The search for manganese incorporation in MoSe$_{{2}}$ monolayer epitaxially grown on graphene

Maxime Gay; Minh-Tuan Dau; Céline Vergnaud; Alain Marty; Frédéric Bonell; Hervé Boukari; Colin Paillet; Bérangère Hyot; Hanako Okuno; Pierre Mallet; Jean-Yves Veuillen; Olivier Renault; Matthieu Jamet

doi:10.5802/crphys.69

The search for manganese incorporation in MoSe

_{2}

monolayer epitaxially grown on graphene

Maxime Gay ¹ ; Minh-Tuan Dau ² ; Céline Vergnaud ² ; Alain Marty ² ; Frédéric Bonell ² ; Hervé Boukari ³ ; Colin Paillet ¹ ; Bérangère Hyot ¹ ; Hanako Okuno ⁴; Pierre Mallet ³; Jean-Yves Veuillen ³; Olivier Renault ¹ ; Matthieu Jamet ²

¹ Univ. Grenoble Alpes, CEA, Leti, F-38000 Grenoble, France
² Univ. Grenoble Alpes, CEA, CNRS, Spintec, F-38000 Grenoble, France
³ Univ. Grenoble Alpes, CNRS, Institut Néel, F-38000 Grenoble, France
⁴ Univ. Grenoble Alpes, CEA, IRIG-MEM, F-38000 Grenoble, France

Comptes Rendus. Physique, Recent advances in 2D material physics, Volume 22 (2021) no. S4, pp. 5-21.

Abstract

The introduction of magnetism in two-dimensional (2D) materials represents an intense field of research nowadays and the quest to reach above-room-temperature ordering temperatures is still underway. Intrinsic ferromagnetism was discovered in 2017 in CrI $_{3}$ and Cr $_{2}$ Ge $_{2}$ Te $_{6}$ in the monolayer form with low Curie temperatures. An alternative method to introduce magnetism into conventional 2D materials is substitutional doping with magnetic impurities similarly to three-dimensional diluted magnetic semiconductors. The case of Mn-doped transition metal dichalcogenide (MoS $_{2}$ , MoSe $_{2}$ , WS $_{2}$ , WSe $_{2}$ ) monolayers is very interesting because combining out-of-plane ferromagnetism and valley contrast leads to ferrovalley materials. In this work, we focus on the incorporation of Mn in MoSe $_{2}$ by molecular beam epitaxy on graphene which has been rarely addressed up to now. By using a multiscale characterization approach, we demonstrate that Mn atoms are incorporated into the MoSe $_{2}$ monolayer up to 5 atomic percent. However, when incorporated into the film, Mn atoms tend to diffuse to the grain edges forming undefined Mo $_{x}$ Mn $_{y}$ Se $_{z}$ phase at grain boundaries after completion of the MoSe $_{2}$ monolayer. This segregation leaves the crystalline and electronic structure of MoSe $_{2}$ unmodified. Above 5%, the saturation of Mn content in MoSe $_{2}$ leads to the formation of epitaxial MnSe clusters.

Online First: 2021-05-03
Published online: 2022-03-08

DOI: 10.5802/crphys.69

Keywords: 2D materials, Magnetic doping, Molecular beam epitaxy, Transmission electron microscopy, Scanning tunneling microscopy, Momentum resolved photoemission electron microscopy

Author's affiliations:

Maxime Gay ¹; Minh-Tuan Dau ²; Céline Vergnaud ²; Alain Marty ²; Frédéric Bonell ²; Hervé Boukari ³; Colin Paillet ¹; Bérangère Hyot ¹; Hanako Okuno ⁴; Pierre Mallet ³; Jean-Yves Veuillen ³; Olivier Renault ¹; Matthieu Jamet ²

¹ Univ. Grenoble Alpes, CEA, Leti, F-38000 Grenoble, France
² Univ. Grenoble Alpes, CEA, CNRS, Spintec, F-38000 Grenoble, France
³ Univ. Grenoble Alpes, CNRS, Institut Néel, F-38000 Grenoble, France
⁴ Univ. Grenoble Alpes, CEA, IRIG-MEM, F-38000 Grenoble, France

License:

CC-BY 4.0

Copyrights: The authors retain unrestricted copyrights and publishing rights

@article{CRPHYS_2021__22_S4_5_0,
     author = {Maxime Gay and Minh-Tuan Dau and C\'eline Vergnaud and Alain Marty and Fr\'ed\'eric Bonell and Herv\'e Boukari and Colin Paillet and B\'erang\`ere Hyot and Hanako Okuno and Pierre Mallet and Jean-Yves Veuillen and Olivier Renault and Matthieu Jamet},
     title = {The search for manganese incorporation {in~MoSe}$_{{2}}$ monolayer epitaxially grown on graphene},
     journal = {Comptes Rendus. Physique},
     pages = {5--21},
     publisher = {Acad\'emie des sciences, Paris},
     volume = {22},
     number = {S4},
     year = {2021},
     doi = {10.5802/crphys.69},
     language = {en},
}

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AU  - Maxime Gay
AU  - Minh-Tuan Dau
AU  - Céline Vergnaud
AU  - Alain Marty
AU  - Frédéric Bonell
AU  - Hervé Boukari
AU  - Colin Paillet
AU  - Bérangère Hyot
AU  - Hanako Okuno
AU  - Pierre Mallet
AU  - Jean-Yves Veuillen
AU  - Olivier Renault
AU  - Matthieu Jamet
TI  - The search for manganese incorporation in MoSe$_{{2}}$ monolayer epitaxially grown on graphene
JO  - Comptes Rendus. Physique
PY  - 2021
SP  - 5
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VL  - 22
IS  - S4
PB  - Académie des sciences, Paris
DO  - 10.5802/crphys.69
LA  - en
ID  - CRPHYS_2021__22_S4_5_0
ER  -

%0 Journal Article
%A Maxime Gay
%A Minh-Tuan Dau
%A Céline Vergnaud
%A Alain Marty
%A Frédéric Bonell
%A Hervé Boukari
%A Colin Paillet
%A Bérangère Hyot
%A Hanako Okuno
%A Pierre Mallet
%A Jean-Yves Veuillen
%A Olivier Renault
%A Matthieu Jamet
%T The search for manganese incorporation in MoSe$_{{2}}$ monolayer epitaxially grown on graphene
%J Comptes Rendus. Physique
%D 2021
%P 5-21
%V 22
%N S4
%I Académie des sciences, Paris
%R 10.5802/crphys.69
%G en
%F CRPHYS_2021__22_S4_5_0

Maxime Gay; Minh-Tuan Dau; Céline Vergnaud; Alain Marty; Frédéric Bonell; Hervé Boukari; Colin Paillet; Bérangère Hyot; Hanako Okuno; Pierre Mallet; Jean-Yves Veuillen; Olivier Renault; Matthieu Jamet. The search for manganese incorporation in MoSe$_{{2}}$ monolayer epitaxially grown on graphene. Comptes Rendus. Physique, Recent advances in 2D material physics, Volume 22 (2021) no. S4, pp. 5-21. doi : 10.5802/crphys.69. https://comptes-rendus.academie-sciences.fr/physique/articles/10.5802/crphys.69/

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