Multiferroic RMnO<sub>3</sub> thin films

Josep Fontcuberta

doi:10.1016/j.crhy.2015.01.012

Multiferroic RMnO₃ thin films
[Films fins de RMnO₃ multiferroïque]

Josep Fontcuberta ¹

¹ Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, Bellaterra 08193, Catalonia, Spain

Comptes Rendus. Physique, Multiferroic materials and heterostructures / Matériaux et hétérostructures multiferroïques, Volume 16 (2015) no. 2, pp. 204-226.

Résumé
Abstract

Les matériaux multiferroïques ont reçu une attention étonnante au cours des dernières décades liée à la possibilité de couplage entre les ordres ferroïques et à son potentiel pour de nouvelles applications et de nouveaux concepts de composants. De ce fait, une nouvelle connaissance des mécanismes de couplage et de la science des matériaux a émergé. Les pérovskites multiferroïques RMnO₃ sont au centre de ces progrès, en ce sens qu'elles fournissent une plateforme adaptée pour façonner les interactions spin–spin et spin–réseau.

En ce qui concerne les applications, le développement de films minces de matériaux multiferroïques a aussi énormément progressé, et de nos jours des films minces de manganites avec des propriétés similaires à celles des matériaux massifs existent. Nous passons en revue ici les résultats obtenus dans le domaine de la croissance de couches minces épitaxiés de RMnO₃ hexagonal et orthorhombique et de la caractérisation de leurs propriétés magnétiques et ferroélectriques. Nous discutons certains enjeux et proposons quelques idées pour des recherches et développements futurs.

Multiferroic materials have received an astonishing attention in the last decades due to expectations that potential coupling between distinct ferroic orders could inspire new applications and new device concepts. As a result, a new knowledge on coupling mechanisms and materials science has dramatically emerged. Multiferroic RMnO₃ perovskites are central to this progress, providing a suitable platform to tailor spin–spin and spin–lattice interactions.

With views towards applications, the development of thin films of multiferroic materials have also progressed enormously and nowadays thin-film manganites are available, with properties mimicking those of bulk compounds. Here we review achievements on the growth of hexagonal and orthorhombic RMnO₃ epitaxial thin films and the characterization of their magnetic and ferroelectric properties, we discuss some challenging issues, and we suggest some guidelines for future research and developments.

Publié le : 2015-02-24

DOI : 10.1016/j.crhy.2015.01.012

Keywords: Multiferroic perovskite films, Cycloidal antiferromagnetic thin films, Hexagonal ferroelectric thin films, Ferroelectric manganite thin films
Mots-clés : Pérovskites multiferroïques, Couches minces antiferromagnétiques à l'ordre cycloïdal, Couches minces ferroélectriques hexagonales, Couches fines ferroélectriques d'oxydes de manganèse

Affiliations des auteurs :

Josep Fontcuberta ¹

¹ Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, Bellaterra 08193, Catalonia, Spain

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     title = {Multiferroic {RMnO\protect\textsubscript{3}} thin films},
     journal = {Comptes Rendus. Physique},
     pages = {204--226},
     publisher = {Elsevier},
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     doi = {10.1016/j.crhy.2015.01.012},
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Josep Fontcuberta. Multiferroic RMnO₃ thin films. Comptes Rendus. Physique, Multiferroic materials and heterostructures / Matériaux et hétérostructures multiferroïques, Volume 16 (2015) no. 2, pp. 204-226. doi : 10.1016/j.crhy.2015.01.012. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2015.01.012/

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Kanata Watanabe; Hotaka Sakaguchi; Fatima Zahra Chafi; Masami Nishikawa; Hironori Asada; Martin Veis; Takayuki Ishibashi Structural and optical properties of hexagonal and orthorhombic YMnO3 thin films prepared by metal-organic decomposition method, Japanese Journal of Applied Physics, Volume 63 (2024) no. 11, p. 11SP16 | DOI:10.35848/1347-4065/ad86ca
M. M. Abd El‑Raheem; Mahrous R. Ahmed; Sara A. Mohamed Influence of the rate of flow of argon on the optical properties of the MnSmO3 films prepared by magnetron sputtering technique, Journal of Materials Science: Materials in Electronics, Volume 35 (2024) no. 17 | DOI:10.1007/s10854-024-12737-8
Selim E. Toktaş; Serkan Dag Magnetoelectroelastic response of functionally graded multiferroic coatings under moving Hertzian contact, Journal of Mechanics of Materials and Structures, Volume 19 (2024) no. 3, p. 343 | DOI:10.2140/jomms.2024.19.343
John C. Mantilla; Luiz C.C.M. Nagamine; Daniel R. Cornejo; Renato Cohen; Wesley de Oliveira; Paulo E.N. Souza; Sebastião W. da Silva; Fermin F.H. Aragón; Pedro L. Gastelois; Paulo C. Morais; José A.H. Coaquira Structural, morphological, and magnetic characterizations of (Fe0.25Mn0.75)2O3 nanocrystals: A comprehensive stoichiometric determination, Materials Chemistry and Physics, Volume 328 (2024), p. 129943 | DOI:10.1016/j.matchemphys.2024.129943
Hong-Miao Zhao; Hang Zhou; Wei Gan; Hui Han; Hui Li; Rui-Chun Xiao Optical fingerprints of two-dimensional interlayer-sliding multiferroic materials, Physical Review B, Volume 110 (2024) no. 12 | DOI:10.1103/physrevb.110.125413
Hao Li; Yali Yang; Shiqing Deng; Hui Liu; Tianyu Li; Yuzhu Song; He Bai; Tao Zhu; Jiaou Wang; Huanhua Wang; Er-Jia Guo; Xianran Xing; Hongjun Xiang; Jun Chen Significantly Enhanced Room-Temperature Ferromagnetism in Multiferroic EuFeO3−δ Thin Films, Nano Letters, Volume 23 (2023) no. 4, p. 1273 | DOI:10.1021/acs.nanolett.2c04447
S. Holbein; P. Steffens; S. Biesenkamp; J. Ollivier; A. C. Komarek; M. Baum; M. Braden Spin-wave dispersion and magnon chirality in multiferroicTbMnO3, Physical Review B, Volume 108 (2023) no. 10 | DOI:10.1103/physrevb.108.104404
Eric Bousquet; Andrés Cano Non-collinear magnetism multiferroicity: the perovskite case, Physical Sciences Reviews, Volume 8 (2023) no. 4, p. 479 | DOI:10.1515/psr-2019-0071
Sara Passuti; Julien Varignon; Adrian David; Philippe Boullay Scanning Precession Electron Tomography (SPET) for Structural Analysis of Thin Films along Their Thickness, Symmetry, Volume 15 (2023) no. 7, p. 1459 | DOI:10.3390/sym15071459
Johanna Nordlander; Margaret A. Anderson; Charles M. Brooks; Megan E. Holtz; Julia A. Mundy Epitaxy of hexagonal ABO3 quantum materials, Applied Physics Reviews, Volume 9 (2022) no. 3 | DOI:10.1063/5.0098277
Chengchao Xu; Jun Li; Huanfang Tian; Zi-An Li; Huaixin Yang; Jianqi Li Flux Method Growth and Structure and Properties Characterization of Rare-Earth Iron Oxides Lu1−xScxFeO3 Single Crystals, Crystals, Volume 12 (2022) no. 6, p. 769 | DOI:10.3390/cryst12060769
A.M. Zhang; H.F. Cao; X.X. Pan; J.J. Zhu; X.S. Wu Strain-modulated structure distortion and magnetic properties of orthorhombic LuMnO3 thin films, Thin Solid Films, Volume 750 (2022), p. 139186 | DOI:10.1016/j.tsf.2022.139186
Igor Hernandes Gomes Marques; Robert Saraiva Matos; Yonny Romaguera-Barcelay; Ştefan Ţălu; Joaquim Agostinho Moreira; Abilio Almeida; Javier Perez de Cruz; Henrique Duarte da Fonseca Filho; Matjaz Valant Investigation of Stereometric and Fractal Patterns of Spin‐Coated LuMnO3 Thin Films, Advances in Materials Science and Engineering, Volume 2021 (2021) no. 1 | DOI:10.1155/2021/9912247
Heidemarie Schmidt Prospects for application of ferroelectric manganites with controlled vortex density, Applied Physics Letters, Volume 118 (2021) no. 14 | DOI:10.1063/5.0032988
Yunwei Sheng; Ignasi Fina; Marin Gospodinov; Josep Fontcuberta Switchable photovoltaic response in hexagonal LuMnO3 single crystals, Applied Physics Letters, Volume 118 (2021) no. 23 | DOI:10.1063/5.0053379
Lanlan Xu; Qingshi Liu; Junling Meng; Wuping Liao; Xiaojuan Liu; Hongjie Zhang Eu–Mn Charge Transfer and the Strong Charge–Spin–Electronic Coupling Behavior in EuMnO3, Inorganic Chemistry, Volume 60 (2021) no. 3, p. 1367 | DOI:10.1021/acs.inorgchem.0c02498
Yunwei Sheng; Ignasi Fina; Marin Gospodinov; Aaron M. Schankler; Andrew M. Rappe; Josep Fontcuberta Bulk photovoltaic effect in hexagonal LuMnO3 single crystals, Physical Review B, Volume 104 (2021) no. 18 | DOI:10.1103/physrevb.104.184116
G.E. Tongue Magne; R.M. Keumo Tsiaze; A.J. Fotué; N.M. Hounkonnou; L.C. Fai Cumulative effects of fluctuations and magnetoelectric coupling in two-dimensional RMnO3 (R = Tb, Lu and Y) multiferroics, Physics Letters A, Volume 400 (2021), p. 127305 | DOI:10.1016/j.physleta.2021.127305
F. Shao; Z. Y. Ren; C. J. Lu; Y. D. Yang; Q. Zhan; Z. P. Li; J. K. Chen; Y. Wu; K. K. Meng; X. G. Xu; J. Miao; Y. Jiang Self-Assembled Hexagonal Lu1–xInxFeO3 Nanopillars Embedded in Orthorhombic Lu1–xInxFeO3 Nanoparticle Matrixes as Room-Temperature Multiferroic Thin Films for Memory Devices and Spintronic Applications, ACS Applied Nano Materials, Volume 3 (2020) no. 8, p. 7516 | DOI:10.1021/acsanm.0c01139
Menglei Li; Hengxin Tan; Wenhui Duan Hexagonal rare-earth manganites and ferrites: a review of improper ferroelectricity, magnetoelectric coupling, and unusual domain walls, Physical Chemistry Chemical Physics, Volume 22 (2020) no. 26, p. 14415 | DOI:10.1039/d0cp02195d
R. Mandal; M. Hirsbrunner; V. Roddatis; R. Gruhl; L. Schüler; U. Roß; S. Merten; P. Gegenwart; V. Moshnyaga Strain-driven structure-ferroelectricity relationship in hexagonal TbMnO3 films, Physical Review B, Volume 102 (2020) no. 10 | DOI:10.1103/physrevb.102.104106
N. El Mekkaoui; S. Idrissi; S. Mtougui; I. El Housni; R. Khalladi; H. Labrim; S. Ziti; L. Bahmad Monte Carlo study of the manganite oxide perovskite YMnO3, Applied Physics A, Volume 125 (2019) no. 9 | DOI:10.1007/s00339-019-2880-6
Jaianth Vijayakumar; David Bracher; Tatiana M. Savchenko; Michael Horisberger; Frithjof Nolting; C. A. F. Vaz Electric field control of magnetism in Si3N4 gated Pt/Co/Pt heterostructures, Journal of Applied Physics, Volume 125 (2019) no. 11 | DOI:10.1063/1.5083148
Chao Ji; Yancheng Wang; Bixiang Guo; Xiaofan Shen; Qunyong Luo; Jianli Wang; Xianwen Meng; Junting Zhang; Xiaomei Lu; Jinsong Zhu Strain engineering of magnetic and orbital order in perovskite LuMnO3 epitaxial films, Physical Review B, Volume 100 (2019) no. 17 | DOI:10.1103/physrevb.100.174417
D. Kumar; A. David; A. Fouchet; A. Pautrat; J. Varignon; C. U. Jung; U. Lüders; B. Domengès; O. Copie; P. Ghosez; W. Prellier Magnetism tailored by mechanical strain engineering in PrVO3 thin films, Physical Review B, Volume 99 (2019) no. 22 | DOI:10.1103/physrevb.99.224405
R.M. Eremina; E.M. Moshkina; A.R. Muftakhutdinov; I.F. Gilmutdinov; N.M. Lyadov Magnetic properties of the warwickite MnMgBO4, Solid State Communications, Volume 290 (2019), p. 64 | DOI:10.1016/j.ssc.2018.12.019
M. Savinov; V. Bovtun; E. Tereshina-Chitrova; A. Stupakov; A. Dejneka; M. Tyunina Dielectric relaxation in epitaxial films of paraelectric-magnetic SrTiO3-SrMnO3 solid solution, Applied Physics Letters, Volume 112 (2018) no. 5 | DOI:10.1063/1.5017667
Dong Chen; Yu-Jia Wang; Yin-Lian Zhu; Xiu-Liang Ma Effect of transition metal (TM) doping on structural and magnetic properties in hexagonal YMn0.917TM0.083O3 systems, Heliyon, Volume 4 (2018) no. 12, p. e00993 | DOI:10.1016/j.heliyon.2018.e00993
Weipeng Wang; Fuyang Liu; Xuejing Zhang; Xi Shen; Yuan Yao; Yanguo Wang; Banggui Liu; Xiaoyang Liu; Richeng Yu Two types of B-site ordered structures of the double perovskite Y2CrMnO6: experimental identification and first-principles study, Inorganic Chemistry Frontiers, Volume 5 (2018) no. 1, p. 217 | DOI:10.1039/c7qi00686a
J. T. Zhang; C. Ji; J. L. Wang; W. S. Xia; X. M. Lu; J. S. Zhu Stabilization of E -type magnetic order caused by epitaxial strain in perovskite manganites, Physical Review B, Volume 97 (2018) no. 8 | DOI:10.1103/physrevb.97.085124
Junting Zhang; Chao Ji; Yanyan Shangguan; Bixiang Guo; Jianli Wang; Fengzhen Huang; Xiaomei Lu; Jinsong Zhu Strain-driven magnetic phase transitions from an antiferromagnetic to a ferromagnetic state in perovskite RMnO3 films, Physical Review B, Volume 98 (2018) no. 19 | DOI:10.1103/physrevb.98.195133
M.-A. Husanu; C. A. F. Vaz Spectroscopic Characterisation of Multiferroic Interfaces, Spectroscopy of Complex Oxide Interfaces, Volume 266 (2018), p. 245 | DOI:10.1007/978-3-319-74989-1_10
R. Eremina; Z. Seidov; I. Ibrahimov; M. Najafzade; M. Aljanov; D. Mamedov; T. Gavrilova; I. Gilmutdinov; V. Chichkov; N. Andreev Magnetization of manganite thin films on ferroelectric substrates, Journal of Magnetism and Magnetic Materials, Volume 440 (2017), p. 179 | DOI:10.1016/j.jmmm.2016.12.108
H P Martins; R J O Mossanek; X Martí; F Sánchez; J Fontcuberta; M Abbate Mn 3dbands and Y–O hybridization of hexagonal and orthorhombic YMnO3thin films, Journal of Physics: Condensed Matter, Volume 29 (2017) no. 29, p. 295501 | DOI:10.1088/1361-648x/aa75e3
Kenta Shimamoto; Saumya Mukherjee; Nicholas S. Bingham; Anna K. Suszka; Thomas Lippert; Christof Niedermayer; Christof W. Schneider Single-axis-dependent structural and multiferroic properties of orthorhombic RMnO3(R=Gd–Lu), Physical Review B, Volume 95 (2017) no. 18 | DOI:10.1103/physrevb.95.184105
Shiqing Deng; Shaobo Cheng; Ming Liu; Jing Zhu Modulating Magnetic Properties by Tailoring In-Plane Domain Structures in Hexagonal YMnO3 Films, ACS Applied Materials Interfaces, Volume 8 (2016) no. 38, p. 25379 | DOI:10.1021/acsami.6b08024
Eric Bousquet; Andrés Cano Non-collinear magnetism in multiferroic perovskites, Journal of Physics: Condensed Matter, Volume 28 (2016) no. 12, p. 123001 | DOI:10.1088/0953-8984/28/12/123001
Maged F. Bekheet; Ingrid Svoboda; Na Liu; Lkhamsuren Bayarjargal; Elisabeth Irran; Christian Dietz; Robert W. Stark; Ralf Riedel; Aleksander Gurlo Ferroelectric InMnO3: Growth of single crystals, structure and high-temperature phase transitions, Journal of Solid State Chemistry, Volume 241 (2016), p. 54 | DOI:10.1016/j.jssc.2016.05.031
Artur Glavic; Hemant Dixit; Valentino R. Cooper; Adam A. Aczel Constructing a magnetic handle for antiferromagnetic manganites, Physical Review B, Volume 93 (2016) no. 14 | DOI:10.1103/physrevb.93.140413
A.J.C. Buurma; G.R. Blake; T.T.M. Palstra; U. Adem Multiferroic Materials: Physics and Properties, Reference Module in Materials Science and Materials Engineering (2016) | DOI:10.1016/b978-0-12-803581-8.09245-6
Hongzhuang Pang; Fengyuan Zhang; Min Zeng; Xingsen Gao; Minghui Qin; Xubing Lu; Jinwei Gao; Jiyan Dai; Qiliang Li Preparation of epitaxial hexagonal YMnO3 thin films and observation of ferroelectric vortex domains, npj Quantum Materials, Volume 1 (2016) no. 1 | DOI:10.1038/npjquantmats.2016.15
Ni Hu; Chengliang Lu; Zhengcai Xia; Rui Xiong; Pengfei Fang; Jing Shi; Jun-Ming Liu Multiferroicity and Magnetoelectric Coupling in TbMnO3 Thin Films, ACS Applied Materials Interfaces, Volume 7 (2015) no. 48, p. 26603 | DOI:10.1021/acsami.5b08091
C A F Vaz; U Staub Magnetoelectronics—electric field control of magnetism in the solid state, Journal of Physics: Condensed Matter, Volume 27 (2015) no. 50, p. 500301 | DOI:10.1088/0953-8984/27/50/500301

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