Growth and characterizations of lead-free ferroelectric KNN-based crystals

Mythili Prakasam; Philippe Veber; Oudomsack Viraphong; Laetitia Etienne; Michel Lahaye; Stanislav Pechev; Eric Lebraud; Kiyoshi Shimamura; Mario Maglione

doi:10.1016/j.crhy.2012.10.002

Growth and characterizations of lead-free ferroelectric KNN-based crystals
[Cristallogenèse et caractérisations de monocristaux ferroélectriques sans plomb à base de KNN]

Mythili Prakasam ¹ ; Philippe Veber ¹ ; Oudomsack Viraphong ¹ ; Laetitia Etienne ¹ ; Michel Lahaye ¹ ; Stanislav Pechev ¹ ; Eric Lebraud ¹ ; Kiyoshi Shimamura ² ; Mario Maglione ¹

¹ ICMCB Université de Bordeaux, CNRS, 87, avenue du Docteur-Albert-Schweitzer, 33608 Pessac cedex, France
² National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan

Comptes Rendus. Physique, Crystal growth / Croissance cristalline, Volume 14 (2013) no. 2-3, pp. 133-140.

Résumé
Abstract

Des monocristaux centimétriques issus du système Li₂O–Na₂O–K₂O–Nb₂O₅–Ta₂O₅–Sb₂O₃ ont été obtenus par la méthode des flux. Les cristaux de composition (Li_0.023Na_0.583K_0.394)(Nb_0.925Ta_0.037Sb_0.038)O₃ et (Li_0.034Na_0.609K_0.357)(Nb_0.896Ta_0.047Sb_0.057)O₃ ont été caractérisés par diffraction des rayons X et se sont avérés appartenir au système quadratique. Leur comportement ferroélectrique spécifique a été confirmé par des mesures diélectriques. Une telle flexibilité des propriétés ferroélectriques de ces cristaux pour de faibles variations de composition ouvre la voie vers une meilleure compréhension des relations entre la structure et la polarisation dans ces solutions solides, qui sont potentiellement une alternative aux matériaux contenant du plomb.

We have grown by flux method centimeter-sized single crystals from pseudo-hexanary Li₂O–Na₂O–K₂O–Nb₂O₅–Ta₂O₅–Sb₂O₃ system. Based on chemical analysis, crystals of compositions (Li_0.023Na_0.583K_0.394)(Nb_0.925Ta_0.037Sb_0.038)O₃ and (Li_0.034Na_0.609K_0.357)(Nb_0.896Ta_0.047Sb_0.057)O₃ were characterized by X-rays diffraction which revealed a tetragonal structure. The dielectric analysis confirmed that the ferroelectric behavior of these crystals is very sensitive to little changes in composition as previously observed on ceramics. Such high flexibility of the ferroelectric properties in crystals opens the way towards improved understanding of the relations between structure and polarization in solid solutions which may be an alternative to the lead-based materials.

Publié le : 2013-02-01

DOI : 10.1016/j.crhy.2012.10.002

Keywords: High temperature solution growth, Inorganic compound, Ferroelectric materials
Mots-clés : Cristallogenèse, Solution hautes températures, Composés inorganiques, Matériaux ferroélectriques

Affiliations des auteurs :

Mythili Prakasam ¹ ; Philippe Veber ¹ ; Oudomsack Viraphong ¹ ; Laetitia Etienne ¹ ; Michel Lahaye ¹ ; Stanislav Pechev ¹ ; Eric Lebraud ¹ ; Kiyoshi Shimamura ² ; Mario Maglione ¹

¹ ICMCB Université de Bordeaux, CNRS, 87, avenue du Docteur-Albert-Schweitzer, 33608 Pessac cedex, France
² National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan

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     title = {Growth and characterizations of lead-free ferroelectric {KNN-based} crystals},
     journal = {Comptes Rendus. Physique},
     pages = {133--140},
     publisher = {Elsevier},
     volume = {14},
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     year = {2013},
     doi = {10.1016/j.crhy.2012.10.002},
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Mythili Prakasam; Philippe Veber; Oudomsack Viraphong; Laetitia Etienne; Michel Lahaye; Stanislav Pechev; Eric Lebraud; Kiyoshi Shimamura; Mario Maglione. Growth and characterizations of lead-free ferroelectric KNN-based crystals. Comptes Rendus. Physique, Crystal growth / Croissance cristalline, Volume 14 (2013) no. 2-3, pp. 133-140. doi : 10.1016/j.crhy.2012.10.002. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2012.10.002/

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