Reactivity of the tethered alkyl uranium bonds of (η5:κ1-C5Me4SiMe2CH2)2U

William J. Evans; Nathan A. Siladke; Joseph W. Ziller

doi:10.1016/j.crci.2010.02.003

Reactivity of the tethered alkyl uranium bonds of (η⁵:κ¹-C₅Me₄SiMe₂CH₂)₂U

William J. Evans ¹ ; Nathan A. Siladke ¹ ; Joseph W. Ziller ¹

¹ Department of Chemistry, University of California, Irvine, California 92697-2025, United States

Comptes Rendus. Chimie, La vitalité de la chimie de coordination des éléments f, Volume 13 (2010) no. 6-7, pp. 775-780.

Résumé

Uranium-carbon bond reactivity has been investigated with the bis(tethered silylalkyl) uranium metallocene (η⁵:κ¹-C₅Me₄SiMe₂CH₂)₂U, 1. Tert-butyl nitrile, ^tBuCN, inserts into both of the tethered U-C bonds to produce the bis(tethered ketimide) complex [η⁵:κ¹-C₅Me₄SiMe₂CH₂C(^tBu)N]₂U, 2, which has unusually bent U-N-C bond angles. Carbon dioxide also inserts into both U-C bonds of 1 yielding the bis(tethered carboxylate) (C₅Me₄SiMe₂CH₂CO₂)₂U, 3. Neither PhCCPh nor PhCCH insert into the U-C bonds, but PhCCH cleaves the silylalkyl tethers in 1 to generate (C₅Me₄SiMe₃)¹⁻ ligands in the complex (C₅Me₄SiMe₃)₂U(CCPh)₂, 4.

Supplementary Materials:
Supplementary material for this article is supplied as a separate file:

mmc1.pdf

Métadonnées

Reçu le : 2009-12-29
Accepté le : 2010-02-09
Publié le : 2010-03-26

DOI : 10.1016/j.crci.2010.02.003

Keywords: Uranium, Cyclopentadienyl ligands, Insertion, Alkyl ligands, Metallocene

Affiliations des auteurs :

William J. Evans ¹ ; Nathan A. Siladke ¹ ; Joseph W. Ziller ¹

¹ Department of Chemistry, University of California, Irvine, California 92697-2025, United States

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     author = {William J. Evans and Nathan A. Siladke and Joseph W. Ziller},
     title = {Reactivity of the tethered alkyl uranium bonds of {(\protect\emph{\ensuremath{\eta}}\protect\textsuperscript{5}:\protect\emph{\ensuremath{\kappa}}\protect\textsuperscript{1}-C\protect\textsubscript{5}Me\protect\textsubscript{4}SiMe\protect\textsubscript{2}CH\protect\textsubscript{2})\protect\textsubscript{2}U}},
     journal = {Comptes Rendus. Chimie},
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William J. Evans; Nathan A. Siladke; Joseph W. Ziller. Reactivity of the tethered alkyl uranium bonds of (η⁵:κ¹-C₅Me₄SiMe₂CH₂)₂U. Comptes Rendus. Chimie, La vitalité de la chimie de coordination des éléments f, Volume 13 (2010) no. 6-7, pp. 775-780. doi : 10.1016/j.crci.2010.02.003. https://comptes-rendus.academie-sciences.fr/chimie/articles/10.1016/j.crci.2010.02.003/

Version originale du texte intégral

Le texte intégral ci-dessous peut contenir quelques erreurs de conversion par rapport à la version officielle de l'article publié.

1 Introduction

Insertion reactions constitute one of the classic types of organometallic reactions that define the reactivity of metal carbon bonds [1]. The insertion reactivity of the U-C bond has been extensively studied with (C₅Me₅)₂UMe₂ [2] and this has resulted in a wealth of actinide complexes with interesting structural features, coordination environments, and reactivity (e.g. Scheme 1) [3–7].

Scheme 1
Insertion reactivity of (C₅Me₅)₂UMe₂.

Organoactinide insertion chemistry has also been studied with (C₅Me₅)₂U(CCPh)₂ [8]. This complex has been frequently used as an in situ initiator for catalytic processes that involve insertion reactions such as the coupling of nitriles, isocyanides, and terminal alkynes, oligomerization of terminal alkynes, and the hydrosilylation of terminal alkynes [9].

Recently, an analog of (C₅Me₅)₂UMe₂ was synthesized, namely (η⁵:κ¹-C₅Me₄SiMe₂CH₂)₂U, 1, that made it possible to examine U-C bond reactivity of a tethered alkyl [10]. Complex 1 is generated from (C₅Me₄SiMe₃)₂UMe₂ by metalation of each of the (C₅Me₄SiMe₃)¹⁻ ligands, Eq. (1) [10]. The U-C bonds in 1 are in a coordination environment similar tothat of (C₅Me₅)₂UMe₂, but variations in reactivity may be observable since the reactive alkyls are tethered to the ancillary cyclopentadienyl ligand [11]. Preliminary studies with carbon monoxide and tert-butyl isocyanide demonstrated that 1 provides both structural data and reactivity modes that are not accessible from (C₅Me₅)₂UMe₂ [10]. With these promising results, we continued our study of this tethered system and report here on the reactivity of 1 with tert-butyl nitrile, carbon dioxide, phenylacetylene, and diphenylacetylene.

2 Experimental

The syntheses and manipulations described below were conducted under nitrogen or argon with rigorous exclusion of air and water using glovebox, Schlenk, and vacuum-line techniques. All reactions were performed at room temperature unless otherwise noted. Solvents were dried over columns containing Q-5 and 4A molecular sieves. Benzene-d₆ was dried over NaK alloy, degassed using three freeze-pump-thaw cycles, and vacuum transferred before use. Tert-butyl nitrile and PhCCH were dried over 4A molecular sieves and degassed using three freeze-pump-thaw cycles before use. PhCCPh was purchased from Aldrich and used as received. Ultrahigh purity carbon dioxide was purchased from Airgas and used as received. (η⁵:κ¹-C₅Me₄SiMe₂CH₂)₂U, 1, was prepared as previously reported [10]. ¹H NMR spectra were recorded with a Bruker GN 500 MHz spectrometer and ¹³C NMR spectra were recorded with a Bruker CRYO 500 MHz spectrometer. Infrared spectra were recorded as KBr pellets on a Varian 1000 FT-IR spectrometer. Elemental analysis was performed on a Perkin Elmer 2400 Series II CHN analyzer.

[η⁵:κ¹-C₅Me₄SiMe₂CH₂C(^tBu)N]₂U, 2. In a glovebox, a red solution of 1 (230 mg, 0.37 mmol) in toluene (10 mL) was added to a stirred solution of ^tBuCN (61 mg, 0.74 mmol) in toluene (5 mL). After 12 h, solvent was removed under vacuum from the red solution to yield 2 as a dark red microcrystalline solid (280 mg, 97%). X-ray quality crystals of 2 were grown from a concentrated hexane solution at −35 °C. ¹H NMR (C₆D₆): δ −36.3 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 6H), −24.7 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 6H), −6.56 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 6H), −4.95 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 6H), −2.45 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 18H), 7.61 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 6H), 20.3 (s, C₅Me₄SiMe₂CH₂C(^tBu)N, 6H), 32.0 (d, C₅Me₄SiMe₂CH₂C(^tBu)N, 2H, ²J_HH = 11.4 Hz), 32.4 (d, C₅Me₄SiMe₂CH₂C(^tBu)N, 2H, ²J_HH = 11.4 Hz). ¹³C NMR (125.5 MHz, C₆D₆): δ −114 (C₅Me₄SiMe₂CH₂C(^tBu)N), −89.1 (C₅Me₄SiMe₂CH₂C(^tBu)N), −83.8 (C₅Me₄SiMe₂CH₂C(^tBu)N), −79.9 (C₅Me₄SiMe₂CH₂C(^tBu)N), −51.3 (C₅Me₄SiMe₂CH₂C(^tBu)N), −18.9 (C₅Me₄SiMe₂CH₂C(^tBu)N), 18.4 (C₅Me₄SiMe₂CH₂C(^tBu)N), 33.5 (C₅Me₄SiMe₂CH₂C(^tBu)N). IR: 2958 s, 2901s, 1605s, 1457m, 1383m, 1326m, 1247s, 1160m, 1046m, 1020m, 991m, 833s, 666m cm⁻¹. Anal. Calcd for C₃₄H₅₈Si₂N₂U: C, 51.75; H, 7.41; N, 3.55. Found: C, 51.22; H, 7.87; N, 3.08.

(C₅Me₄SiMe₂CH₂CO₂)₂U, 3. A red solution of 1 (320 mg, 0.51 mmol) in benzene (25 mL) in a 100 mL Schlenk flask was attached to a high vacuum line and degassed by three freeze-pump-thaw cycles. One atmosphere of CO₂ was introduced to the reaction flask, the solution was stirred for 15 min, and the solution became yellow-brown. The reaction was degassed by one freeze-pump-thaw cycle, brought into a glovebox, and the solvent was removed under vacuum to yield 3 as a gold powder (350 mg, 96%). ¹H NMR (C₆D₆): δ −10.0 (s, C₅Me₄SiMe₂CH₂CO₂, 6H), −5.72 (s, C₅Me₄SiMe₂CH₂CO₂, 6H), −5.58 (s, C₅Me₄SiMe₂CH₂CO₂, 2H), −3.46 (s, C₅Me₄SiMe₂CH₂CO₂, 6H), −3.10 (s, C₅Me₄SiMe₂CH₂CO₂, 6H), 0.63 (s, C₅Me₄SiMe₂CH₂CO₂, 6H), 14.7 (s, C₅Me₄SiMe₂CH₂CO₂, 2H), 15.6 (s, C₅Me₄SiMe₂CH₂CO₂, 6H). ¹³C NMR (125.5 MHz, C₆D₆): δ −40.5 (C₅Me₄SiMe₂CH₂CO₂), −13.8 (C₅Me₄SiMe₂CH₂CO₂), −1.69 (C₅Me₄SiMe₂CH₂CO₂), −0.616 (C₅Me₄SiMe₂CH₂CO₂), 3.30 (C₅Me₄SiMe₂CH₂CO₂), 16.5 (C₅Me₄SiMe₂CH₂CO₂), 60.9 (C₅Me₄SiMe₂CH₂CO₂). IR: 2955m, 2914m, 1562s, 1492s, 1443m, 1329m, 1284m, 1046m, 966m, 729w, 834m cm⁻¹. Anal. Calcd for C₂₆H₄₀Si₂O₄U: C, 43.93; H, 5.67. Found: C, 44.20; H, 5.61.

(C₅Me₄SiMe₃)₂U(CCPh)₂, 4. A solution of 1 (240 mg, 0.39 mmol) in toluene (10 mL) was added to a stirred solution of PhCCH (79 mg, 0.77 mmol) in toluene (5 mL). After 12 h, the solvent was removed from the red solution under vacuum to yield 4 as a red powder (303 mg, 95%). X-ray quality crystals of 4 were grown from a concentrated hexane solution at −35 °C. ¹H NMR (C₆D₆): δ −11.1 (d, CCPh, 4H, ³J_HH = 11.4 Hz), −4.96 (s, C₅Me₄SiMe₃, 12H), −2.52 (s, C₅Me₄SiMe₃, 18H), −1.72 (t, CCPh, 4H, ³J_HH = 11.4 Hz), 3.79 (t, CCPh, 2H, ³J_HH = 11.4 Hz), 17.2 (s, C₅Me₄SiMe₃, 12H). ¹³C NMR (125.5 MHz, C₆D₆): δ −41.2 (C₅Me₄SiMe₃), 4.09 (C₅Me₄SiMe₃), 4.53 (C₅Me₄SiMe₃), 51.2 (CCPh), 99.1 (CCPh), 127 (CCPh). IR: 3077w, 2962s, 2950s, 2902s, 2730w, 2055s, 1977w, 1875w, 1800w, 1594m, 1570w, 1485m, 1441m, 1381w, 1347w, 1327m, 1242s, 1198m, 1125m, 1070w, 1024m, 988w, 912w, 846s, 781m, 755s, 690m, 633m, 571w, 533m cm⁻¹. Anal. Calcd for C₄₀H₅₂Si₂U: C, 58.09; H, 6.34. Found for three separate samples of crystalline material: C, 55.36–56.63; H, 5.83–6.09. The C:H ratio of each sample; 9.2:1, 9.5:1, and 9.3:1 are consistent with that calculated of 9.2:1. Evidently, incomplete combustion occurs with this sample. Similar problems have been observed in the past [12].

Reaction of 1 and PhCCPh. A solution of 1 (52 mg, 0.08 mmol) in toluene (5 mL) was added to a stirred solution of PhCCPh (29 mg, 0.17 mmol) in toluene (3 mL). After 12 h, the solvent was removed from the red solution under vacuum. No reaction was observed as determined by the ¹H NMR spectrum of the isolated solid as only resonances for 1 and PhCCPh were observed.

3 Results and discussion

Reactivity of 1 with ^tBuCN. The insertion of nitriles into U-C bonds to form uranium ketimides is well-known from studies with the amide metallacycle [(Me₃Si)₂N]₂U(CH₂SiMe₂NSiMe₃) [13] and with (C₅Me₅)₂UR₂ metallocenes [6,14]. Actinide ketimides have also been postulated as intermediates in hydroamination reactions with alkynes [9a]. With such a well-established body of work on nitrile insertion into terminal U-C bonds for comparison, it was of interest to investigate the reactivity of 1 with nitriles.

Insertion into both of the tethered U-C bonds of 1 occurs with ^tBuCN to produce [η⁵:κ¹-C₅Me₄SiMe₂CH₂C(^tBu)N]₂U, 2, as a dark red microcrystalline solid in 97% yield, Eq. (2). Complex 2 has been characterized by NMR and IR spectroscopy, elemental analysis, and

X-ray crystallography (Fig. 1). Complex 2 has two tethered ketimide ligands as a result of a 1,2-insertion of ^tBuCN into both the tethered alkyl bonds of 1. In contrast, the isocyanide ^tBuNC inserts by a 1,1-insertion into both U-C bonds of 1, as shown in Eq. (3) [10]. Complex 2 isthe first example of an actinide metallocene complex containing tethered ketimide ligands.

Fig. 1
Thermal ellipsoid plot of [η⁵:κ¹-C₅Me₄SiMe₂CH₂C(^tBu)N]₂U, 2, drawn at the 50% probability level. Hydrogen atoms have been omitted for clarity.

The ¹H NMR spectrum of 2 contains nine resonances consistent with insertion of one equiv of ^tBuCN into each of the U-C bonds of 1. The resonances can be assigned to the four unique methyl groups on each cyclopentadienyl ring, two unique methyl groups on each silicon atom, two non-equivalent protons on the methylene groups, and one resonance for the two equivalent tert-butyl groups. Unlike the ¹H NMR spectrum of 1, which lacks any resonance assignable to the (C₅Me₄SiMe₂CH₂)²⁻ methylene groups bound to the paramagnetic uranium [10], the appearance of resonances for the methylene groups in 2 is consistent with an insertion that moves the methylene groups further from the paramagnetic metal.

The IR spectrum of 2 contained an absorption at 1605 cm⁻¹ attributable to a CN bond stretch that is lower than that of free ^tBuCN at 2231 cm⁻¹ [15]. This CN absorbance is similar to the 1620 cm⁻¹ absorption observed for the uranium metallacycle [(Me₃Si)₂N]₂U[NC(Me)CH₂SiMe₂NSiMe₃] [13,16], formed from an insertion reaction similar to that shown in Eq. (2).

The metallocene structure of 2 is not unusual, but the uranium ketimide linkages were affected by the tethering. Selected bond distances and angles for 2 are given in Table 2. The 2.473 and 2.482 Å U-(ring centroid) bond distances and the 139.7° (ring centroid)-U-(ring centroid) bond angle are typical of U⁴⁺ metallocene complexes with the (C₅Me₄SiMe₃)¹⁻ ligand [10]. The 1.264(3) Å N1-C13 and 1.268(3) Å N2-C30 bond distances of the tethered ketimide ligand are similar to those of untethered ketimide ligands [6,14] and are consistent with the IR data that suggested a CN bond. The short U1-N1 and U1-N2 bond distances, both of which are 2.173(2) Å, are also similar to these in other uranium-ketimide complexes [6,14]. In general, U-N ketimide bond distances are typically shorter than those of U-N amide bonds and this has been attributed to π-bonding between uranium and the nitrogen of the ketimide ligand [6,14]. This π-bonding interaction has also been used to explain the near linear U-N-C bond angles present in untethered ketimide ligands [6]. In contrast, the 152.64(2) and 152.47(2)° U-N-C bond angles in 2 deviate significantly from linearity due to the restraints imposed by the tethering. It has previously been shown that short metal-ligand bond distances and linear M-A-B angles are not necessarily correlated [17].

Reactivity of 1 with CO₂. Since spectroscopic data on the reaction of (C₅Me₅)₂UMe₂ with CO₂ to form (C₅Me₅)₂U(O₂CMe)₂ has been reported [7], it was expected that 1 would also react with this substrate. The reaction of 1 with CO₂ (1 atm) formed a complex consistent with the tethered bis(tethered carboxylate), (C₅Me₄SiMe₂CH₂CO₂)₂U, 3, Eq. (4).

Complex 3 was characterized by NMR and IR spectroscopy and by elemental analysis, but like (C₅Me₅)₂U(O₂CMe)₂ [7], single crystals were not obtained. The spectroscopic data are consistent with CO₂ insertion into both U-C bonds of 1 as observed with ^tBuCN and ^tBuNC. The ¹H NMR spectrum of 3 is similar to that of 2 in that resonances assignable to the (C₅Me₄SiMe₂CH₂)²⁻ methylene protons are present. This again indicates that the methylene groups have been moved away from the metal by an insertion reaction. The IR spectrum is also consistent with the insertion of CO₂ into the U-C bonds of 1 since an absorption assignable to a carboxylate C-O stretch is present at 1562 cm⁻¹, which is similar to the 1540 cm⁻¹ C-O stretch reported for (C₅Me₅)₂U(O₂CMe)₂ [7].

Reactivity of 1 with PhCCH. The reaction of 1 with PhCCH was examined to determine whether insertion is possible or if cleavage of the tethered U-C bond would occur to form an alkynide. Straub and co-workers have found that terminal alkynes can display both types of reactivity with uranium metallocenes [9]. The reaction of 1 with two equiv of PhCCH produced (C₅Me₄SiMe₃)₂U(CCPh)₂, 4, as a red powder in 94% yield, Eq. (5). Complex 4 was characterizedby NMR and IR spectroscopy, elemental analysis and X-ray crystallography (Fig. 2).

Fig. 2
Thermal ellipsoid plot of (C₅Me₄SiMe₃)₂U(CCPh)₂, 4, drawn at the 50% probability level. Hydrogen atoms have been omitted for clarity.

The cleavage of the tethered U-C bond by PhCCH was evident from the ¹H NMR spectrum, which resembled that of (C₅Me₄SiMe₃)₂UCl₂ [10] rather than the more complicated spectra of 1–3. The IR spectrum of 4 contained a strong absorbance at 2055 cm⁻¹, attributable to the CC bond, which is similar to those previously reported for uranium alkynides such as 2056 cm⁻¹ in (C₅Me₅)₂U(CCPh)₂ [8b] and 2062 cm⁻¹ in (C₅Me₅)₂U(NPh₂)(CCPh) [18].

X-ray crystallography revealed that the structure of 4 is similar to those of (C₅Me₄SiMe₃)₂UCl₂ and (C₅Me₄SiMe₃)₂UMe₂ in terms of the 2.448 and 2.451 Å U1-(ring centroid) bond distances as well as the 143.8° (ring centroid)-U1-(ring centroid) bond angle [10]. As observed in these other complexes, the trimethylsilyl group of 4 is bent away from the metal and therefore does not distort the metallocene structure [10]. The 2.390(2) Å U1-C25 and 2.369(3) Å U1-C33 bond lengths are shorter than the 2.425(2) Å U-C(Me) bond distance of (C₅Me₄SiMe₃)₂UMe₂ [10], but similar to the U-C bond lengths of 2.398(5) Å in (C₅Me₅)₂U(CCPh)₂ [8].

The reaction of 1 with PhCCPh was also investigated to assess the possibility of alkyne insertion into the tethered U-C bonds without the option for sigma bond metathesis of the U-C bonds as occurs with PhCCH. However, no reaction was observed with PhCCPh.

4 Conclusion

Complex 1 provides a platform to study the insertion reactivity of uranium-alkyl bonds in a tethered system. Tert-butyl nitrile undergoes a 1,2-insertion into both tethered U-C bonds of 1 to produce a bis(tethered ketimide), 2, that differs from untethered uranium ketimides in that the U-N-C bond angles are not linear. CO₂ also inserts into both U-C bonds to produce a bis(tethered carboxylate). PhCCH does not undergo insertion, but provides a convenient route to cleave the tethered U-C bonds of 1 to form an untethered product with an easily identifiable infrared label.

5 Crystallographic data

CCDC 759467 (2) and CCDC 759466 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif.

Acknowledgements

We thank the Chemical Sciences, Geosciences, and Biosciences Division of the Office of Basic Energy Sciences of the Department of Energy for support and Michael K. Takase for assistance with the X-ray crystallography.

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Trevor W. Hayton Hydride, Alkyl, Aryl, Acetylide, Carbonyl, and Cyanide Complexes of the Actinides, Comprehensive Organometallic Chemistry IV (2022), p. 58 | DOI:10.1016/b978-0-12-820206-7.00024-x
Nathalie H. Co; Ashton R. Davis; Chong Deng; Varit Chantranuwathana; Eva R. Himel Rubin; Merzia Subhan; Wenliang Huang; Paula L. Diaconescu Amide and Ketimide Metal Complexes, Comprehensive Coordination Chemistry III (2021), p. 178 | DOI:10.1016/b978-0-08-102688-5.00117-3
Pablo Waldschmidt; Christopher J. Hoerger; Judith Riedhammer; Frank W. Heinemann; Christina T. Hauser; Karsten Meyer CO2 Activation with Formation of Uranium Carbonate Complexes in a Closed Synthetic Cycle, Organometallics, Volume 39 (2020) no. 9, p. 1602 | DOI:10.1021/acs.organomet.9b00786
Yanxiao Liu; Ruozhuang Liu; Wanjian Ding; Dongqi Wang Evaluation of Influencing Factors in Tetravalent Uranium Complex-Mediated CO2 Functionalization by Density Functional Theory, The Journal of Physical Chemistry A, Volume 124 (2020) no. 13, p. 2683 | DOI:10.1021/acs.jpca.0c00724
Olaf Walter Actinide Organometallic Complexes with π‐Ligands, Chemistry – A European Journal, Volume 25 (2019) no. 12, p. 2927 | DOI:10.1002/chem.201803413
Alexander J. Ayres; Ashley J. Wooles; Markus Zegke; Floriana Tuna; Stephen T. Liddle Preparation of Heterobimetallic Ketimido-Actinide-Molybdenum Complexes, Inorganic Chemistry, Volume 58 (2019) no. 19, p. 13077 | DOI:10.1021/acs.inorgchem.9b01993
Kimberly C. Mullane; Peter Hrobárik; Thibault Cheisson; Brian C. Manor; Patrick J. Carroll; Eric J. Schelter 13C NMR Shifts as an Indicator of U–C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study, Inorganic Chemistry, Volume 58 (2019) no. 7, p. 4152 | DOI:10.1021/acs.inorgchem.8b03175
Rami J. Batrice; Isabell S.R. Karmel; Guy Yardeni; Moris S. Eisen Actinide Elements in Catalysis, Encyclopedia of Inorganic and Bioinorganic Chemistry (2018), p. 1 | DOI:10.1002/9781119951438.eibc2564
Markéta Suvova; Kieran T. P. O’Brien; Joy H. Farnaby; Jason B. Love; Nikolas Kaltsoyannis; Polly L. Arnold Thorium(IV) and Uranium(IV) trans-Calix[2]benzene[2]pyrrolide Alkyl and Alkynyl Complexes: Synthesis, Reactivity, and Electronic Structure, Organometallics, Volume 36 (2017) no. 23, p. 4669 | DOI:10.1021/acs.organomet.7b00633
Haolin Yin; Patrick J. Carroll; Eric J. Schelter Cerium(III) and Uranium(IV) Complexes of the 2-Fluorophenyl Trimethylsilyl Amide Ligand: C–F → Ln/An Interactions that Modulate the Coordination Spheres of f-Block Elements, Inorganic Chemistry, Volume 55 (2016) no. 11, p. 5684 | DOI:10.1021/acs.inorgchem.6b00785
Matthew R. MacDonald; Ryan R. Langeslay; Joseph W. Ziller; William J. Evans Synthesis, Structure, and Reactivity of the Ethyl Yttrium Metallocene, (C5Me5)2Y(CH2CH3), Including Activation of Methane, Journal of the American Chemical Society, Volume 137 (2015) no. 46, p. 14716 | DOI:10.1021/jacs.5b08597
Jessica A. Higgins Frey; F. Geoffrey N. Cloke; S. Mark Roe Synthesis and Reactivity of a Mixed-Sandwich Uranium(IV) Primary Amido Complex, Organometallics, Volume 34 (2015) no. 11, p. 2102 | DOI:10.1021/om501190x
Erli Lu; William Lewis; Alexander J. Blake; Stephen T. Liddle The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide–Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex, Angewandte Chemie, Volume 126 (2014) no. 35, p. 9510 | DOI:10.1002/ange.201404898
Erli Lu; William Lewis; Alexander J. Blake; Stephen T. Liddle The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide–Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex, Angewandte Chemie International Edition, Volume 53 (2014) no. 35, p. 9356 | DOI:10.1002/anie.201404898
Henry S. La Pierre; Karsten Meyer Activation of Small Molecules by Molecular Uranium Complexes, Progress in Inorganic Chemistry Volume 58 (2014), p. 303 | DOI:10.1002/9781118792797.ch05
R. J. Batrice; I.-S. R. Karmel; M. S. Eisen 2.13 Product Class 13: Organometallic Complexes of the Actinides, Knowledge Updates 2012/4 (2013) | DOI:10.1055/b-0035-128264
Jessica A. Higgins; F. Geoffrey N. Cloke; S. Mark Roe Synthesis and CO2 Insertion Chemistry of Uranium(IV) Mixed-Sandwich Alkyl and Hydride Complexes, Organometallics, Volume 32 (2013) no. 19, p. 5244 | DOI:10.1021/om400720m
Nathan A. Siladke; Christopher L. Webster; Justin R. Walensky; Michael K. Takase; Joseph W. Ziller; Daniel J. Grant; Laura Gagliardi; William J. Evans Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex, Organometallics, Volume 32 (2013) no. 21, p. 6522 | DOI:10.1021/om4008482
Elsa Mora; Leonor Maria; Biplab Biswas; Clément Camp; Isabel C. Santos; Jacques Pécaut; Adelaide Cruz; José M. Carretas; Joaquim Marçalo; Marinella Mazzanti Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives, Organometallics, Volume 32 (2013) no. 5, p. 1409 | DOI:10.1021/om3010806
Michel Ephritikhine Recent Advances in Organoactinide Chemistry As Exemplified by Cyclopentadienyl Compounds, Organometallics, Volume 32 (2013) no. 9, p. 2464 | DOI:10.1021/om400145p
Nathan A. Siladke; Jennifer LeDuc; Joseph W. Ziller; William J. Evans Synthesis and Insertion Chemistry of Mixed Tether Uranium Metallocene Complexes, Chemistry – A European Journal, Volume 18 (2012) no. 46, p. 14820 | DOI:10.1002/chem.201201908
Frank T. Edelmann Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2010, Coordination Chemistry Reviews, Volume 256 (2012) no. 23-24, p. 2641 | DOI:10.1016/j.ccr.2012.07.027
Oanh P. Lam; Karsten Meyer Uranium-mediated carbon dioxide activation and functionalization, Polyhedron, Volume 32 (2012) no. 1, p. 1 | DOI:10.1016/j.poly.2011.07.015
S. A. Cotton The actinides, Annual Reports Section "A" (Inorganic Chemistry), Volume 107 (2011), p. 264 | DOI:10.1039/c1ic90009a
Polly L. Arnold Uranium-mediated activation of small molecules, Chemical Communications, Volume 47 (2011) no. 32, p. 9005 | DOI:10.1039/c1cc10834d
Nathan A. Siladke; Joseph W. Ziller; William J. Evans Insertion, Isomerization, and Cascade Reactivity of the Tethered Silylalkyl Uranium Metallocene (η5-C5Me4SiMe2CH2-κC)2U, Journal of the American Chemical Society, Volume 133 (2011) no. 10, p. 3507 | DOI:10.1021/ja109491k
Olivier Bénaud; Jean-Claude Berthet; Pierre Thuéry; Michel Ephritikhine The Bis Metallacyclic Anion [U(NSiMe32)(CH2SiMe2NSiMe3)2]−, Inorganic Chemistry, Volume 49 (2010) no. 17, p. 8117 | DOI:10.1021/ic1012044

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