Au cours des années récentes, les techniques d'analyse spectroscopique de perte d'énergie (EELS) et d'émission X (EDX) ont été poussées jusqu'à l'identification d'atomes individuels. Nous présentons ici une sélection de résultats récents acquis en microscopie électronique à balayage en transmission (STEM) équipée pour les spectroscopies EELS et EDX, qui montrent des succès enregistrés sur des atomes uniques au sein de matériaux de basse dimensionnalité.
Recently the possibilities of chemical analysis by means of electron energy-loss spectroscopy (EELS) and energy dispersive X-ray spectroscopy (EDX) have been pushed to the single atom limit. Here we show examples for successful single-atom spectroscopy in low-dimensional materials using scanning transmission electron microscopy (STEM) together with EELS and EDX.
@article{CRPHYS_2014__15_2-3_151_0, author = {Kazu Suenaga}, title = {Elemental analysis down to the single atom with electron beams}, journal = {Comptes Rendus. Physique}, pages = {151--157}, publisher = {Elsevier}, volume = {15}, number = {2-3}, year = {2014}, doi = {10.1016/j.crhy.2013.12.003}, language = {en}, }
Kazu Suenaga. Elemental analysis down to the single atom with electron beams. Comptes Rendus. Physique, Volume 15 (2014) no. 2-3, pp. 151-157. doi : 10.1016/j.crhy.2013.12.003. https://comptes-rendus.academie-sciences.fr/physique/articles/10.1016/j.crhy.2013.12.003/
[1] Element-selective single atom imaging, Science, Volume 290 (2000), pp. 2280-2282
[2] PEELS compositional profiling and mapping at nanometer spatial resolution, Ultramicroscopy, Volume 58 (1995), pp. 42-54
[3] The microanalysis of light elements using transmitted energy loss electrons, Ultramicroscopy, Volume 1 (1975), pp. 33-52
[4] Correction of higher-order geometrical aberration by triple 3-fold astigmatism field, J. Electron Microsc., Volume 58 (2009), pp. 341-347
[5] Higher-order aberration corrector for an image-forming system in a transmission electron microscope, Ultramicroscopy, Volume 110 (2010), pp. 958-961
[6] Performance of low-voltage STEM/TEM with delta corrector and cold field emission gun, J. Electron Microsc., Volume 59 (2010), p. S7-S13 (Supplement)
[7] Visualizing and identifying single atoms using electron energy-loss spectroscopy with low accelerating voltage, Nat. Chem., Volume 1 (2009), pp. 415-418
[8] Gentle STEM: ADF imaging and EELS at low primary energies, Ultramicroscopy, Volume 110 (2010), pp. 935-945
[9] Irradiation effects in carbon nanostructures, Rep. Prog. Phys., Volume 62 (1999), pp. 1181-1221
[10] Single atom spectroscopy with reduced delocalization effect using a 30 kV STEM, Eur. Phys. J. Appl. Phys., Volume 54 (2011), p. 33508
[11] The GIF Quantum, a next generation post-column imaging filter, Ultramicroscopy, Volume 110 (2010), pp. 962-970
[12] Fabrication of a free-standing boron nitride single layer and its defects assignments, Phys. Rev. Lett., Volume 102 (2009), p. 195505
[13] Atom-by-atom structural and chemical analysis by annular dark-field electron microscopy, Nature, Volume 464 (2010), pp. 571-574
[14] Experimental analysis of charge redistribution due to chemical bonding by high-resolution transmission electron microscopy, Nat. Mater., Volume 10 (2011), pp. 209-215
[15] Core-level spectroscopy of point defects in single layer h-BN, Phys. Rev. Lett., Volume 108 (2012), p. 075501
[16] Single-layer MoS2 transistors, Nat. Nanotechnol., Volume 6 (2011), pp. 147-150
[17] Tunable band-gap photoluminescence from atomically thin transition-metal dichalcogenide alloys, ACS Nano, Volume 7 (2013), pp. 4610-4616
[18] Visualization and quantification of transition metal atomic mixing in Mo1 − xWxS2 single layers, Nat. Commun., Volume 4 (2013), p. 1351
[19] Atom-by-atom spectroscopy at graphene edge, Nature, Volume 468 (2010), pp. 1088-1090
[20] Detection of photons emitted from single Er atoms in energy-dispersive EDX spectroscopy, Nat. Photonics, Volume 6 (2012), pp. 545-548
[21] Single atom identification by energy-dispersive X-ray spectroscopy, Appl. Phys. Lett., Volume 100 (2012), p. 154101
[22] A New System of Chemical Philosophy, Strand, London, 1808 (printed by S. Russell for R. Bickerstaff)
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