Comptes Rendus
Physical colors in cultural heritage: Surface plasmons in glass
[Couleurs physiques et patrimoine culturel : Plasmons de surface dans les verres]
Comptes Rendus. Physique, Physics and heritage, Volume 10 (2009) no. 7, pp. 649-659.

Le verre rubis et les céramiques lustrées sont pratiquement les seuls exemples de couleurs physiques dans le patrimoine culturel. L'effet physique principal à l'origine de leur couleur est l'excitation de modes de plasmons de surface dans des nanoparticules métalliques. Dans les lustres, les interférences dues à une stucture multicouche complexe viennent ajouter un brillant effet d'iridescence. Nous rappelons en détail le principe des plasmons et l'illustrons par le verre rubis. Les céramiques lustrées sont étudiées plus en détail du fait de la complexité des phénomènes impliqués : plasmon, diffusion, interférence entre faisceaux lumineux réfléchis spéculairement, mais aussi entre faisceaux diffusés.

Gold ruby glass and lustre ceramics are the almost unique examples of physical colors in the cultural heritage. The main physical effect at the origin of their color is the excitation of surface plasmon modes in metal nanoparticles. Moreover, in lustre, interference effects due a multilayer structure add a bright iridescence. The principle of plasmons is recalled in detail and applied to Gold ruby glass. The case of luster ceramics is treated in more detail due to the complexity of the effects involved: plasmon, scattering, interference between specular reflected light beams and also between scattered beams.

Publié le :
DOI : 10.1016/j.crhy.2009.08.004
Keywords: Physical color, Surface plasmon, Interference, Scattering, Ruby glass, Luster ceramic, Cultural heritage
Mots-clés : Couleur physique, Plasmon de surface, Interférence, Diffusion, Verre rubis, Céramique lustrée, Patrimoine culturel

Jacques Lafait 1 ; Serge Berthier 1 ; Christine Andraud 1 ; Vincent Reillon 1 ; Julie Boulenguez 1

1 Institut des nanosciences de Paris, UMR 7588 CNRS – Université Pierre-et-Marie-Curie, Paris 6, Campus Boucicaut, 140, rue de Lourmel, 75015 Paris, France
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Jacques Lafait; Serge Berthier; Christine Andraud; Vincent Reillon; Julie Boulenguez. Physical colors in cultural heritage: Surface plasmons in glass. Comptes Rendus. Physique, Physics and heritage, Volume 10 (2009) no. 7, pp. 649-659. doi : 10.1016/j.crhy.2009.08.004. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2009.08.004/

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