Plan
Comptes Rendus

Corrigendum to “A time-resolved study of the multiphase chemistry of excited carbonyls: Imidazole-2-carboxaldehyde and halides” [C. R. Chimie 17 (7–8) (2014) 801–807; doi:10.1016/j.crci.2014.03.008]
Comptes Rendus. Chimie, Volume 18 (2015) no. 4, p. 468.
Métadonnées
Publié le :
DOI : 10.1016/j.crci.2015.01.012
Liselotte Tinel 1 ; Stéphane Dumas 1 ; Christian George 1

1 Université de Lyon-1, CNRS, UMR5256, IRCELYON, Institut de recherche sur la catalyse et l’environnement de Lyon, 69626 Lyon, France
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     author = {Liselotte Tinel and St\'ephane Dumas and Christian George},
     title = {Corrigendum to {{\textquotedblleft}A} time-resolved study of the multiphase chemistry of excited carbonyls: {Imidazole-2-carboxaldehyde} and halides{\textquotedblright} {[C.} {R.} {Chimie} 17 (7{\textendash}8) (2014) 801{\textendash}807; doi:10.1016/j.crci.2014.03.008]},
     journal = {Comptes Rendus. Chimie},
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Liselotte Tinel; Stéphane Dumas; Christian George. Corrigendum to “A time-resolved study of the multiphase chemistry of excited carbonyls: Imidazole-2-carboxaldehyde and halides” [C. R. Chimie 17 (7–8) (2014) 801–807; doi:10.1016/j.crci.2014.03.008]. Comptes Rendus. Chimie, Volume 18 (2015) no. 4, p. 468. doi : 10.1016/j.crci.2015.01.012. https://comptes-rendus.academie-sciences.fr/chimie/articles/10.1016/j.crci.2015.01.012/

Version originale du texte intégral

Imidazole-2-carboxaldehyde (IC) reactivity in the presence of halide anions (Cl, Br, I) has been studied by laser flash photolysis in aqueous solution at room temperature. Iodide anions showed to be efficient quenchers of triplet state IC. We suggest that this type of quenching reaction is a driving force of oxidation reactions in the oceanic surface micro-layer (SML) and a source of halogen atoms in the atmosphere.

This study has been funded by the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement 290852–AIRSEA.


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