Comptes Rendus

Sommaire du Fascicule no. 1

GECOM-CONCOORD

Editorial
Éditorial
Préface à ce numéro thématique
Pigment identification by spectroscopic means: an arts/science interface
Détermination de la composition énantiomérique dˈesters dˈacides aminés par spectroscopie de RMN à lˈaide dˈune chiroporphyrine de cobalt(III) comme agent chiral de déplacement chimique
Chiroporphyrines froncées à distorsion adjustable
The reduction of molecular oxygen by iron porphyrins
Atom transfer radical polymerisation of styrene controlled by phosphine-containing coordination compounds of Mo(III)/Mo(IV)
Pyridine bis(imine) cobalt or iron complexes for ethylene and 1-hexene (co)polymerisation
New synthetic route to methylaluminoxane for ethylene polymerisation in the presence of zirconocene
Dédoublement et détermination des excès énantiomériques des complexes de ruthéniumII hexacoordinés 〚Ru(bpy)2ppy〛+ et 〚Ru(bpy)2Quo〛+ (bpy = bipyridine, ppy = phénylpyridine, Quo = 8-quinolate) utilisés comme templates dans la construction de réseaux anioniques tridimensionnels
Hydrothermal synthesis of TiO2 anatase nanocrystals using hexaprismatic-shaped oxo-carboxylate complexes
Improved syntheses of the electronically unsaturated heterobimetallic complexes 〚(η-C5Me5)Ni··· ¯M(CO)3(η-C5H5)〛 (M = Mo, W), and their use as cluster building blocks: X-ray structure of the chiral trimetallic cluster 〚FeNiMo(μ3-CO)(μ2-CO)(CO)5(η-C5H5)(η-C5Me5)〛

Sommaire du Fascicule no. 2

Gecom-Concoord 2001. Albe, France. 2e partie

Neodymium and uranium borohydride complexes, precursors to cationic derivatives: comparison of 4f and 5f element complexes
[Complexes borohydrures du néodyme et de l'uranium, précurseurs de dérivés cationiques : comparaison de complexes des éléments 4f et 5f.]
Complexes triflates de l’uranium
Classical and non-classical iron hydrides: synthesis, NMR characterisation, theoretical investigation and X-ray crystal structure of the iron(IV) dihydride 〚Cp*Fe(dppe)(H)2〛+BF4–
Bio-inspired iron catalysts for degradation of aromatic pollutants and alkane hydroxylation
An unexpected insertion of acetone into the silicon–carbon terminus of an sp carbon chain: syntheses and structures of model monoplatinum hexatriynyl and octatetraynyl complexes
Influence de l’énergie interne sur la réactivité de l’ion Fe(CO)2+ avec le diméthyléther, étudiée dans un spectromètre de masse FT–ICR
On the mechanism of the zirconium-catalysed addition of ethyl Grignard reagents to imines
[Mécanisme de l’addition des éthylmagnésiens aux imines sous catalyse au zirconium.]
Synthesis and crystal structure of 〚PdMe{PPh2NHC(O)Me}{O=C(NH2)Me}〛〚BF4〛, a palladium complex containing the acetamide ligand
[Synthèse et structure cristallographique de 〚PdMe{PPh2NHC(O)Me}{O=C(NH2)Me}〛〚BF4〛, un complexe du palladium comportant le ligand acétamide.]
Preparation of new (η6-arene)Mn(CO)3+ complexes involving Pd-catalysed/exo-hydride abstraction sequence

Sommaire du Fascicule no. 3

Lead-free relaxor ferroelectrics with ‘TTB’ structure
Caractérisation des couches minces de Cd1–xZnxS préparées par dépôt chimique
The location of the double bonds in substituted conjugated alkadienes by using the ethanethiol and gas chromatography/mass spectrometry
[Localisation des doubles liaisons conjuguées dans des alcadiènes substitués par couplage CG/SM après dérivation par l’éthanethiol.]
Antimicrobial activity of calixarenes
Conditions de la condensation de Knoevenagel–Cope pour la synthèse de cétones α,β-éthyléniques
L’acide déhydracétique, précurseur de nouvelles pyridopyrimidines, thiazolopyrimidines et pyridones
HOMMAGE À FERNAND GALLAIS
Erratum
Erratum

Sommaire du Fascicule no. 4

Éditorial
account / revue
Metal oxo complexes as catalysts for the isomerisation of allylic alcohols
Transition metal-based homopolymerisation of macromonomers
[Procédés de synthèse de polymacromonomères en présence de métaux de transition.]
Bond-stretch isomerism: a case study of a quiet controversy
A 1,1’-ferrocenylene-bridged analogue of BIPNOR
Synthesis and X-ray crystal structure of 〚VCl3((–)-sparteine)〛 and 〚FeCl2((–)-sparteine)〛
[Synthèse et structure moléculaire de 〚VCl3((–)-spartéine)〛 et de 〚FeCl2((–)-spartéine)〛.]
Differentiation of planar chiral enantiomers of 〚Cp*M(2-alkyl-Phenoxo)〛 〚BF4〛 {M = Rh, Ir} by the trisphat anion
Unusual efficiency of a non-heme iron complex as catalyst for the hydroxylation of aromatic compounds by hydrogen peroxide: comparison with iron porphyrins
Syntheses, interconversions and reactivity of heteropalladacycles made from aryl isocyanates and various phenanthroline Pd(II) precursors with small molecules
Effect of chloride ions on allylic diphosphine palladium (II) complexes: NMR characteristics and chemical reactivity
[Effet des ions chlorure sur des complexes diphosphines allyliques du palladium : caractéristiques RMN et réactivité chimique.]
Synthesis and stereochemical study of a trioxaquine prepared from cis-bicyclo〚3.3.0〛octane-3,7-dione
‘A rendezvous with an old flame’: revisiting olefin hydrogenation with new rhodium and iridium catalysts
New phosphorus-containing dendrimers with ferrocenyl units in each layer
Application of electron-transfer chain catalysis: preparation of bridged 〚{(η5-C5H5)Fe(CO)2}2(μ-diphosphine)2+〛 complexes without chelated 〚(η5-C5H5)Fe(CO)(η2-diphosphine)+〛 byproducts
Is the isonicotinoyl radical generated during activation of isoniazid by MnIII-pyrophosphate?
[Le radical isonicotinoyle, intermédiaire réactif formé lors de l’activation de l’isoniazide par le pyrophosphate de manganèse(III) ?]
Vectorial properties of small vesicles
Synthesis, characterisation and properties of a crescent-shaped tetranuclear bis-dirhodium complex
Multiply chiral phosphite/phosphonite ligands: tuning enantioselectivity by choice of diastereomers

Sommaire du Fascicule no. 5

Numero hommage a John A. Osborn/2e partie

Direct observation and study of the successive elemental steps of catalytic ring-opening metathesis polymerisation (ROMP) reactions: a retrospective review of a fruitful collaboration with John Osborn
Réduction électrochimique de porphyrines portant un groupement électroactif pyridinium
Synthesis of large chelate rings with diphosphites built on a cyclodextrin scaffold. Unexpected formation of 1,2-phenylene-capped α-cyclodextrins
Synthesis and structure of dimeric Rh-bis(tertiary phosphine) complexes, exceptionally useful synthetic precursors
Enantioselective imine hydrogenation with Ir diphosphine catalysts: fighting deactivation
The solid-state isomerization of cis- and trans-(η5-C5H4Me)Mo(CO)2(P(OiPr)3)I
Iron(III) 2,3-dihydroxyterephthalamides revisited. Charge effects on highly stable ferric complexes
Molecular structures and mixed spin states of chloroiron(III) complexes of the 2,3-diethyl-(detpp), 2,3,7,8-tetraethyl-(cis-tetpp), 2,3,12,13-tetraethyl-(trans-tetpp) and 2,3,7,8,12,13-hexaethyl-(hetpp) 5,10,15,20-tetraphenylporphyrin complexes
Perfluorooctyl substituted triphenylphosphites as ligands for hydroformylation of higher olefins in fluorocarbon/hydrocarbon biphasic medium
How well do we understand self-assembly algorithms? From prototype grid to polymers
Synthesis and characterisation of bite angle-dependent (η1-allyl)Rh and (η3-allyl)Rh complexes bearing diphosphine ligands. Implications for nucleophilic substitution reactions
Design and synthesis of multiple-loop receptors based on a calix〚4〛arene scaffold for protein surface recognition
Hydride complexes of ruthenium derived from the heterolytic activation of dihydrogen by amidophosphine complexes
[Complexes d’hydrures de ruthénium dérivés de l’activation hétérolytique du dihydrogène par des complexes amidophosphines.]
Oxidative DNA damage from sulfite autoxidation catalyzed by manganese(III)
Pseudo-tetrahedral semi-sandwich cycloruthenated compounds: 1H NMR data and DFT-calculations about the racemisation process of the ruthenium atom
The unusual inhibition of a dirhodium tetraphosphine-based bimetallic hydroformylation catalyst by PPh3
Molecular tectonics: design and structural analysis of 1-D and 2-D self-inclusion molecular networks in the crystalline state
Presence or absence of a nonlinear effect according to the asymmetric catalyst preparation in the alkylation of benzaldehyde

Sommaire du Fascicule no. 6-7

Caractérisation des propriétés électriques des parois de pores d’une membrane
Le recyclage des mélanges de polymères thermoplastiques. Aspects thermodynamiques, chimiques et applications industrielles
Identification des allotropes S6 et S7 du soufre dans le trophosome du vestimentifère Riftia pachyptila
Synthèse de nouvelles 7 (5)-〚benzimidazol-2-yl〛méthyl-2 (7)-méthyl-1,2,4-triazolo〚1,5-a〛(〚4,3-a〛)pyrimidines
Synthèse et analyse radiocristallographique de la solution solide K2PdCl4–xBrx (0 < x < 4)
Metallation of tetratolylporphyrin by Cu2+ catalysed by LiClO4
Algorithme de dénombrement des graphes chiraux et achiraux d’un cycloalcane monocyclique hétérosubstitué de formule brute CnHm1Xm2Ym3
Effets chimiques et magnétovolumiques compétitifs dans les nitrures d’insertion
Analyse physico-chimique du système quaternaire Na+,Mn2+/Cl–,(H2PO2)–//H2O
Synthèse de nouveaux dérivés du 1-hydroxyindole et du pyrazole

Sommaire du Fascicule no. 8-9

Un nouveau composé d’intercalation du graphite : une phase lamellaire graphite–lithium–calcium
Dispersion dans l’environnement routier et urbain de Pt, Pd, et Rh émis par les pots d’échappement catalytiques. Étude de la spéciation des éléments
Reductive alkylation of anhydrides and lactones: direct access to monosubstituted lactones
Total synthesis of asymmetric flavonoids: the development and applications of 13C-labelling
[Synthèse totale de flavonoïdes asymétriques : développements et applications du marquage au carbone 13.]
Étude par chromatographie en phase gazeuse de nouveaux composés cristaux liquides nématiques à chaîne latérale
Synthesis of some new thorium phosphates
Glass formation study within the TeO2–TlF and Tl2Te3O7–TlF systems
Synthesis of new 3-substituted-2H-1,2-naphthothiazin-4(3H)-one 1,1-dioxides via directed ortho-metalation reaction
[Synthèse de nouveaux 1,1-dioxydes de 2H-1,2-naphtothiazin-4(3H)-one 3-substitués via la réaction de métallation ortho-dirigée.]

Sommaire du Fascicule no. 10

Synthesis and selective transformation of nitrogen-containing compounds via radical pathways
Supramolecular networks based on octacyanometallates of Mo and W
Synthesis of further biological compounds in interstellar-like conditions
[Synthèse de nouveaux composés biologiques dans des conditions quasi interstellaires.]
Étude de la réactivité des radicaux α-ester : influence des centres stéréogènes en position α’ et β’
Synthesis of iron oxide-based magnetic nanomaterials and composites
Structural diversity of cyanide-bridged bimetallic clusters based on hexacyanometallate building blocks

Sommaire du Fascicule no. 11

Avant-propos
Vapour-phase deposition of multicomponent fluoride glasses
UV-absorption and radiation effects in different glasses doped with iron and tin in the ppm range
A survey of transition-metal-containing phosphate glasses
Optical properties and redox state of silicate glass melts
Nanoscale phase separation effects near 𝑟 ¯=2.4 and 2.67, and rigidity transitions in chalcogenide glasses
Spectral migration of excitation energy among Nd3+ ions in fluoroarsenate glasses
Alkali and alkali–lead oxynitride phosphate glasses: a comparative structural study by NMR and XPS
1.3-μm-emission properties and local structure of Dy3+ in chalcohalide glasses
Structure and properties of glasses in the system Li2O–SnO–B2O3
Tin ions in float glass cause anomalies
Crystal growth and classical nucleation theory
Glass sintering with concurrent crystallization
Novel structural behaviour of iron in alkali–alkaline-earth–silica glasses
Solvent properties of glass melts: resemblance to aqueous solutions
Photoinduced fluidity in chalcogenide glasses

Sommaire du Fascicule no. 12

Avant-propos
Rare-earth-doped glasses for fiber amplifiers in broadband telecommunication
Network entropy and connectivity: the underlying factors determining compositional trends in the glass-transition temperature
Structure–property relationships in multicomponent oxide glasses
Rare-earth-doped transparent glass ceramics
From gel to glass
Clustering of rare earths in GeAs sulfide glass
Applications of chalcogenide glass optical fibers
Frequency upconversion in rare-earth doped fluoroindate glasses
Preparation of zinc sodium polyphosphates glasses from coacervates precursors. Characterisation of the obtained glasses, and their applications
Infrared glass fibers for in-situ sensing, chemical and biochemical reactions
Scandium fluorophosphate glasses: a structural approach
Compositional effects and spectroscopy of rare earths (Er3+, Tm3+, and Nd3+) in tellurite glasses
L’importance des phénomènes d’oxydo-réduction dans le verre