Comptes Rendus
no. 3
Chemo-mechanics couplings in polymer matrix materials exposed to thermo-oxidative environments
[Couplages oxydation–mécanique dans les résines de type époxy soumises à un environnement dit « haute température »]
Marco Gigliotti1  ; Jean-Claude Grandidier1
1 Institut Pprime, CNRS – ENSMA – Universitè de Poitiers, Département Physique et Mécanique des Matériaux, ENSMA Téleport 2 – 1, Avenue Clement Ader, BP 40109 – F86961 Futuroscope Chasseneuil Cedex, France
Comptes Rendus. Mécanique, Volume 338 (2010) no. 3, pp. 164-175.

Le présent article s'intéresse à la modélisation des couplages entre l'oxydation et la mécanique dans les résines de type époxy soumises à un environnement dit « haute température » (150 °C). Le couplage entre le schéma mécanistique de réaction diffusion de l'oxygène et la mécanique est abordé théoriquement en utilisant une approche classique de la thermodynamique des processus irréversibles. Il est montré que le phénomène de diffusion–réaction peut être influencé par le tenseur des déformations mais aussi par le gradient spatial de la trace des déformations.

The present article focuses on the modelling of chemo-mechanics couplings in polymer matrix materials exposed to thermo-oxidative environments at high temperatures (150 °C). The coupling between oxygen reaction–diffusion and mechanics is put in evidence theoretically through the employment of a unified approach, based on the thermodynamics of irreversible processes; it is found that oxygen reaction–diffusion in the polymer matrix can be influenced by the strain tensor, in particular by its trace and by its spatial gradients.

Reçu le :
Accepté le :
Publié le :
DOI : 10.1016/j.crme.2010.02.008
Keywords: Continuum mechanics, Thermo-oxidation, Diffusion–mechanics couplings, Thermodynamics of irreversible processes
Mots-clés : Milieux continus, Thermo oxydation, Couplage diffusion mécanique, Thermodynamique des processus irréversibles

Marco Gigliotti 1 ; Jean-Claude Grandidier 1

1 Institut Pprime, CNRS – ENSMA – Universitè de Poitiers, Département Physique et Mécanique des Matériaux, ENSMA Téleport 2 – 1, Avenue Clement Ader, BP 40109 – F86961 Futuroscope Chasseneuil Cedex, France 
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Marco Gigliotti; Jean-Claude Grandidier. Chemo-mechanics couplings in polymer matrix materials exposed to thermo-oxidative environments. Comptes Rendus. Mécanique, Volume 338 (2010) no. 3, pp. 164-175. doi : 10.1016/j.crme.2010.02.008. https://comptes-rendus.academie-sciences.fr/mecanique/articles/10.1016/j.crme.2010.02.008/

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