Comptes Rendus
Photonique moleculaire : matériaux, physique et composants/Molecular photonics: materials, physics and devices
Organic photovoltaic materials and devices
Comptes Rendus. Physique, Volume 3 (2002) no. 4, pp. 523-542.

Les cellules solaires photovoltaïques organiques sont porteuses d'un potentiel de développement important dans la recherche de modules bas coût pour la production d'électricité domestique. Nous examinons les principes et techniques nécessaires à leur développement : les semi-conducteurs organiques, leurs propriétés de transport et leurs caractéristiques photo-physiques, les matériaux photovoltaı̈ques organiques, la technologie des dispositifs, le comportement électrique et optique des cellules, l'état de l'art, les limitations et les perspectives. Malgré de récents records, la recherche sur les cellules solaires organiques en est toujours à ses débuts lorsqu'on la compare au silicium en termes de performances en stabilité et en efficacité. Un rendement solaire nominal voisin de 10 % sera l'objectif des recherches pour les années qui viennent.

Organic photovoltaic solar cells bere an important potential of development in the search for low-cost modules for the production of domestic electricity. We review the principles and techniques needed for their development: organic semiconductors, their transport properties and photophysical characteristics, photovoltaic molecule and polymer structures, device technologies, electrical and optical behaviour of the cells, state of the art, limitations and perspectives. Despite some recent record efficiencies, research on organic solar cells is still in its infancy when stability and efficiency have to be compared with the performances of silicon cells. A nominal 10% solar efficiency is the research target for the next few years.

Accepté le :
Publié le :
DOI : 10.1016/S1631-0705(02)01335-X
Keywords: photovoltaic solar cell, organic semiconductor, molecular engineering, photogeneration
Mots clés : cellule solaire photovoltaïque, semi-conducteur organique, ingénierie moléculaire, photo-génération
Jean-Michel Nunzi 1

1 ERT Cellules solaires photovoltaïques plastiques, Laboratoire POMA, UMR-CNRS 6136, Université d'Angers, 2, boulevard Lavoisier, 49045 Angers, France
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Jean-Michel Nunzi. Organic photovoltaic materials and devices. Comptes Rendus. Physique, Volume 3 (2002) no. 4, pp. 523-542. doi : 10.1016/S1631-0705(02)01335-X. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/S1631-0705(02)01335-X/

[1] C.W. Tang Two-layer organic photovoltaic cell, Appl. Phys. Lett., Volume 48 (1986), p. 183

[2] J.H. Schön; Ch. Kloc; B. Batlogg Efficient photovoltaic energy conversion in pentacene-based heterojunctions, Appl. Phys. Lett., Volume 77 (2000), p. 2473

[3] P. Le Barny; V. Dentan; H. Facoetti; M. Vergnolle; G. Vériot; B. Servet C. R. Acad. Sci. Paris Sér. IV, 1 (2000), p. 493

[4] J. Kalinowski Electroluminescence in organics, J. Phys. D, Volume 32 (1999), p. R179

[5] J. Simon; J.-J. André Molecular Semiconductors: Photoelectrical Properties and Solar Cells, Springer, 1985

[6] K. Petritsch, Organic solar cell architectures, PhD thesis, Graz, 2000

[7] T. Dantas de Morais; F. Chaput; J.-P. Boilot; K. Lahlil; B. Darracq; Y. Lévy C. R. Acad. Sci. Paris Sér. IV, 1 (2000), p. 479

[8] K. Müllen; G. Wegner Electronic Materials: The Oligomer Approach, Wiley–VCH, Weinheim, 1998

[9] M. Halim; J.N.G. Pillow; I.D.W. Samuel; P.L. Burn Adv. Mater., 11 (1999), p. 371

[10] J. Kido; K. Hongawa; K. Okuyama; K. Nagai Appl. Phys. Lett., 64 (1994), p. 815

[11] Z.L. Zhang; X.Y. Jiang; S.H. Xu; T. Nagatomo Organic Electroluminescent Materials and Devices (S. Miyata; H.S. Nalwa, eds.), Gordon and Breach, Amsterdam, 1997, p. 203

[12] E. Gautier-Thianche; C. Sentein; A. Lorin; C. Denis; P. Raimond; J.M. Nunzi J. Appl. Phys., 83 (1998), p. 4236

[13] F. Cacialli; R.H. Friend; C.-M. Bouche; P. Le Barny; H. Facoetti; F. Soyer; P. Robin J. Appl. Phys., 83 (1998), p. 2343

[14] X. Jiang; R.A. Register; K.A. Killeen; M.E. Thompson; F. Pschenitzka; J.C. Sturm Chem. Mater., 12 (2000), p. 2542

[15] I. Seguy; P. Destruel; H. Bock An all-columnar bilayer light-emitting diode, Synth. Met., Volume 111–112 (2000), p. 15

[16] S.F.J. Appleyard; S.R. Day; R.D. Pickford; M.R. Willis J. Mater. Chem., 10 (2000), p. 169

[17] J. Kim; K.G. Chitibabu; M.J. Cazeca; W. Kim; J. Kumar; S.K. Tripathy Optical, and Magnetic Properties of Organic Solid-State Materials V, Materials Research Society Symposium Proceedings, 488, MRS, Boston, 1997, p. 527

[18] V. Cimrova; M. Remmers; D. Neher; G. Wegner Adv. Mater., 8 (1996), p. 146

[19] A. Wu; T. Fujuwara; M. Jikei; M.-A. Kakimoto; Y. Imai; T. Kubota; M. Iwamoto Thin Solid. Films, 284-285 (1996), p. 901

[20] H. Tokuhisa; M. Era; T. Tsutsui Appl. Phys. Lett., 72 (1998), p. 2639

[21] E. Arias-Marin; J.C. Arnault; D. Guillon; T. Maillou; J. Le Moigne; B. Geffroy; J.M. Nunzi Langmuir, 16 (2000), p. 4309

[22] F. Nuesch; L. Si-Ahmed; B. François; L. Zuppiroli Adv. Mater., 9 (1997), p. 222

[23] F. Papadimitrakopoulos; X.M. Zhang; K.A. Higginson IEEE Proceedings, 4 (1998) no. 1

[24] H.J. Wagner; R.O. Loufty; C. Hsio J. Mater. Sci., 17 (1982), p. 2780

[25] V. Dentan; M. Vergnolle; H. Facoetti; G. Vériot C. R. Acad. Sci. Paris Sér. IV, 1 (2000), p. 425

[26] L. Salem The Molecular Orbital Theory of Conjugated Systems, Benjamin, New York, 1966

[27] A. Moliton Les sources de lumière, traité d'optoélectronique (J.P. Goure, ed.), Hermes, Paris, 2001

[28] F. Charra; D. Fichou; J.M. Nunzi; N. Pfeffer Chem. Phys. Lett., 192 (1992), p. 566

[29] J.M. Nunzi; N. Pfeffer; F. Charra; T.P. Nguyen; V.H. Tran Nonlinear Opt., 10 (1995), p. 273

[30] N. Kirova; S. Barzovskii; A.R. Bishop Synth. Met., 100 (1999), p. 29

[31] C. Kittel Introduction à la physique de l'état solide, Bordas, Paris, 1972

[32] C. Cojan; G.P. Agrawal; C. Flytzanis Phys. Rev. B, 15 (1977), p. 909

[33] P.W. Su; J.R. Schrieffer; A.L. Heeger Phys. Rev. Lett., 42 (1979), p. 1698

[34] J.L. Brédas; R.R. Chance; R. Silbey; G. Nicolas; P. Durand J. Chem. Phys., 77 (1982), p. 371

[35] G. Leising; S. Tasch; W. Graupner Handbook of Conducting Polymers (T.A. Skotheim, ed.), M. Dekker, 1998 (Chapter 30)

[36] J. Lange; H. Bässler Phys. Stat. Sol. B, 114 (1982), p. 561

[37] J.H. Schön; C. Kloc; A. Dodabalapur; B. Batlogg Science, 289 (2000), p. 599

[38] M. Schott C. R. Acad. Sci. Paris Sér. IV, 1 (2000), p. 381

[39] D. Emin (T.A. Skotheim, ed.), Handbook of Conducting Polymers, 2, M. Dekker, 1996 (Chapter 26)

[40] W.D. Gill Photoconductivity and Related Phenomena (J. Mort; D.M. Pai, eds.), Elsevier, 1976, p. 63

[41] R.G. Kepler; P.M. Beeson; S.J. Jacobs; R.A. Anderson; M.B. Sinclair; V.S. Valencia; P.A. Cahill Appl. Phys. Lett., 66 (1995), p. 3618

[42] G. Horowitz Adv. Mater., 10 (1998), p. 365

[43] P.W.M. Blom; M.J.M. De Jong; J.J.M. Vleggaar Appl. Phys. Lett., 68 (1996), p. 3308

[44] H.C.F. Martens; J.N. Huiberts; P.W.M. Blom Appl. Phys. Lett., 77 (2000), p. 1852

[45] M. Reddecker; D.D.C. Bradley; M. Inbasekaran; E.P. Woo Appl. Phys. Lett., 74 (1999), p. 1400

[46] H. Scher Photoconductivity and Related Phenomena (J. Mort; D.M. Pai, eds.), Elsevier, 1976, p. 63

[47] M.N. Bussac; L. Zuppiroli Phys. Rev. B, 55 (1997), p. 15587

[48] J.H. Schön; C. Kloc; R.C. Haddon; B. Batlogg Science, 288 (2000), p. 656

[49] J.H. Schön; S. Berg; C. Kloc; B. Batlogg Science, 287 (2000), p. 1022

[50] G. Juska; K. Arlauskas; R. Osterbacka; H. Stubb Synth. Met., 109 (2000), p. 173

[51] H. Sirringhaus; P.J. Brown; R.H. Friend; M.M. Nielsen; K. Bechgaard; B.M.W. Langeveld-Voss; A.J.H. Spiering; R.A.J. Janssen; E.W. Meijer Synth. Met., 111–112 (2000), p. 129

[52] J.H. Schön; A. Dodabalapur; Z. Bao; Ch. Kloc; O. Schenker; B. Batlogg Nature, 410 (2001), p. 189

[53] G.G. Malliaras; Y. Shen; D.H. Dunlap; H. Murata; Z.H. Kafafi Appl. Phys. Lett., 79 (2001), p. 2582

[54] A.R. Inigo; C.H. Tan; W. Fann; Y.-S. Huang; G.-Y. Perng; S.-A. Chen Adv. Mater., 13 (2001), p. 504

[55] C. Sentein; C. Fiorini; A. Lorin; J.M. Nunzi Adv. Mater., 9 (1997), p. 809

[56] H. Murata; G.G. Malliaras; M. Uchida; Y. Shen; Z.H. Kafafi Chem. Phys. Lett., 339 (2001), p. 161

[57] H. Kageyama; K. Ohnishi; S. Nomura; Y. Shirota Chem. Phys. Lett., 277 (1997), p. 137

[58] J. Turro Modern Molecular Photochemistry, University Science Books, Mill Valley, CA, 1991

[59] U. Mitschke; P. Bäuerle J. Mater. Chem., 10 (2000), p. 1471

[60] R.E. Martin; F. Geneste; A.B. Holmes C. R. Acad. Sci. Paris Sér. IV, 1 (2000), p. 447

[61] J. Roncali Chem. Rev., 97 (1997), p. 173

[62] Les Composants Electroniques Organiques, États-Unis Microélectronique 24 (2001)

[63] D. Godovsky; L. Chen; L. Pettersson; O. Inganas; M.R. Andersson; J.C. Hummelen The use of combinatorial materials development for polymer solar cells, Adv. Mater. Opt. Electron., Volume 10 (2000), p. 47

[64] N.S. Sariciftci Polymeric photovoltaic materials, Current Opinion Solid State Mater. Sci., Volume 4 (1999), p. 373

[65] K.Y. Law Organic photoconductive materials: recent trends and developments, Chem. Rev., Volume 93 (1993), p. 449

[66] G.A. Chamberlain Organic solar cells: a review, Solar Cells, Volume 8 (1983), p. 47

[67] L. Sicot, Étude et réalisation de cellules photovoltaïques en polymère, PhD thesis, Orsay, 1999

[68] J. Rostalski; D. Meissner Monochromatic versus solar efficiencies of organic solar cells, Solar Energy Mater. Solar Cells, Volume 61 (2000), p. 87

[69] S.M. Sze Physics of Semiconductor Devices, Wiley, 1981

[70] A. Ricaud Photopiles solaires, Presses polytechniques et universitaires romandes, 1997

[71] T. Tsuzuki; Y. Shirota; J. Rostalski; D. Meissner The effect of fullerene doping on photoelectric conversion using titanyl phthalocyanine and a perylene pigment, Solar Energy Mater. Solar Cells, Volume 61 (2000), p. 1

[72] T. Fromherz; F. Padinger; D. Gebeyehu; C. Brabec; J.C. Hummelen; N.S. Sariciftci Comparison of photovoltaic devices containing various blends of polymer and fullerene derivatives, Solar Energy Mater. Solar Cells, Volume 63 (2000), p. 61

[73] L. Schmidt-Mende; A. Fechtenkötter; K. Müllen; E. Moons; R.H. Friend; J.D. MacKenzie Self-organized discotic liquid crystals for high-efficiency organic photovoltaics, Science, Volume 293 (2001), p. 1119

[74] T. Stuebinger; W. Bruetting Exciton diffusion and optical interference in organic donor–acceptor photovoltaic cells, J. Appl. Phys., Volume 90 (2001), p. 3623

[75] P. Peumans; S.R. Forrest Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells, Appl. Phys. Lett., Volume 79 (2001), p. 126

[76] M. Pope; E. Swenberg Electronic Processes in Organic Crystals, Clarendon Press, Oxford, 1982

[77] D. Wöhrle; D. Meissner Adv. Mater., 3 (1991), p. 129

[78] M. Granstrom; K. Petritsch; A.C. Arias; A. Lux; M.R. Andersson; R.H. Friend Laminated fabrication of polymeric photovoltaic diodes, Nature, Volume 395 (1998), p. 257

[79] D. Meissner Plastic solar cell, Photon, Volume 2 (1999)

[80] J. Rostalski; D. Meissner Photocurrent spectroscopy for the investigation of charge carrier generation and transport mechanisms in organic p/n-junction solar cells, Solar Energy Mater. Solar Cells, Volume 63 (2000), p. 37

[81] J.H. Schön; Ch. Kloc; E. Bucher; B. Batlogg Efficient organic photovoltaic diodes based on doped pentacene, Nature, Volume 403 (2000), p. 408

[82] L. Sicot; B. Geffroy; A. Lorin; P. Raimond; C. Sentein; J.-M. Nunzi Photovoltaic properties of Schottky and pn type solar cells based on polythiophene, J. Appl. Phys., Volume 90 (2001), p. 1047

[83] M. Pfeiffer; A. Beyer; T. Fritz; K. Leo Controlled doping of phthalocyanine layers by cosublimation with acceptor molecules: A systematic Seebeck and conductivity study, Appl. Phys. Lett., Volume 73 (1998), p. 3202

[84] I. Seguy; R. Mamy; P. Destruel; P. Jolinat; H. Bock Photoemission study of the ITO/triphenylene/perylene/Al interfaces, Appl. Surf. Sci., Volume 174 (2001), p. 310

[85] S.-G. Liu; G. Sui; R.A. Cormier; R.M. Leblanc; B.A. Gregg Self-organizing liquid crystal perylene diimide thin films: spectroscopy, crystallinity, and molecular orientation, J. Phys. Chem. B, Volume 106 (2002), p. 1307

[86] A.-J. Attias; C. Cavalli; B. Donnio; D. Guillon; P. Hapiot; J. Malthête Columnar mesophase from a new disclike mesogen based on a 3,5-dicyano-2,4,6-tristyrylpyridine core, Chem. Mater., Volume 14 (2002), p. 375

[87] B. O'Regan; M. Grätzel Nature, 353 (1991), p. 737

[88] N.S. Sariciftci; L. Smilowitz; A.J. Heeger; F. Wudl Science, 258 (1992), p. 1474

[89] C.J. Brabec; N.S. Sariciftci; J.C. Hummelen Plastic solar cells, Adv. Funct. Mater., Volume 11 (2001), p. 15

[90] J. Liu; Y. Shi; Y. Yang Solvation-induced morphology effects on the performance of polymer-based photovoltaic devices, Adv. Funct. Mater., Volume 11 (2001), p. 420

[91] J.-F. Eckert; J.-F. Nicoud; J.-F. Nierengarten; S.-G. Liu; L. Echegoyen; F. Barigelletti; N. Armaroli; L. Ouali; V. Krasnikov; G. Hadziioannou Fullerene – Oligophenylenevinylene hybrids: synthesis, electronic properties, and incorporation in photovoltaic devices, J. Am. Chem. Soc., Volume 122 (2000), p. 7467

[92] M. Angeles Herranz; N. Martin A new building block for diels-alder reactions in p-extended tetrathiafulvalenes: synthesis of a novel electroactive C60-based dyad, Organ. Lett., Volume 1 (1999), p. 2005

[93] H. Neugebauer; C. Brabec; J.C. Hummelen; N.S. Sariciftci Stability and photodegradation mechanisms of conjugated polymer/fullerene plastic solar cells, Solar Energy Mater. Solar Cells, Volume 61 (2000), p. 35

[94] J.S. Miller Interpenetrating lattices – materials of the future, Adv. Mater., Volume 13 (2001), p. 525

[95] A.C. Arango; L.R. Johnson; V.N. Bliznyuk; Z. Schlesinger; S.A. Carter; H.-H. Hörhold Efficient titanium oxide/conjugated polymer photovoltaics for solar energy conversion, Adv. Mater., Volume 12 (2000), p. 1689

[96] X. Peng; L. Manna; W. Yang; J. Wickham; E. Scher; A. Kadavanich; A.P. Alivisatos Shape control of CdSe nanocrystals, Nature, Volume 404 (2000), p. 59

[97] W.U. Huynh; J.J. Dittmer; A.P. Alivisatos Hybrid nanorod–polymer solar cells, Science, Volume 295 (2002), p. 2425

[98] C. Sentein, C. Fiorini, A. Lorin, J.M. Nunzi, Dispositif semiconducteur en polymère comportant au moins une fonction redresseuse et procédé de fabrication d'un tel dispositif, European Patent, 1997

[99] C. Sentein; C. Fiorini; A. Lorin; L. Sicot; J.-M. Nunzi Study of orientation induced molecular rectification in polymer films, Opt. Mater., Volume 9 (1998), p. 316

[100] L. Sicot; C. Fiorini; A. Lorin; P. Raimond; C. Sentein; J.-M. Nunzi Improvement of the photovoltaic properties of polythiophene-based cells, Solar Energy Mater. Solar Cells, Volume 63 (2000), p. 49

[101] C. Sentein; C. Fiorini; A. Lorin; J.M. Nunzi; P. Raimond; L. Sicot Poling induced improvement of organic-polymer device efficiency, Synth. Met., Volume 102 (1999), pp. 989-990

[102] J.-M. Nunzi; C. Sentein; C. Fiorini; A. Lorin; P. Raimond Oriented polymer photovoltaic cells, SPIE Proc., 4108, 2001, p. 41

[103] M. Yahiro; D. Zou; T. Tsutsui Recoverable degradation phenomena of quantum efficiency in organic EL devices, Synth. Met., Volume 111–112 (2000), p. 245

[104] J.M. Kroon; M.M. Wienk; W.J.H. Verhees; J.C. Hummelen Accurate efficiency determination and stability studies of conjugated polymer/fullerene solar cells, Thin Solid Films, Volume 403–404 (2002), p. 223

[105] E. Gautier; A. Lorin; J.M. Nunzi; A. Schalchli; J.J. Benattar; D. Vital Electrode interface effects on ITO/polymer/metal light emitting diodes, Appl. Phys. Lett., Volume 69 (1996), p. 1071

[106] A. Goetzberger; C. Hebling Photovoltaic materials, past, present, future, Solar Energy Mat. Solar Cells, Volume 62 (2000), p. 1

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