Light polarization properties of three fold symmetry gold nanoparticles: Model and experiments

Hong Shen; Jérémy Rouxel; Nicolas Guillot; Marc Lamy de la Chapelle; Timothée Toury

doi:10.1016/j.crhy.2012.09.004

Nanophotonics and near field / Nanophotonique et champ proche

Light polarization properties of three fold symmetry gold nanoparticles: Model and experiments
[Comportement à la polarisation optique de nanoparticules de symétrie dʼordre 3 : Modèle et résultats expérimentaux]

Hong Shen ¹ ; Jérémy Rouxel ^1,² ; Nicolas Guillot ³ ; Marc Lamy de la Chapelle ³ ; Timothée Toury ¹

¹ ICD-LNIO, UMR STMR CNRS 6279, université de technologie de Troyes, 12, rue Marie-Curie, 10000 Troyes, France
² Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
³ Laboratoire CSPBAT UMR 7244, université Paris 13, 74, rue Marcel-Cachin, 93017 Bobigny, France

Comptes Rendus. Physique, Volume 13 (2012) no. 8, pp. 830-836.

Résumé
Abstract

Dans cet article, nous démontrons que toutes les nanostructures, même de géométrie complexe, qui appartiennent au groupe de symétrie ponctuel $C_{n}$ avec $n \geq 3$ ont une réponse optique linéaire ne dépendant pas de la polarisation de la lumière incidente, si son vecteur dʼonde est parallèle à lʼaxe de symétrie $C_{n}$ . Nous avons fabriqué des nanoparticules dʼor en forme de triangle et dʼétoile par lithographie électronique. Leur comportement apolaire est confirmé expérimentalement par des mesures sur les résonances plasmon et par diffusion Raman exaltée de surface.

In this study, we demonstrate that any complex nanostructure that belongs to $C_{n}$ , with $n \geq 3$ , symmetry point group for along at least one dimension displays apolar linear response to light input when the incoming wave vector is parallel to the $C_{n}$ axis. Triangle and star shaped gold nanoparticles were designed and fabricated by electron beam lithography (EBL) technique. The apolar behavior of such nanostructures was experimentally confirmed by way of localized surface plasmon resonances (LSPR) properties and surface-enhanced Raman scattering (SERS) measurements.

Publié le : 2012-10-01

DOI : 10.1016/j.crhy.2012.09.004

Keywords: Gold nanoparticles, Light polarization, Symmetry point group
Mot clés : Nanoparticules dʼor, Polarisation optique, Groupe ponctuel de symétrie

Affiliations des auteurs :

Hong Shen ¹ ; Jérémy Rouxel ^{1, 2} ; Nicolas Guillot ³ ; Marc Lamy de la Chapelle ³ ; Timothée Toury ¹

¹ ICD-LNIO, UMR STMR CNRS 6279, université de technologie de Troyes, 12, rue Marie-Curie, 10000 Troyes, France
² Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
³ Laboratoire CSPBAT UMR 7244, université Paris 13, 74, rue Marcel-Cachin, 93017 Bobigny, France

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     author = {Hong Shen and J\'er\'emy Rouxel and Nicolas Guillot and Marc Lamy de la Chapelle and Timoth\'ee Toury},
     title = {Light polarization properties of three fold symmetry gold nanoparticles: {Model} and experiments},
     journal = {Comptes Rendus. Physique},
     pages = {830--836},
     publisher = {Elsevier},
     volume = {13},
     number = {8},
     year = {2012},
     doi = {10.1016/j.crhy.2012.09.004},
     language = {en},
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Hong Shen; Jérémy Rouxel; Nicolas Guillot; Marc Lamy de la Chapelle; Timothée Toury. Light polarization properties of three fold symmetry gold nanoparticles: Model and experiments. Comptes Rendus. Physique, Volume 13 (2012) no. 8, pp. 830-836. doi : 10.1016/j.crhy.2012.09.004. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2012.09.004/

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