Comptes Rendus
no. 8
Nanophotonics and near field / Nanophotonique et champ proche
DNA – novel nanomaterial for applications in photonics and in electronics
[ADN – nanomatériau nouveau pour les applications en photonique et en électronique]
Ileana Rau1  ; James G. Grote2 ; Francois Kajzar1, 3  ; Agnieszka Pawlicka4
1 Faculty of Applied Chemistry and Materials Science, University Politehnica Bucharest, Bucharest, Romania
2 Air Force Research Laboratory, AFRL/RXPS, 3005 Hobson Way, Wright–Patterson Air Force Base, OH 45433-7707, USA
3 Université dʼAngers, institut des sciences et technologies moleculaires dʼAngers, MOLTECH Anjou – UMR CNRS 6200, équipe interaction moleculaire optique non lineaire et structuration MINOS, 2, boulevard Lavoisier, 49045 Angers cedex, France
4 IQSC, Universidade de São Paulo, C.P. 780, CEP 13566-590, São Carlos, SP, Brazil
Comptes Rendus. Physique, Nanophotonics and near field/Nanophotonique et champ proche, Volume 13 (2012) no. 8, pp. 853-864.

Fonctionnalisation de lʼacide désoxyribonucléique (ADN) avec des composées tensioactifs et avec les molécules actives, la fabrication des films minces ainsi que leurs propriétés optiques linéaires, non linéaires et électriques sont examinées et discutées. Avec lʼaide dʼun modèle quantique à trois niveaux nous montrons que la variation anormale de la susceptibilité cubique en fonction de la concentration du chromophore dans des films minces faits à partir des complexes ADN–CTMA, dopés avec le Disperse Red 1, peut être expliquée par le déplacement de la bande dʼabsorption. Nous décrivons également comment lʼADN peut être plastifié et transformé en membranes conductrices. La conductivité électrique de ces membranes peut être contrôlée par un dopage adéquat avec des ions ou polymères conducteurs. Les membranes obtenues montrent une conductivité électrique élevée. La conductivité, mesurée à lʼambiante, varies entre de 3.5×10−4 et 10−5S/cm en fonction du dopant utilisé. Elle croit avec la température, pour attendre ca 10−3S/cm, dans le meilleur cas, à 358 K, en obéissant essentiellement la loi dʼArrhénius. Les applications pratiques des complexes dérivés de lʼADN sont également décrites et discutés.

Functionalization with surfactants and with active molecules of deoxyribonucleic acid (DNA), thin film processing as well as their nonlinear optical and electrical properties are reviewed and discussed. On the basis of a quantum three level model, we show that the anomalous concentration variation of cubic susceptibility χ(3)(−3ω;ω,ω,ω) in thin films of DNA–CTMA complexes doped with Disperse Red 1 chromophore can be explained by the concentration variation of two-photon resonance contribution. We show also that the DNA complexes, plasticized with glycerol and adequately doped can be processed into self standing conducting membranes with a high electrical conductivity. The measured ionic conductivity at room temperature, depending on dopant used and its concentration, is in the range of 3.5×10−4–10−5S/cm and increases linearly as a function of temperature, reaching 10−3S/cm at 358 K for the most conducting sample, obeying predominantly the Arrhenius law. Practical applications of DNA complexes are also described and discussed.

Publié le :
DOI : 10.1016/j.crhy.2012.09.005
Keywords: Deoxyribonucleic acid, DNA–CTMA complex, Functionalized DNA–CTMA, NLO properties, Third harmonic generation, Solid electrochromic cells
Mots-clés : Lʼacide désoxyribonucléique, LʼADN–CTMA, LʼADN–CTMA fonctionnalisé, Propriétés optiques non linéaires, De troisième génération dʼharmonique trois, Cellule électrochromique solide

Ileana Rau 1 ; James G. Grote 2 ; Francois Kajzar 1, 3 ; Agnieszka Pawlicka 4

1 Faculty of Applied Chemistry and Materials Science, University Politehnica Bucharest, Bucharest, Romania
2 Air Force Research Laboratory, AFRL/RXPS, 3005 Hobson Way, Wright–Patterson Air Force Base, OH 45433-7707, USA
3 Université dʼAngers, institut des sciences et technologies moleculaires dʼAngers, MOLTECH Anjou – UMR CNRS 6200, équipe interaction moleculaire optique non lineaire et structuration MINOS, 2, boulevard Lavoisier, 49045 Angers cedex, France
4 IQSC, Universidade de São Paulo, C.P. 780, CEP 13566-590, São Carlos, SP, Brazil 
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Ileana Rau; James G. Grote; Francois Kajzar; Agnieszka Pawlicka. DNA – novel nanomaterial for applications in photonics and in electronics. Comptes Rendus. Physique, Nanophotonics and near field/Nanophotonique et champ proche, Volume 13 (2012) no. 8, pp. 853-864. doi : 10.1016/j.crhy.2012.09.005. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2012.09.005/

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[97] I. Iosub; F. Kajzar; M. Makowska-Janusik; A. Aurelia Meghea; A. Tane; I. Rau Electronic structure and optical properties of some anthocyanins extracted from grapes, Opt. Mater., Volume 34 (2012) no. 10, pp. 1644-1650

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  • Sesuraj Balasamy; Surya Sekaran; Rajalakshmanan Eswaramoorthy Marine biopolymers in biosensing, Marine Biopolymers (2025), p. 469 | DOI:10.1016/b978-0-443-15606-9.00016-4
  • Rafał Węgłowski; Anna Spadło; Dorota Węgłowska Banana DNA derivatives as homeotropic alignment layers in optical devices, Soft Matter, Volume 20 (2024) no. 43, p. 8561 | DOI:10.1039/d4sm00322e
  • Akimitsu Okamoto Nucleic Acids in Green Chemistry, Handbook of Chemical Biology of Nucleic Acids (2023), p. 2447 | DOI:10.1007/978-981-19-9776-1_80
  • Adrian Petris; Petronela Gheorghe; Ileana Rau Influence of continuous wave laser light at 532 nm on transmittance and on photoluminescence of DNA-CTMA-RhB solutions, Heliyon, Volume 9 (2023) no. 10, p. e20410 | DOI:10.1016/j.heliyon.2023.e20410
  • Bo Bo Han; Osamah Alsalman; Jaymit Surve; Juveriya Parmar; Sofyan Taya; Shobhit K. Patel Compact size Zr–Fe2O3 inspired metal-dielectric angle and polarization insensitive nanostructure for efficient solar energy absorption, International Journal of Thermal Sciences, Volume 190 (2023), p. 108330 | DOI:10.1016/j.ijthermalsci.2023.108330
  • Adrian Petris; Petronela Gheorghe; Ileana Rău DNA–CTMA Matrix Influence on Rhodamine 610 Light Emission in Thin Films, Polymers, Volume 15 (2023) no. 14, p. 3105 | DOI:10.3390/polym15143105
  • Petronela Gheorghe; Adrian Petris; Adina Mirela Anton Optical Limiting Properties of DNA Biopolymer Doped with Natural Dyes, Polymers, Volume 16 (2023) no. 1, p. 96 | DOI:10.3390/polym16010096
  • Amro Abd Al Fattah Amara Natural Polymer Types and Applications, Biomolecules from Natural Sources (2022), p. 31 | DOI:10.1002/9781119769620.ch2
  • Ana Laura Torres-Huerta; Aurora Antonio-Pérez; Yolanda García-Huante; Nayelhi Julieta Alcázar-Ramírez; Juan Carlos Rueda-Silva Biomolecule-Based Optical Metamaterials: Design and Applications, Biosensors, Volume 12 (2022) no. 11, p. 962 | DOI:10.3390/bios12110962
  • Akimitsu Okamoto Nucleic Acids in Green Chemistry, Handbook of Chemical Biology of Nucleic Acids (2022), p. 1 | DOI:10.1007/978-981-16-1313-5_80-1
  • Lada Puntus; Konstantin Lyssenko; Ilya V. Taidakov; Francois Kajzar; Ileana Rău Corona poling of PMMA based thin films doped by oxy and carboxy derivatives of [2,2]paracyclophane, Optical Materials, Volume 131 (2022), p. 112663 | DOI:10.1016/j.optmat.2022.112663
  • Ana‐Maria Manea‐Saghin; Cosmina Andreea Marin; Carla‐Cezarina Pădurețu; François Kajzar Third-order optical nonlinearity of DNA‐CTMA complex doped with different aromatic moieties, Optics Laser Technology, Volume 149 (2022), p. 107863 | DOI:10.1016/j.optlastec.2022.107863
  • Marjan Ghasemi; Hayoung Jeong; Donggyu Kim; Byungjoo Kim; Joon Ik Jang; Kyunghwan Oh Linear and nonlinear optical properties of transfer ribonucleic acid (tRNA) thin solid films, RSC Advances, Volume 12 (2022) no. 14, p. 8661 | DOI:10.1039/d1ra09412b
  • Adam Szukalski; Przemysław Krawczyk; Bouchta Sahraoui; Beata Jędrzejewska Multifunctional Oxazolone Derivative as an Optical Amplifier, Generator, and Modulator, The Journal of Physical Chemistry B, Volume 126 (2022) no. 8, p. 1742 | DOI:10.1021/acs.jpcb.1c08056
  • Matjaž Ličen; Stefano Masiero; Silvia Pieraccini; Irena Drevenšek-Olenik Reversible Photoisomerization in Thin Surface Films from Azo-Functionalized Guanosine Derivatives, ACS Omega, Volume 6 (2021) no. 23, p. 15421 | DOI:10.1021/acsomega.1c01879
  • Dan Bai; Huhu Feng; Xingchen Yu; Chenxin Ran; Wei Huang Functional Nucleic Acid Hybrid Materials for Photovoltaic Cells: Design, Fabrication, and Performance, Advances in Sustainable Energy (2021), p. 67 | DOI:10.1007/978-3-030-74406-9_3
  • Aleksandra Radko; Jacek Nizioł; Katarzyna Makyła-Juzak; Robert Ekiert; Natalia Górska; Andrzej Górecki; Monika Marzec Properties of DNA-CTMA monolayers obtained by Langmuir-Blodgett technique, Materials Science and Engineering: B, Volume 263 (2021), p. 114859 | DOI:10.1016/j.mseb.2020.114859
  • Yueh-Cheng Lin; Chi-Hsien Cheng; Yu-Chueh Hung; Ruth Shinar; Ioannis Kymissis; Emil J. List-Kratochvil, Organic and Hybrid Sensors and Bioelectronics XIV (2021), p. 23 | DOI:10.1117/12.2593450
  • Christofer Lendel; Niclas Solin Protein nanofibrils and their use as building blocks of sustainable materials, RSC Advances, Volume 11 (2021) no. 62, p. 39188 | DOI:10.1039/d1ra06878d
  • Gratiela Teodora Tihan; Mihaela Mindroiu; Ileana Rau; Lucas Marinho Nóbrega de Assis; Agnieszka Pawlicka; Roxana Gabriela Zgarian The electrochromic device performance with DNA based electrolyte, Materials Chemistry and Physics, Volume 241 (2020), p. 122349 | DOI:10.1016/j.matchemphys.2019.122349
  • Adrian Petris; Petronela Gheorghe; Ileana Rau; Ana-Maria Manea-Saghin; Francois Kajzar All-optical spatial phase modulation in films of dye-doped DNA biopolymer, European Polymer Journal, Volume 110 (2019), p. 130 | DOI:10.1016/j.eurpolymj.2018.11.021
  • Iraj S. Amiri; M.M. Ariannejad; J. Ali; P. Yupapin Design of optical splitter using ion-exchange method for DNA bio-sensor, Journal of King Saud University - Science, Volume 31 (2019) no. 4, p. 549 | DOI:10.1016/j.jksus.2018.03.012
  • Adina-Mirela Anton; Ileana Rau; Francois Kajzar; Alina-Marieta Simion; Cristian Simion Third order nonlinear optical properties of DNA-based biopolymers thin films doped with selected natural chromophores, Optical Materials, Volume 88 (2019), p. 181 | DOI:10.1016/j.optmat.2018.11.037
  • Natalia V. Kamanina; Andrea Camposeo; Yuris Dzenis; Maria Farsari; Luana Persano, Advanced Manufacturing Technologies for Micro- and Nanosystems in Security and Defence (2018), p. 22 | DOI:10.1117/12.2501864
  • Izabel Caldeira; Andressa Lüdtke; Fabiele Tavares; Camila Cholant; Raphael Balboni; Wladimir H. Flores; Alexandre Galio; Agnieszka Pawlicka; César O. Avellaneda Ecologically friendly xanthan gum-PVA matrix for solid polymeric electrolytes, Ionics, Volume 24 (2018) no. 2, p. 413 | DOI:10.1007/s11581-017-2223-6
  • Adina-Mirela Anton; Ileana Rau; Francois Kajzar; Alina-Marieta Simion; Cristian Pirvu; Nicoleta Radu; Cristian Simion Natural materials with enhanced optical damage threshold, Optical Materials, Volume 86 (2018), p. 1 | DOI:10.1016/j.optmat.2018.09.022
  • Mokae Fanuel Bambo; Rui Werner Marcedo Krause; Richard Motlhaletsi Moutloali Facile Method for the Synthesis of Copper Nanoparticles Supported on the Organoclay Material, Journal of Biomaterials and Nanobiotechnology, Volume 08 (2017) no. 02, p. 144 | DOI:10.4236/jbnb.2017.82010
  • Jacek Nizioł; Joanna Fiedor; Joanna Pagacz; Edyta Hebda; Monika Marzec; Ewa Gondek; I. V. Kityk DNA-hexadecyltrimethyl ammonium chloride complex with enhanced thermostability as promising electronic and optoelectronic material, Journal of Materials Science: Materials in Electronics, Volume 28 (2017) no. 1, p. 259 | DOI:10.1007/s10854-016-5519-9
  • Francois Kajzar; Ileana Rau A simple technique for measuring the optical propagation losses in thin films, Molecular Crystals and Liquid Crystals, Volume 655 (2017) no. 1, p. 51 | DOI:10.1080/15421406.2017.1362310
  • Jacek Nizioł; Katarzyna Makyła-Juzak; Mateusz M. Marzec; Robert Ekiert; Monika Marzec; Ewa Gondek Thermal stability of the solid DNA as a novel optical material, Optical Materials, Volume 66 (2017), p. 344 | DOI:10.1016/j.optmat.2017.02.035
  • Beata Derkowska-Zielinska; Kamil Fedus; Hongzhen Wang; Christophe Cassagne; Georges Boudebs Nonlinear optical characterization of Disperse Orange 3, Optical Materials, Volume 72 (2017), p. 545 | DOI:10.1016/j.optmat.2017.06.055
  • Maria‐Luiza Mircea; Ana‐Maria Manea; François Kajzar; Ileana Rau Tuning NLO Susceptibility in Functionalized DNA, Advanced Optical Materials, Volume 4 (2016) no. 2, p. 271 | DOI:10.1002/adom.201500312
  • Cristiano C. Jayme; Jerzy Kanicki; François Kajzar; Ana F. Nogueira; Agnieszka Pawlicka Influence of DNA and DNA-PEDOT: PSS on dye sensitized solar cell performance, Molecular Crystals and Liquid Crystals, Volume 627 (2016) no. 1, p. 38 | DOI:10.1080/15421406.2015.1137680
  • Jacek Nizioł; Robert Ekiert; Maciej Śniechowski; Magdalena Słomiany; Mateusz M. Marzec Thermally forced transitions of DNA-CTMA complex microstructure, Optical Materials, Volume 56 (2016), p. 84 | DOI:10.1016/j.optmat.2016.01.049
  • Anca Aldea; Ana-Maria Albu; Ileana Rau New polymeric materials for photonic applications: Preliminary investigations, Optical Materials, Volume 56 (2016), p. 90 | DOI:10.1016/j.optmat.2016.01.032
  • Maria Magliulo; Kyriaki Manoli; Eleonora Macchia; Gerardo Palazzo; Luisa Torsi Tailoring Functional Interlayers in Organic Field‐Effect Transistor Biosensors, Advanced Materials, Volume 27 (2015) no. 46, p. 7528 | DOI:10.1002/adma.201403477
  • A. C. Nwanya; C. I. Amaechi; A. E. Udounwa; R. U. Osuji; M. Maaza; F. I. Ezema Complex impedance and conductivity of agar-based ion-conducting polymer electrolytes, Applied Physics A, Volume 119 (2015) no. 1, p. 387 | DOI:10.1007/s00339-014-8979-x
  • C Pradeep; C P G Vallabhan; P Radhakrishnan; V P N Nampoori Amplified spontaneous emission from PicoGreen dye intercalated in deoxyribonucleic acid lipid complex, Laser Physics Letters, Volume 12 (2015) no. 12, p. 125802 | DOI:10.1088/1612-2011/12/12/125802
  • Douglas Burgess; Gari Owen; Harbinder Rana; Roberto Zamboni; François Kajzar; Attila A. Szep; A. Pawlicka; A. Firmino; F. Sentanin; R. C. Sabadini; D. E. Q. Jimenez; C. C. Jayme; M. Mindroiu; R. G. Zgarian; G. T. Tihan; I. Rau; M. M. Silva; A. F. Nogueira; J. Kanicki; F. Kajzar, Optics and Photonics for Counterterrorism, Crime Fighting, and Defence XI; and Optical Materials and Biomaterials in Security and Defence Systems Technology XII, Volume 9652 (2015), p. 96520U | DOI:10.1117/12.2196924
  • T. Bazaru Rujoiu; A. Petris; V. I. Vlad; I. Rau; A.-M. Manea; F. Kajzar Lasing in DNA–CTMA doped with Rhodamine 610 in butanol, Physical Chemistry Chemical Physics, Volume 17 (2015) no. 19, p. 13104 | DOI:10.1039/c5cp01727k
  • Chunhe Yang; Aiwei Tang; Xu Li; Fujun Zhang; Feng Teng Electrochemistry of Cu(I) doped CdS nanoparticles hosted by DNA–CTMA in aqueous electrolyte, Materials Chemistry and Physics, Volume 147 (2014) no. 3, p. 1074 | DOI:10.1016/j.matchemphys.2014.06.061
  • Franciani C. Sentanin; Lucas Ponez; Agnieszka Pawlicka Electrochromic Windows with PVB Electrolytes, Molecular Crystals and Liquid Crystals, Volume 604 (2014) no. 1, p. 107 | DOI:10.1080/15421406.2014.968040
  • Christopher E. Tabor; François Kajzar; Toshikuni Kaino; Yasuhiro Koike; Fahima Ouchen; Eliot Gomez; Donna Joyce; Adrienne Williams; Steve Kim; Emily Heckman; Lewis Johnson; Perry Yaney; Narayanan Venkat; Andrew Steckl; François Kajzar; Ileana Rau; Agnieszka Pawlicka; Paras Prasad; James Grote, Organic Photonic Materials and Devices XVI, Volume 8983 (2014), p. 89831A | DOI:10.1117/12.2041321
  • E.L. Albuquerque; U.L. Fulco; V.N. Freire; E.W.S. Caetano; M.L. Lyra; F.A.B.F. de Moura DNA-based nanobiostructured devices: The role of quasiperiodicity and correlation effects, Physics Reports, Volume 535 (2014) no. 4, p. 139 | DOI:10.1016/j.physrep.2013.10.004
  • Chunhe Yang; Aiwei Tang; Feng Teng Electrochemistry of deoxyribonucleic acid–cetyltrimethylammonium complex with considering O2 effect, Thin Solid Films, Volume 550 (2014), p. 630 | DOI:10.1016/j.tsf.2013.10.040
  • Chunhe Yang; Aiwei Tang; Xu Li; Kejian Jiang; Feng Teng Electrochemical evaluation of the frontier orbitals of organic dyes in aqueous electrolyte, Electrochimica Acta, Volume 102 (2013), p. 108 | DOI:10.1016/j.electacta.2013.04.005
  • Alexandrina Tane; Francois Kajzar; Roxana Zgarian; Ileana Rau; Dawid Grabarek; Paweł Karpinski; Andrzej Miniewicz Refractive index and surface relief grating formation in DNA based dye-doped films, Macromolecular Research, Volume 21 (2013) no. 3, p. 331 | DOI:10.1007/s13233-013-1131-5
  • Julien Massin; Stéphane Parola; Chantal Andraud; François Kajzar; Ileana Rau Enhanced fluorescence of isophorone derivatives in DNA based materials, Optical Materials, Volume 35 (2013) no. 10, p. 1810 | DOI:10.1016/j.optmat.2013.04.021
  • Ana-Maria Manea; Ileana Rau; Francois Kajzar; Aurelia Meghea Fluorescence, spectroscopic and NLO properties of green tea extract in deoxyribonucleic acid, Optical Materials, Volume 36 (2013) no. 1, p. 140 | DOI:10.1016/j.optmat.2013.04.016
  • Ana-Maria Manea; Ileana Rau; Alexandrina Tane; Francois Kajzar; Lech Sznitko; Andrzej Miniewicz Poling kinetics and second order NLO properties of DCNP doped PMMA based thin film, Optical Materials, Volume 36 (2013) no. 1, p. 69 | DOI:10.1016/j.optmat.2013.05.012
  • Screening and identification of bioorganic light-emitting substances from marine macrophytes, ALGAE, Volume 30 (1970) no. 2, p. 171 | DOI:10.4490/algae.2015.30.2.171

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