Hydrodynamics and physics of soft objects/Hydrodynamique et physique des objets mous
Structure and flow of polyelectrolyte microgels: from suspensions to glasses
[Structure et écoulement de microgels polyélectrolytes : de la suspension au verre]
[Structure et écoulement de microgels polyélectrolytes : de la suspension au verre]
Comptes Rendus. Physique, Volume 4 (2003) no. 2, pp. 221-230.
Polyelectrolyte microgels are soft particles due to their ability to de-swell osmotically. In dilute suspensions, they behave like soft Brownian particles. Above close-packing, they form pastes which share many features with glasses. The flow properties of suspensions and pastes are universal. They can be tuned at will to get the rheological behaviour which is desired.
Les microgels polyélectrolytes sont des particules colloı̈dales « molles ». Leur élasticité est dominée par l'entropie de translation des contre-ions. Dans les suspensions diluées, les microgels se comportent comme des particules browiennes susceptibles de se gonfler et de se dégonfler par effet osmotique. A partir d'une concentration en polymère généralement faible, les microgels forment des pâtes dont la dynamique présentent des analogies fortes avec celle des verres. Les propriétés d'écoulement des suspensions et des pâtes sont universelles. Elles peuvent être ajustées à volonté afin d'obtenir le comportement rhéologique recherché.
Publié le :
DOI :
10.1016/S1631-0705(03)00046-X
Keywords:
Polyelectrolyte microgels, Brownian particles, Pastes
Mots-clés : Microgels polyélectrolytes, Particules browiennes, Pâtes
Mots-clés : Microgels polyélectrolytes, Particules browiennes, Pâtes
Affiliations des auteurs :
Michel Cloitre 1 ; Régis Borrega 1 ; Fabrice Monti 1 ; Ludwik Leibler 1
@article{CRPHYS_2003__4_2_221_0,
author = {Michel Cloitre and R\'egis Borrega and Fabrice Monti and Ludwik Leibler},
title = {Structure and flow of polyelectrolyte microgels: from suspensions to glasses},
journal = {Comptes Rendus. Physique},
pages = {221--230},
publisher = {Elsevier},
volume = {4},
number = {2},
year = {2003},
doi = {10.1016/S1631-0705(03)00046-X},
language = {en},
}
TY - JOUR AU - Michel Cloitre AU - Régis Borrega AU - Fabrice Monti AU - Ludwik Leibler TI - Structure and flow of polyelectrolyte microgels: from suspensions to glasses JO - Comptes Rendus. Physique PY - 2003 SP - 221 EP - 230 VL - 4 IS - 2 PB - Elsevier DO - 10.1016/S1631-0705(03)00046-X LA - en ID - CRPHYS_2003__4_2_221_0 ER -
%0 Journal Article %A Michel Cloitre %A Régis Borrega %A Fabrice Monti %A Ludwik Leibler %T Structure and flow of polyelectrolyte microgels: from suspensions to glasses %J Comptes Rendus. Physique %D 2003 %P 221-230 %V 4 %N 2 %I Elsevier %R 10.1016/S1631-0705(03)00046-X %G en %F CRPHYS_2003__4_2_221_0
Michel Cloitre; Régis Borrega; Fabrice Monti; Ludwik Leibler. Structure and flow of polyelectrolyte microgels: from suspensions to glasses. Comptes Rendus. Physique, Volume 4 (2003) no. 2, pp. 221-230. doi : 10.1016/S1631-0705(03)00046-X. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/S1631-0705(03)00046-X/
[1] Europhys. Lett., 42 (1998), p. 271
[2] Europhys. Lett., 76 (1996), p. 153
[3] Langmuir, 12 (1996), p. 4060
[4] Adv. Colloid Interface Sci., 80 (1999) no. 1
[5] Progr. Org. Coatings 20 (1992), p. 487
[6] R. Borrega, Suspensions de microgels polyélectrolytes : propriétés physico-chimiques, rhéologie, écoulemen, Thèse de l'Université Paris VI, 2000
[7] J. Colloid Interface Sci., 133 (1989), p. 265
[8] J. Chim. Phys., 93 (1996), p. 941
[9] Responsive Gels: Volume Transitions I (K. Dusek, ed.), Springer-Verlag, Berlin, 1993 (See articles in)
[10] J. Phys. Chem. B, 102 (1998), p. 1364
[11] Europhys. Lett., 47 (1999), p. 729
[12] Macromolecules, 29 (1996), p. 8260
[13] J. Rheology, 38 (1994), p. 201
[14] Phys. Rev. Lett., 90 (2003) (068303-1)
[15] Theory of Elasticity, Butterworth–Heinemann, 1995
[16] Phys. Rev. Lett., 75 (1995), p. 2051
[17] Phys. Rev. E, 54 (1996), p. 5436
[18] Phys. Rev. Lett., 75 (1995), p. 2610
[19] Physical Aging in Amorphous Polymers and Other Materials, Elsevier, Amsterdam, 1978
[20] Phys. Rev. Lett., 85 (2000), p. 4820
[21] Phys. Rev. E, 78 (1997), p. 2020
[22] J. Rheology, 44 (2000), p. 323
[23] C. R. Acad. Sci., 84 (2000) no. IV, p. 2275
[24] J. Non-Newton. Fluid Mech., 81 (1999), p. 133
- A Free Energy Model for the Plateau Shear Modulus in Thermosensitive Microgel Suspensions, Langmuir, Volume 41 (2025) no. 6, p. 4084 | DOI:10.1021/acs.langmuir.4c04528
- Influence of concentration on dynamic penetration and mechanical properties of cornstarch suspensions, Physics of Fluids, Volume 37 (2025) no. 5 | DOI:10.1063/5.0265631
- A multi-body finite element model for hydrogel packings: linear response to shear, Soft Matter, Volume 21 (2025) no. 7, p. 1363 | DOI:10.1039/d4sm00916a
- Powdered Cross-Linked Gelatin Methacryloyl as an Injectable Hydrogel for Adipose Tissue Engineering, Gels, Volume 10 (2024) no. 3, p. 167 | DOI:10.3390/gels10030167
- Influence of Sonication on the Molecular Characteristics of Carbopol® and Its Rheological Behavior in Microgels, Gels, Volume 10 (2024) no. 7, p. 420 | DOI:10.3390/gels10070420
- Self-Healing of Charged Microgels in Neutral and Charged Environments, Langmuir, Volume 39 (2023) no. 22, p. 7530 | DOI:10.1021/acs.langmuir.2c03054
- Integrated data-driven modeling and experimental optimization of granular hydrogel matrices, Matter, Volume 6 (2023) no. 3, p. 1015 | DOI:10.1016/j.matt.2023.01.011
- Osmotic swelling behavior of surface-charged ionic microgels, The Journal of Chemical Physics, Volume 159 (2023) no. 18 | DOI:10.1063/5.0161027
- Pectin-based microgels for rheological modification in the dilute to concentrated regimes, Journal of Colloid and Interface Science, Volume 628 (2022), p. 684 | DOI:10.1016/j.jcis.2022.07.147
- Transient dynamics of soft particle glasses in startup shear flow. Part II: Memory and aging, Journal of Rheology, Volume 66 (2022) no. 4, p. 717 | DOI:10.1122/8.0000448
- Carbomer microgels as model yield-stress fluids, Reviews in Chemical Engineering, Volume 38 (2022) no. 7, p. 881 | DOI:10.1515/revce-2020-0016
- Linear viscoelastic properties of adhesive soft particle glasses, Journal of Rheology, Volume 65 (2021) no. 3, p. 463 | DOI:10.1122/8.0000239
- Effect of D-Mannitol on the Microstructure and Rheology of Non-Aqueous Carbopol Microgels, Materials, Volume 14 (2021) no. 7, p. 1782 | DOI:10.3390/ma14071782
- Internal structure of ultralow-crosslinked microgels: From uniform deswelling to phase separation, Physical Review E, Volume 103 (2021) no. 2 | DOI:10.1103/physreve.103.022614
- Suspensions of Soft Colloidal Particles, Theory and Applications of Colloidal Suspension Rheology (2021), p. 227 | DOI:10.1017/9781108394826.007
- Criteria for colloidal gelation of thermo-sensitive poly(N-isopropylacrylamide) based microgels, Journal of Colloid and Interface Science, Volume 568 (2020), p. 165 | DOI:10.1016/j.jcis.2020.02.047
- Surface functionalization of carbon nanotubes by biological adhesive polymers carbopol for developing high‐permittivity polymer composites, Journal of Vinyl and Additive Technology, Volume 26 (2020) no. 2, p. 165 | DOI:10.1002/vnl.21729
- Signatures of Overaging in an Aqueous Dispersion of Carbopol, Langmuir, Volume 36 (2020) no. 48, p. 14849 | DOI:10.1021/acs.langmuir.0c02887
- Pathways and challenges towards a complete characterization of microgels, Nature Communications, Volume 11 (2020) no. 1 | DOI:10.1038/s41467-020-17774-5
- Behavior and mechanics of dense microgel suspensions, Proceedings of the National Academy of Sciences, Volume 117 (2020) no. 44, p. 27096 | DOI:10.1073/pnas.2008076117
- Effect of geometrical confinement on the flow of soft microgel particle pastes, Rheologica Acta, Volume 59 (2020) no. 7, p. 435 | DOI:10.1007/s00397-020-01209-5
- Correlation of droplet elasticity and volume fraction effects on emulsion dynamics, Soft Matter, Volume 16 (2020) no. 10, p. 2574 | DOI:10.1039/c9sm02394a
- Transport Phenomena in Viscoplastic Materials, Transport Phenomena in Complex Fluids, Volume 598 (2020), p. 167 | DOI:10.1007/978-3-030-35558-6_5
- Mobility of Yield Stress Fluids on Lubricant-Impregnated Surfaces, ACS Applied Materials Interfaces, Volume 11 (2019) no. 17, p. 16123 | DOI:10.1021/acsami.8b21478
- Rheological properties of concentrated slurries of harvested, incubated and ruptured Nannochloropsis sp. cells, BMC Chemical Engineering, Volume 1 (2019) no. 1 | DOI:10.1186/s42480-019-0011-y
- Viscosity of protein-stabilized emulsions: Contributions of components and development of a semipredictive model, Journal of Rheology, Volume 63 (2019) no. 1, p. 179 | DOI:10.1122/1.5062837
- , SPE/ICoTA Well Intervention Conference and Exhibition (2019) | DOI:10.2118/194251-ms
- Osmotic pressure of permeable ionic microgels: Poisson-Boltzmann theory and exact statistical mechanical relations in the cell model, The Journal of Chemical Physics, Volume 151 (2019) no. 7 | DOI:10.1063/1.5091115
- Compressive resistance of granular-scale microgels: From loose to dense packing, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 553 (2018), p. 406 | DOI:10.1016/j.colsurfa.2018.05.064
- An experimental and numerical study of wellbore leakage mitigation using pH-triggered polymer gelant, Fuel, Volume 217 (2018), p. 444 | DOI:10.1016/j.fuel.2017.12.098
- Elastic and Flow Properties of Densely Packed Binary Microgel Mixtures with Size and Stiffness Disparities, Macromolecules, Volume 51 (2018) no. 23, p. 9901 | DOI:10.1021/acs.macromol.8b01625
- Chemical and microstructural controls on viscoplasticity in Carbopol hydrogel, Polymer, Volume 139 (2018), p. 44 | DOI:10.1016/j.polymer.2018.01.080
- Concentration-dependent swelling and structure of ionic microgels: simulation and theory of a coarse-grained model, Soft Matter, Volume 14 (2018) no. 22, p. 4530 | DOI:10.1039/c8sm00799c
- Phase behavior of binary and polydisperse suspensions of compressible microgels controlled by selective particle deswelling, Physical Review E, Volume 96 (2017) no. 3 | DOI:10.1103/physreve.96.032609
- A review on wall slip in high solid dispersions, Rheologica Acta, Volume 56 (2017) no. 3, p. 283 | DOI:10.1007/s00397-017-1002-7
- Interpenetration of polymeric microgels at ultrahigh densities, Scientific Reports, Volume 7 (2017) no. 1 | DOI:10.1038/s41598-017-01471-3
- The glass and jamming transitions of soft polyelectrolyte microgel suspensions, Soft Matter, Volume 12 (2016) no. 16, p. 3710 | DOI:10.1039/c5sm03001c
- Swelling, structure, and phase stability of compressible microgels, Soft Matter, Volume 12 (2016) no. 44, p. 9086 | DOI:10.1039/c6sm02056a
- Dielectric spectroscopy of ionic microgel suspensions, Soft Matter, Volume 12 (2016) no. 48, p. 9705 | DOI:10.1039/c6sm01683a
- Counterion-induced swelling of ionic microgels, The Journal of Chemical Physics, Volume 145 (2016) no. 16 | DOI:10.1063/1.4964864
- Thermo-Resistant Soft Glassy Suspensions of Polymeric Micellar Nanoparticles in Ionic Liquid, ACS Applied Materials Interfaces, Volume 7 (2015) no. 23, p. 12411 | DOI:10.1021/am507587s
- Viscosity of soft spherical micro-hydrogel suspensions, Journal of Colloid and Interface Science, Volume 442 (2015), p. 75 | DOI:10.1016/j.jcis.2014.11.064
- Build-up and two-step relaxation of internal stress in jammed suspensions, Journal of Rheology, Volume 59 (2015) no. 1, p. 63 | DOI:10.1122/1.4901750
- Electrostatic Interactions and Osmotic Pressure of Counterions Control the pH-Dependent Swelling and Collapse of Polyampholyte Microgels with Random Distribution of Ionizable Groups, Macromolecules, Volume 48 (2015) no. 16, p. 5914 | DOI:10.1021/acs.macromol.5b01305
- , SPE Annual Technical Conference and Exhibition (2015) | DOI:10.2118/174940-ms
- Avalanche-like fluidization of a non-Brownian particle gel, Soft Matter, Volume 11 (2015) no. 46, p. 9026 | DOI:10.1039/c5sm01259g
- Tunable rheology of dense soft deformable colloids, Current Opinion in Colloid Interface Science, Volume 19 (2014) no. 6, p. 561 | DOI:10.1016/j.cocis.2014.09.007
- Slip Length Measurements Using µPIV and TIRF‐Based Velocimetry, Israel Journal of Chemistry, Volume 54 (2014) no. 11-12, p. 1589 | DOI:10.1002/ijch.201400111
- Sensitive microgels as model colloids and microcapsules, Journal of Polymer Science Part A: Polymer Chemistry, Volume 52 (2014) no. 4, p. 435 | DOI:10.1002/pola.27024
- Dynamical role of slip heterogeneities in confined flows, Physical Review E, Volume 89 (2014) no. 5 | DOI:10.1103/physreve.89.052309
- Form factor of pNIPAM microgels in overpacked states, The Journal of Chemical Physics, Volume 141 (2014) no. 3 | DOI:10.1063/1.4885444
- Particulate and continuum mechanics of microgel pastes: effect and non-effect of compositional heterogeneity, Colloid and Polymer Science, Volume 291 (2013) no. 12, p. 2927 | DOI:10.1007/s00396-013-3032-8
- Local mobility and microstructure in periodically sheared soft particle glasses and their connection to macroscopic rheology, Journal of Rheology, Volume 57 (2013) no. 3, p. 1023 | DOI:10.1122/1.4802631
- Surfactant-Activated Microgels: A New Pathway to Rheology Modification, Langmuir, Volume 29 (2013) no. 50, p. 15521 | DOI:10.1021/la403723x
- Macro- and Microrheology of Heterogeneous Microgel Packings, Macromolecules, Volume 46 (2013) no. 5, p. 1962 | DOI:10.1021/ma302255x
- Microscopic Origin of Internal Stresses in Jammed Soft Particle Suspensions, Physical Review Letters, Volume 111 (2013) no. 26 | DOI:10.1103/physrevlett.111.268301
- A simple shear cell for the direct visualization of step-stress deformation in soft materials, Rheologica Acta, Volume 52 (2013) no. 5, p. 383 | DOI:10.1007/s00397-013-0679-5
- Swelling and shear viscosity of stimuli-responsive colloidal systems, Soft Matter, Volume 9 (2013) no. 22, p. 5319 | DOI:10.1039/c3sm50374g
- Elasticity of compressed microgel suspensions, Soft Matter, Volume 9 (2013) no. 22, p. 5401 | DOI:10.1039/c3sm50222h
- The Polymer/Colloid Duality of Microgel Suspensions, Annual Review of Physical Chemistry, Volume 63 (2012) no. 1, p. 25 | DOI:10.1146/annurev-physchem-032511-143735
- pH‐Responsive Nanogels: Synthesis and Physical Properties, Hydrogel Micro and Nanoparticles (2012), p. 81 | DOI:10.1002/9783527646425.ch4
- Thermorheological properties of a Carbopol gel under shear, Journal of Non-Newtonian Fluid Mechanics, Volume 183-184 (2012), p. 14 | DOI:10.1016/j.jnnfm.2012.07.005
- How do soft particle glasses yield and flow near solid surfaces?, Soft Matter, Volume 8 (2012) no. 1, p. 140 | DOI:10.1039/c1sm06074k
- Phase and non-equilibrium behaviour of microgel suspensions as a function of particle stiffness, Soft Matter, Volume 8 (2012) no. 15, p. 4141 | DOI:10.1039/c2sm06973c
- Short-ranged pair distribution function for concentrated suspensions of soft particles, Soft Matter, Volume 8 (2012) no. 15, p. 4216 | DOI:10.1039/c2sm06940g
- UCST-Like Hybrid PAAm-AA/Fe3O4 Microgels. Effect of Fe3O4 Nanoparticles on Morphology, Thermosensitivity and Elasticity, Langmuir, Volume 27 (2011) no. 13, p. 8027 | DOI:10.1021/la200579j
- Yielding, Flow, and Slip in Microgel Suspensions: From Microstructure to Macroscopic Rheology, Microgel Suspensions (2011), p. 283 | DOI:10.1002/9783527632992.ch11
- Rheology of Industrially Relevant Microgels, Microgel Suspensions (2011), p. 327 | DOI:10.1002/9783527632992.ch13
- Swelling Thermodynamics of Microgel Particles, Microgel Suspensions (2011), p. 71 | DOI:10.1002/9783527632992.ch4
- Bulk and shear moduli of compressed microgel suspensions, Physical Review E, Volume 84 (2011) no. 6 | DOI:10.1103/physreve.84.060402
- Mircorheology and jamming in a yield-stress fluid, Rheologica Acta, Volume 50 (2011) no. 4, p. 317 | DOI:10.1007/s00397-010-0519-9
- Glassy dynamics and mechanical response in dense fluids of soft repulsive spheres. II. Shear modulus, relaxation-elasticity connections, and rheology, The Journal of Chemical Physics, Volume 134 (2011) no. 20 | DOI:10.1063/1.3592565
- Micromechanics of Soft Particle Glasses, High Solid Dispersions, Volume 236 (2010), p. 117 | DOI:10.1007/12_2010_90
- Rheological fingerprinting of an aging soft colloidal glass, Journal of Rheology, Volume 54 (2010) no. 4, p. 915 | DOI:10.1122/1.3442901
- Dynamics and rheology of colloidal star polymers, Soft Matter, Volume 6 (2010) no. 12, p. 2825 | DOI:10.1039/b926526k
- The effect of perchlorate ions on a pyridine-based microgel, Advances in Colloid and Interface Science, Volume 147-148 (2009), p. 67 | DOI:10.1016/j.cis.2008.11.002
- From Polymers to Colloids: Engineering the Dynamic Properties of Hairy Particles, High Solid Dispersions, Volume 236 (2009), p. 1 | DOI:10.1007/12_2009_31
- Review on the dynamics and micro-structure of pH-responsive nano-colloidal systems, Advances in Colloid and Interface Science, Volume 136 (2008) no. 1-2, p. 25 | DOI:10.1016/j.cis.2007.07.002
- Influence of short-range forces on wall-slip in microgel pastes, Journal of Rheology, Volume 52 (2008) no. 5, p. 1241 | DOI:10.1122/1.2963135
- Doubly Responsive Polymer−Microgel Composites: Rheology and Structure, Langmuir, Volume 24 (2008) no. 20, p. 11474 | DOI:10.1021/la8018056
- Preparation, Properties and Applications of Colloidal Microgels, Handbook of Industrial Water Soluble Polymers (2007), p. 268 | DOI:10.1002/9780470988701.ch9
- Elastic properties of soft particle pastes, Journal of Rheology, Volume 50 (2006) no. 3, p. 353 | DOI:10.1122/1.2186982
- Microstructure and rheology of stimuli-responsive microgel systems—effect of cross-linked density, Advances in Colloid and Interface Science, Volume 113 (2005) no. 2-3, p. 111 | DOI:10.1016/j.cis.2005.01.002
- Tailoring the Flow Properties of Soft Colloidal Dispersions, Macromolecular Symposia, Volume 229 (2005) no. 1, p. 99 | DOI:10.1002/masy.200551112
- Microstructure and rheological properties of pH-responsive core–shell particles, Polymer, Volume 46 (2005) no. 23, p. 10066 | DOI:10.1016/j.polymer.2005.08.007
- Slip and flow in pastes of soft particles: Direct observation and rheology, Journal of Rheology, Volume 48 (2004) no. 6, p. 1295 | DOI:10.1122/1.1795171
- Slip and Flow in Soft Particle Pastes, Physical Review Letters, Volume 92 (2004) no. 19 | DOI:10.1103/physrevlett.92.198302
- Dynamics and microstructure of charged soft nano-colloidal particles, Polymer, Volume 45 (2004) no. 16, p. 5515 | DOI:10.1016/j.polymer.2004.05.055
Cité par 88 documents. Sources : Crossref
Commentaires - Politique