Comptes Rendus
Nanophotonics and near field / Nanophotonique et champ proche
Light polarization properties of three fold symmetry gold nanoparticles: Model and experiments
[Comportement à la polarisation optique de nanoparticules de symétrie dʼordre 3 : Modèle et résultats expérimentaux]
Comptes Rendus. Physique, Volume 13 (2012) no. 8, pp. 830-836.

Dans cet article, nous démontrons que toutes les nanostructures, même de géométrie complexe, qui appartiennent au groupe de symétrie ponctuel Cn avec n3 ont une réponse optique linéaire ne dépendant pas de la polarisation de la lumière incidente, si son vecteur dʼonde est parallèle à lʼaxe de symétrie Cn. Nous avons fabriqué des nanoparticules dʼor en forme de triangle et dʼétoile par lithographie électronique. Leur comportement apolaire est confirmé expérimentalement par des mesures sur les résonances plasmon et par diffusion Raman exaltée de surface.

In this study, we demonstrate that any complex nanostructure that belongs to Cn, with n3, symmetry point group for along at least one dimension displays apolar linear response to light input when the incoming wave vector is parallel to the Cn axis. Triangle and star shaped gold nanoparticles were designed and fabricated by electron beam lithography (EBL) technique. The apolar behavior of such nanostructures was experimentally confirmed by way of localized surface plasmon resonances (LSPR) properties and surface-enhanced Raman scattering (SERS) measurements.

Publié le :
DOI : 10.1016/j.crhy.2012.09.004
Keywords: Gold nanoparticles, Light polarization, Symmetry point group
Mot clés : Nanoparticules dʼor, Polarisation optique, Groupe ponctuel de symétrie

Hong Shen 1 ; Jérémy Rouxel 1, 2 ; Nicolas Guillot 3 ; Marc Lamy de la Chapelle 3 ; Timothée Toury 1

1 ICD-LNIO, UMR STMR CNRS 6279, université de technologie de Troyes, 12, rue Marie-Curie, 10000 Troyes, France
2 Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
3 Laboratoire CSPBAT UMR 7244, université Paris 13, 74, rue Marcel-Cachin, 93017 Bobigny, France
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     title = {Light polarization properties of three fold symmetry gold nanoparticles: {Model} and experiments},
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Hong Shen; Jérémy Rouxel; Nicolas Guillot; Marc Lamy de la Chapelle; Timothée Toury. Light polarization properties of three fold symmetry gold nanoparticles: Model and experiments. Comptes Rendus. Physique, Volume 13 (2012) no. 8, pp. 830-836. doi : 10.1016/j.crhy.2012.09.004. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2012.09.004/

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