Superconductivity in transuranium elements and compounds

Jean-Christophe Griveau; Éric Colineau

doi:10.1016/j.crhy.2014.07.001

Superconductivity in transuranium elements and compounds

Jean-Christophe Griveau ¹ ; Éric Colineau ¹

¹ European Commission, Joint Research Centre (JRC), Institute for Transuranium Elements (ITU), Actinide Research Unit, Postfach 2340, 76125 Karlsruhe, Germany

Comptes Rendus. Physique, Emergent phenomena in actinides, Volume 15 (2014) no. 7, pp. 599-615.

Abstract
Résumé

We present here an overview of the properties of transuranium superconductors, but also of the (non-superconducting) transuranium analogues of uranium superconductors. We briefly review superconductivity in actinide elements and uranium compounds and focus in particular on the ${PuTX}_{5}$ ( $T = Co, Rh$ ; $X = Ga, In$ ) series, the largest superconducting system in actinides and ${NpPd}_{5} {Al}_{2}$ , the so far unique neptunium superconductor. The effects of chemical substitution, ageing and pressure on the properties of transuranium superconductors are also discussed.

Nous présentons ici un aperçu des propriétés des supraconducteurs transuraniens, mais aussi des analogues transuraniens (non supraconducteurs) des supraconducteurs à base d'uranium. Nous examinons brièvement la supraconductivité dans les éléments d'actinides et les composés d'uranium, puis nous présentons en particulier la famille des composés ${PuTX}_{5}$ ( $T = Co, Rh$ , $X = Ga, In$ ), la série la plus étendue de supraconducteurs parmi les actinides ainsi que ${NpPd}_{5} {Al}_{2}$ , le seul supraconducteur au neptunium connu à ce jour. Les effets de la substitution chimique, du vieillissement et de la pression sur les propriétés des supraconducteurs transuraniens sont également discutés.

Published online: 2014-07-24

DOI: 10.1016/j.crhy.2014.07.001

Keywords: Transuranium, Superconductivity, Non-conventional superconductors
Mots-clés : Transuraniens, Supraconductivité

Author's affiliations:

Jean-Christophe Griveau ¹; Éric Colineau ¹

¹ European Commission, Joint Research Centre (JRC), Institute for Transuranium Elements (ITU), Actinide Research Unit, Postfach 2340, 76125 Karlsruhe, Germany

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Jean-Christophe Griveau; Éric Colineau. Superconductivity in transuranium elements and compounds. Comptes Rendus. Physique, Emergent phenomena in actinides, Volume 15 (2014) no. 7, pp. 599-615. doi : 10.1016/j.crhy.2014.07.001. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2014.07.001/

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