Vibrations and Heat Transfer in Glasses: The Role Played by Disorder

Anne Tanguy

doi:10.5802/crphys.162

Vibrations and Heat Transfer in Glasses: The Role Played by Disorder

Anne Tanguy ^1,²

¹ Univ. Lyon, INSA Lyon, CNRS, LaMCoS, UMR5259, Villeurbanne, 69621, France
² ONERA, University Paris-Saclay, Chemin de la Hunière, BP 80100, Palaiseau, 92123, France

Comptes Rendus. Physique, From everyday glass to disordered solids, Volume 24 (2023) no. S1, pp. 73-97.

Abstract
Résumé

Amorphous materials are also distinguished from crystals by their thermal properties. The structural disorder seems to be responsible both for a significant increase in heat capacity compared to crystals of the same composition, but also for a significant decrease in thermal conductivity. The temperature dependence of thermal conductivity, unusual for common interpretations of solid-state physics, gave rise to a lot of debates. We review in this article different interpretations of thermal conductivity in amorphous materials. We show finally that the temperature dependence of thermal conductivity in dielectric materials can be understood by relating it to the disorder-dependent harmonic vibrational eigenmodes.

Les matériaux amorphes se distinguent aussi des cristaux par leurs propriétés thermiques. Le désordre structural semble être responsable à la fois d’une augmentation importante de la capacité calorifique par rapport aux cristaux de même composition, mais aussi d’une diminution importante de la conductivité thermique. La dépendance en température de la conductivité thermique, inhabituelle pour les interprétations usuelles de la physique du solide, a fait couler beaucoup d’encre. Nous passons en revue dans cet article différentes interprétations de la conductivité thermique dans les matériaux amorphes. Nous montrons que la dépendance en température dans les matériaux diélectriques peut aussi être comprise à l’aide de l’effet du désordre structural sur les modes propres de vibration.

Received: 2023-02-27
Revised: 2023-03-01
Accepted: 2023-08-01
Online First: 2023-11-13
Published online: 2024-04-26

DOI: 10.5802/crphys.162

Keywords: amorphous materials, glasses, acoustic attenuation, thermal Properties, thermo-mechanical behaviour, plasticity
Mots-clés : matériaux amorphes, verres, atténuation acoustique, propriétés thermiques, comportement thermo-mécanique, plasticité

Author's affiliations:

Anne Tanguy ^{1, 2}

¹ Univ. Lyon, INSA Lyon, CNRS, LaMCoS, UMR5259, Villeurbanne, 69621, France
² ONERA, University Paris-Saclay, Chemin de la Hunière, BP 80100, Palaiseau, 92123, France

License:

CC-BY 4.0

Copyrights: The authors retain unrestricted copyrights and publishing rights

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     author = {Anne Tanguy},
     title = {Vibrations and {Heat} {Transfer} in {Glasses:} {The} {Role} {Played} by {Disorder}},
     journal = {Comptes Rendus. Physique},
     pages = {73--97},
     publisher = {Acad\'emie des sciences, Paris},
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     language = {en},
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Anne Tanguy. Vibrations and Heat Transfer in Glasses: The Role Played by Disorder. Comptes Rendus. Physique, From everyday glass to disordered solids, Volume 24 (2023) no. S1, pp. 73-97. doi : 10.5802/crphys.162. https://comptes-rendus.academie-sciences.fr/physique/articles/10.5802/crphys.162/

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