Comptes Rendus
no. S1
Vibrations and Heat Transfer in Glasses: The Role Played by Disorder
[Vibrations et transferts de chaleur dans les verres : le rôle du désordre]
Anne Tanguy1, 2
1 Univ. Lyon, INSA Lyon, CNRS, LaMCoS, UMR5259, Villeurbanne, 69621, France
2 ONERA, University Paris-Saclay, Chemin de la Hunière, BP 80100, Palaiseau, 92123, France
Comptes Rendus. Physique, Volume 24 (2023) no. S1, pp. 73-97.

Les matériaux amorphes se distinguent aussi des cristaux par leurs propriétés thermiques. Le désordre structural semble être responsable à la fois d’une augmentation importante de la capacité calorifique par rapport aux cristaux de même composition, mais aussi d’une diminution importante de la conductivité thermique. La dépendance en température de la conductivité thermique, inhabituelle pour les interprétations usuelles de la physique du solide, a fait couler beaucoup d’encre. Nous passons en revue dans cet article différentes interprétations de la conductivité thermique dans les matériaux amorphes. Nous montrons que la dépendance en température dans les matériaux diélectriques peut aussi être comprise à l’aide de l’effet du désordre structural sur les modes propres de vibration.

Amorphous materials are also distinguished from crystals by their thermal properties. The structural disorder seems to be responsible both for a significant increase in heat capacity compared to crystals of the same composition, but also for a significant decrease in thermal conductivity. The temperature dependence of thermal conductivity, unusual for common interpretations of solid-state physics, gave rise to a lot of debates. We review in this article different interpretations of thermal conductivity in amorphous materials. We show finally that the temperature dependence of thermal conductivity in dielectric materials can be understood by relating it to the disorder-dependent harmonic vibrational eigenmodes.

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DOI : 10.5802/crphys.162
Keywords: amorphous materials, glasses, acoustic attenuation, thermal Properties, thermo-mechanical behaviour, plasticity
Mot clés : matériaux amorphes, verres, atténuation acoustique, propriétés thermiques, comportement thermo-mécanique, plasticité
Anne Tanguy 1, 2

1 Univ. Lyon, INSA Lyon, CNRS, LaMCoS, UMR5259, Villeurbanne, 69621, France
2 ONERA, University Paris-Saclay, Chemin de la Hunière, BP 80100, Palaiseau, 92123, France
Licence : CC-BY 4.0
Droits d'auteur : Les auteurs conservent leurs droits 
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Anne Tanguy. Vibrations and Heat Transfer in Glasses: The Role Played by Disorder. Comptes Rendus. Physique, Volume 24 (2023) no. S1, pp. 73-97. doi : 10.5802/crphys.162. https://comptes-rendus.academie-sciences.fr/physique/articles/10.5802/crphys.162/

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