Comptes Rendus
no. 7-8
Science in the making 2: From 1940 to the early 1980s / La science en mouvement 2 : de 1940 aux premières années 1980
Dynamic nuclear polarization
[Polarisation dynamique nucléaire]
Maurice Goldman1
1 Académie des sciences, 23, quai de Conti, 75006 Paris, France
Comptes Rendus. Physique, Volume 20 (2019) no. 7-8, pp. 694-705.

La polarisation nucléaire dynamique (en anglais DNP) se réfère à l'augmentation de la polarisation de spins nucléaires dans la matière condensée, liquide ou solide, couplés à des spins électroniques à faible concentration relative, en induisant des transitions radio ou micro-ondes de fréquence proche d'une fréquence de résonance électronique dans un champ magnétique extérieur. Une autre méthode décrite consiste en l'utilisation indirecte du pompage optique à température proche de la température ordinaire pour la polarisation nucléaire de gaz rares. Les divers mécanismes de polarisation sont décrits en termes physiques. Ceci est suivi d'une description succincte des principales applications de la DNP dans différents domaines de la physique, de la chimie et de la médecine.

Dynamic nuclear polarization, or DNP, refers to the increase of the polarization of nuclear spins in condensed matter, liquid or solid, coupled with electronic spins at low relative concentration, by inducing radio or microwave transitions at frequencies close to the electronic resonance frequency in the external magnetic field. Another described method relies on indirect optical pumping methods at temperatures close to room temperature for the nuclear polarization of rare gases. The various mechanisms of DNP are described in physical terms. This is followed by a succinct description of its main applications in various domains of physics, in chemistry and in medicine.

Publié le :
DOI : 10.1016/j.crhy.2019.05.010
Keywords: DNP, Liquids, Solids, Gases, Applications
Mot clés : DNP, Liquides, Solides, Gaz, Applications
Maurice Goldman 1

1 Académie des sciences, 23, quai de Conti, 75006 Paris, France 
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Maurice Goldman. Dynamic nuclear polarization. Comptes Rendus. Physique, Volume 20 (2019) no. 7-8, pp. 694-705. doi : 10.1016/j.crhy.2019.05.010. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2019.05.010/

[1] A. Abragam The Principles of Nuclear Magnetism, Oxford University Press, Oxford, UK, 1961

[2] C.P. Slichter Principles of Magnetic Resonance, Springer-Verlag, Berlin, 1990

[3] M. Goldman Spin Temperature and Nuclear Magnetic Resonance in Solids, Oxford University Press, Oxford, UK, 1970

[4] M. Goldman Quantum Description of High-Resolution NMR in Liquids, Oxford University Press, Oxford, UK, 1988

[5] R.V. Pound Phys. Rev., 81 (1951), p. 156

[6] E.M. Purcell; R.V. Pound Phys. Rev., 81 (1951), p. 279

[7] A. Abragam; W.G. Proctor Phys. Rev., 109 (1958), p. 1441

[8] A.G. Redfield Phys. Rev., 98 (1955), p. 1787

[9] A.W. Overhauser Phys. Rev., 92 (1953), p. 411

[10] T.R. Carver; C.P. Slichter Phys. Rev., 92 (1953), p. 212

[11] I. Solomon Phys. Rev., 99 (1955), p. 559

[12] I. Solomon; N. Bloembergen J. Chem. Phys., 25 (1956), p. 261

[13] A. Abragam; J. Combrisson; I. Solomon C. r. hebd. séances Acad. sci., 245 (1957), p. 157

[14] M-A. Bouchiat; T.R. Carver; C.M. Varnum Phys. Rev. Lett., 5 (1960), p. 373

[15] F.D. Colegrove; L.D. Schearer; G.K. Walters Phys. Rev., 132 (1963), p. 2561

[16] T.R. Gentile; P.J. Nacher; B. Saam; T.T.G. Walker Rev. Mod. Phys., 89 (2017)

[17] A. Abragam; M. Goldman Rep. Prog. Phys., 41 (1978), p. 395

[18] A. Abragam; M. Goldman Nuclear Magnetism: Order and Disorder, Oxford University Press, Oxford, UK, 1982 (Chap. 6)

[19] T. Wenckebach Essentials of Dynamic Nuclear Polarization, Spindrift Publications, The Netherlands, 2016

[20] C.D. Jeffries Phys. Rev., 106 (1957), p. 164

[21] A. Abragam; W.G. Proctor C. r. hebd. séances Acad. sci., 246 (1958), p. 2253

[22] M. Goldman; A. Landesman C. r. hebd. séances Acad. sci., 252 (1961), p. 263

[23] M. Goldman Eindhoven, The Netherlands, July 1962 (J. Smidt, ed.), North Holland, Amsterdam (1963), p. 688

[24] M. Goldman; A. Landesman Phys. Rev., 132 (1963), p. 610

[25] I. Solomon Eindhoven, The Netherlands, July 1962 (J. Smidt, ed.), North Holland, Amsterdam (1963), p. 25

[26] S.F.J. Cox; V. Bouffard; M. Goldman J. Phys. C, 6 (1973), p. L100

[27] M. Goldman; S.F.J. Cox; V. Bouffard J. Phys. C, 7 (1974), p. 2940

[28] W. De Boer; M. Borghini; K. Morimoto; T.O. Niinikoski J. Low Temp. Phys., 15 (1974), p. 249

[29] W. De Boer J. Low Temp. Phys., 22 (1976), p. 185

[30] A. Abragam; M. Goldman Nuclear Magnetism: Order and Disorder, Oxford University Press, Oxford, UK, 1982 (Chap. 8)

[31] C. Urbina; J-F. Jacquinot; M. Goldman J. Phys. C, 19 (1986), p. 2275

[32] M. Goldman; J-F. Jacquinot; C. Urbina J. Phys. C, 19 (1986), p. 2299

[33] J-H. Ardenkjaer-Larsen J. Magn. Res., 264 (2016), p. 3

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