chaari 1 ; Jamel Bouaziz 1 ; Khaled Bouzouita 3

1 Laboratoire de chimie industrielle, École nationale d'ingénieurs de Sfax, BP W, 3038 Sfax, Tunisie
2 Institut préparatoire aux études d'ingénieurs de Sfax, BP 805, 3018 Sfax, Tunisie
3 Unité de chimie inorganique, faculté des sciences de Monastir, Tunisie 
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Foued Ben Ayed; Kamel Chaari; Jamel Bouaziz; Khaled Bouzouita. Frittage du phosphate tricalcique. Comptes Rendus. Physique, Towards reconfigurable and cognitive communications, Volume 7 (2006) no. 7, pp. 825-835. doi : 10.1016/j.crhy.2006.07.012. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2006.07.012/

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