Comptes Rendus

Issue no. 1 Table of Contents

GECOM-CONCOORD

Editorial
p. 1
Éditorial
[Editorial]
p. 3
Préface à ce numéro thématique
[Foreword to this thematic issue]
p. 5
Pigment identification by spectroscopic means: an arts/science interface
p. 7-20
Détermination de la composition énantiomérique dˈesters dˈacides aminés par spectroscopie de RMN à lˈaide dˈune chiroporphyrine de cobalt(III) comme agent chiral de déplacement chimique
[Determination of enantiomer composition of amino acid esters by 1H NMR spectroscopy using a chiral cobalt(III) porphyrin shift reagent.]
p. 21-25
Chiroporphyrines froncées à distorsion adjustable
[Ruffled chiroporphyrins with adjustable bridles.]
p. 27-31
The reduction of molecular oxygen by iron porphyrins
p. 33-36
Atom transfer radical polymerisation of styrene controlled by phosphine-containing coordination compounds of Mo(III)/Mo(IV)
p. 37-42
Pyridine bis(imine) cobalt or iron complexes for ethylene and 1-hexene (co)polymerisation
p. 43-48
New synthetic route to methylaluminoxane for ethylene polymerisation in the presence of zirconocene
p. 49-52
Dédoublement et détermination des excès énantiomériques des complexes de ruthéniumII hexacoordinés 〚Ru(bpy)2ppy〛+ et 〚Ru(bpy)2Quo〛+ (bpy = bipyridine, ppy = phénylpyridine, Quo = 8-quinolate) utilisés comme templates dans la construction de réseaux anioniques tridimensionnels
[Resolution and determination of the enantiomeric excesses of hexacoordinated complexes of RuII: 〚Ru(bpy)2ppy〛+ and 〚Ru(bpy)2Quo〛+ (bpy = bipyridine, ppy = phenylpyridine, Quo = 8-quinolate) used as cationic templates in the formation of three-dimensional anionic networks.]
p. 53-58
Hydrothermal synthesis of TiO2 anatase nanocrystals using hexaprismatic-shaped oxo-carboxylate complexes
p. 59-66
Improved syntheses of the electronically unsaturated heterobimetallic complexes 〚(η-C5Me5)Ni··· ¯M(CO)3(η-C5H5)〛 (M = Mo, W), and their use as cluster building blocks: X-ray structure of the chiral trimetallic cluster 〚FeNiMo(μ3-CO)(μ2-CO)(CO)5(η-C5H5)(η-C5Me5)〛
p. 67-72

Issue no. 2 Table of Contents

Gecom-Concoord 2001. Albe, France. 2e partie

Neodymium and uranium borohydride complexes, precursors to cationic derivatives: comparison of 4f and 5f element complexes
p. 73-80
Complexes triflates de l’uranium
p. 81-87
Classical and non-classical iron hydrides: synthesis, NMR characterisation, theoretical investigation and X-ray crystal structure of the iron(IV) dihydride 〚Cp*Fe(dppe)(H)2〛+BF4–
p. 89-98
Bio-inspired iron catalysts for degradation of aromatic pollutants and alkane hydroxylation
p. 99-109
An unexpected insertion of acetone into the silicon–carbon terminus of an sp carbon chain: syntheses and structures of model monoplatinum hexatriynyl and octatetraynyl complexes
p. 111-118
Influence de l’énergie interne sur la réactivité de l’ion Fe(CO)2+ avec le diméthyléther, étudiée dans un spectromètre de masse FT–ICR
[Influence of the internal excitation of Fe(CO)2+ on its reactivity with dimethylether, observed in a Fourier Transform–ICR cell.]
p. 119-125
On the mechanism of the zirconium-catalysed addition of ethyl Grignard reagents to imines
p. 127-130
Synthesis and crystal structure of 〚PdMe{PPh2NHC(O)Me}{O=C(NH2)Me}〛〚BF4〛, a palladium complex containing the acetamide ligand
p. 131-135
Preparation of new (η6-arene)Mn(CO)3+ complexes involving Pd-catalysed/exo-hydride abstraction sequence
p. 137-141

Issue no. 3 Table of Contents

Lead-free relaxor ferroelectrics with ‘TTB’ structure
p. 143-148
Caractérisation des couches minces de Cd1–xZnxS préparées par dépôt chimique
[Characterisation of Cd1–xZnxS thin films prepared by chemical bath deposition.]
p. 149-155
The location of the double bonds in substituted conjugated alkadienes by using the ethanethiol and gas chromatography/mass spectrometry
p. 157-162
Antimicrobial activity of calixarenes
p. 163-169
Conditions de la condensation de Knoevenagel–Cope pour la synthèse de cétones α,β-éthyléniques
[Knoevenagel–Cope condensation conditions applied to ketolisation reaction.]
p. 171-175
L’acide déhydracétique, précurseur de nouvelles pyridopyrimidines, thiazolopyrimidines et pyridones
[Dehydroacetic acid precursor of a novel pyridopyrimidine, thiazolo-pyrimidine and pyridone.]
p. 177-183
HOMMAGE À FERNAND GALLAIS
[A TRIBUTE TO FERNAND GALLAIS]
p. 185-208
Erratum
p. 209
Erratum
p. 210-211

Issue no. 4 Table of Contents

Éditorial
[Editorial]
p. 213-216
account / revue
Metal oxo complexes as catalysts for the isomerisation of allylic alcohols
p. 217-224
Transition metal-based homopolymerisation of macromonomers
p. 225-234
Bond-stretch isomerism: a case study of a quiet controversy
p. 235-244
A 1,1’-ferrocenylene-bridged analogue of BIPNOR
p. 245-249
Synthesis and X-ray crystal structure of 〚VCl3((–)-sparteine)〛 and 〚FeCl2((–)-sparteine)〛
p. 251-255
Differentiation of planar chiral enantiomers of 〚Cp*M(2-alkyl-Phenoxo)〛 〚BF4〛 {M = Rh, Ir} by the trisphat anion
p. 257-262
Unusual efficiency of a non-heme iron complex as catalyst for the hydroxylation of aromatic compounds by hydrogen peroxide: comparison with iron porphyrins
p. 263-266
Syntheses, interconversions and reactivity of heteropalladacycles made from aryl isocyanates and various phenanthroline Pd(II) precursors with small molecules
p. 267-287
Effect of chloride ions on allylic diphosphine palladium (II) complexes: NMR characteristics and chemical reactivity
p. 289-296
Synthesis and stereochemical study of a trioxaquine prepared from cis-bicyclo〚3.3.0〛octane-3,7-dione
p. 297-302
‘A rendezvous with an old flame’: revisiting olefin hydrogenation with new rhodium and iridium catalysts
p. 303-308
New phosphorus-containing dendrimers with ferrocenyl units in each layer
p. 309-318
Application of electron-transfer chain catalysis: preparation of bridged 〚{(η5-C5H5)Fe(CO)2}2(μ-diphosphine)2+〛 complexes without chelated 〚(η5-C5H5)Fe(CO)(η2-diphosphine)+〛 byproducts
p. 319-324
Is the isonicotinoyl radical generated during activation of isoniazid by MnIII-pyrophosphate?
p. 325-330
Vectorial properties of small vesicles
p. 331-335
Synthesis, characterisation and properties of a crescent-shaped tetranuclear bis-dirhodium complex
p. 337-340
Multiply chiral phosphite/phosphonite ligands: tuning enantioselectivity by choice of diastereomers
p. 341-344

Issue no. 5 Table of Contents

Numero hommage a John A. Osborn/2e partie

Direct observation and study of the successive elemental steps of catalytic ring-opening metathesis polymerisation (ROMP) reactions: a retrospective review of a fruitful collaboration with John Osborn
p. 345-351
Réduction électrochimique de porphyrines portant un groupement électroactif pyridinium
[Electrochemical reduction of porphyrins bearing an electroactive pyridinium group.]
p. 353-358
Synthesis of large chelate rings with diphosphites built on a cyclodextrin scaffold. Unexpected formation of 1,2-phenylene-capped α-cyclodextrins
p. 359-372
Synthesis and structure of dimeric Rh-bis(tertiary phosphine) complexes, exceptionally useful synthetic precursors
p. 373-378
Enantioselective imine hydrogenation with Ir diphosphine catalysts: fighting deactivation
p. 379-385
The solid-state isomerization of cis- and trans-(η5-C5H4Me)Mo(CO)2(P(OiPr)3)I
p. 387-394
Iron(III) 2,3-dihydroxyterephthalamides revisited. Charge effects on highly stable ferric complexes
p. 395-404
Molecular structures and mixed spin states of chloroiron(III) complexes of the 2,3-diethyl-(detpp), 2,3,7,8-tetraethyl-(cis-tetpp), 2,3,12,13-tetraethyl-(trans-tetpp) and 2,3,7,8,12,13-hexaethyl-(hetpp) 5,10,15,20-tetraphenylporphyrin complexes
p. 405-416
Perfluorooctyl substituted triphenylphosphites as ligands for hydroformylation of higher olefins in fluorocarbon/hydrocarbon biphasic medium
p. 417-424
How well do we understand self-assembly algorithms? From prototype grid to polymers
p. 425-430
Synthesis and characterisation of bite angle-dependent (η1-allyl)Rh and (η3-allyl)Rh complexes bearing diphosphine ligands. Implications for nucleophilic substitution reactions
p. 431-440
Design and synthesis of multiple-loop receptors based on a calix〚4〛arene scaffold for protein surface recognition
p. 441-450
Hydride complexes of ruthenium derived from the heterolytic activation of dihydrogen by amidophosphine complexes
p. 451-460
Oxidative DNA damage from sulfite autoxidation catalyzed by manganese(III)
p. 461-466
Pseudo-tetrahedral semi-sandwich cycloruthenated compounds: 1H NMR data and DFT-calculations about the racemisation process of the ruthenium atom
p. 467-472
The unusual inhibition of a dirhodium tetraphosphine-based bimetallic hydroformylation catalyst by PPh3
p. 473-480
Molecular tectonics: design and structural analysis of 1-D and 2-D self-inclusion molecular networks in the crystalline state
p. 481-486
Presence or absence of a nonlinear effect according to the asymmetric catalyst preparation in the alkylation of benzaldehyde
p. 487-491

Issue no. 6-7 Table of Contents

Caractérisation des propriétés électriques des parois de pores d’une membrane
[Characterisation of electrical properties of membrane pore walls.]
p. 493-505
Le recyclage des mélanges de polymères thermoplastiques. Aspects thermodynamiques, chimiques et applications industrielles
[Recycling of polymer wastes as blends. Thermodynamic, chemical aspects, applications at the industrial scale.]
p. 507-512
Identification des allotropes S6 et S7 du soufre dans le trophosome du vestimentifère Riftia pachyptila
[Identification of S6 and S7 sulphur allotropes in trophosome of Riftia pachyptila (Vestimentifera) from Hydrothermal vents.]
p. 513-516
Synthèse de nouvelles 7 (5)-〚benzimidazol-2-yl〛méthyl-2 (7)-méthyl-1,2,4-triazolo〚1,5-a〛(〚4,3-a〛)pyrimidines
[Synthesis of new 7 (5)-〚benzimidazol-2-yl〛methyl-5 (7)-methyl-1,2,4-triazolo〚1,5-a〛(〚4,3-a〛)pyrimidines.]
p. 517-523
Synthèse et analyse radiocristallographique de la solution solide K2PdCl4–xBrx (0 < x < 4)
[Synthesis and crystallographic analysis of the K2PdCl4–xBrx (0 < x < 4) solid solution.]
p. 525-528
Metallation of tetratolylporphyrin by Cu2+ catalysed by LiClO4
p. 529-532
Algorithme de dénombrement des graphes chiraux et achiraux d’un cycloalcane monocyclique hétérosubstitué de formule brute CnHm1Xm2Ym3
p. 533-538
Effets chimiques et magnétovolumiques compétitifs dans les nitrures d’insertion
[Competitive chemical and magnetovolume effects in insertion nitrides.]
p. 539-546
Analyse physico-chimique du système quaternaire Na+,Mn2+/Cl–,(H2PO2)–//H2O
[Physicochemical analysis of the system Na+,Mn2+/Cl–,(H2PO2)–//H2O.]
p. 547-549
Synthèse de nouveaux dérivés du 1-hydroxyindole et du pyrazole
[Synthesis of new derivatives of 1-hydroxyindole and pyrazole.]
p. 551-557

Issue no. 8-9 Table of Contents

Un nouveau composé d’intercalation du graphite : une phase lamellaire graphite–lithium–calcium
[A new graphite intercalation compound: a graphite–lithium–calcium lamellar phase.]
p. 559-564
Dispersion dans l’environnement routier et urbain de Pt, Pd, et Rh émis par les pots d’échappement catalytiques. Étude de la spéciation des éléments
[Dispersion of Pt, Pd and Rh produced by catalytic converters into the roadside and urban environment. Element speciation study.]
p. 565-570
Reductive alkylation of anhydrides and lactones: direct access to monosubstituted lactones
p. 571-575
Total synthesis of asymmetric flavonoids: the development and applications of 13C-labelling
p. 577-590
Étude par chromatographie en phase gazeuse de nouveaux composés cristaux liquides nématiques à chaîne latérale
[Study of nomadic new liquid crystals with lateral chain by gas chromatography.]
p. 591-598
Synthesis of some new thorium phosphates
p. 599-606
Glass formation study within the TeO2–TlF and Tl2Te3O7–TlF systems
p. 607-610
Synthesis of new 3-substituted-2H-1,2-naphthothiazin-4(3H)-one 1,1-dioxides via directed ortho-metalation reaction
p. 611-621

Issue no. 10 Table of Contents

Synthesis and selective transformation of nitrogen-containing compounds via radical pathways
p. 623-638
Supramolecular networks based on octacyanometallates of Mo and W
p. 639-649
Synthesis of further biological compounds in interstellar-like conditions
p. 651-653
Étude de la réactivité des radicaux α-ester : influence des centres stéréogènes en position α’ et β’
[Reactivity study of α-ester radicals: influence of the chiral centres in α’ and β’ positions.]
p. 655-658
Synthesis of iron oxide-based magnetic nanomaterials and composites
p. 659-664
Structural diversity of cyanide-bridged bimetallic clusters based on hexacyanometallate building blocks
p. 665-672

Issue no. 11 Table of Contents

Avant-propos
[Foreword]
p. 673
Vapour-phase deposition of multicomponent fluoride glasses
p. 675-678
UV-absorption and radiation effects in different glasses doped with iron and tin in the ppm range
p. 679-692
A survey of transition-metal-containing phosphate glasses
p. 693-703
Optical properties and redox state of silicate glass melts
p. 705-712
Nanoscale phase separation effects near 𝑟 ¯=2.4 and 2.67, and rigidity transitions in chalcogenide glasses
p. 713-724
Spectral migration of excitation energy among Nd3+ ions in fluoroarsenate glasses
p. 725-729
Alkali and alkali–lead oxynitride phosphate glasses: a comparative structural study by NMR and XPS
p. 731-738
1.3-μm-emission properties and local structure of Dy3+ in chalcohalide glasses
p. 739-749
Structure and properties of glasses in the system Li2O–SnO–B2O3
p. 751-757
Tin ions in float glass cause anomalies
p. 759-763
Crystal growth and classical nucleation theory
p. 765-771
Glass sintering with concurrent crystallization
p. 773-786
Novel structural behaviour of iron in alkali–alkaline-earth–silica glasses
p. 787-796
Solvent properties of glass melts: resemblance to aqueous solutions
p. 797-804
Photoinduced fluidity in chalcogenide glasses
p. 805-811

Issue no. 12 Table of Contents

Avant-propos
[Foreword]
p. 813
Rare-earth-doped glasses for fiber amplifiers in broadband telecommunication
p. 815-824
Network entropy and connectivity: the underlying factors determining compositional trends in the glass-transition temperature
p. 825-830
Structure–property relationships in multicomponent oxide glasses
p. 831-843
Rare-earth-doped transparent glass ceramics
p. 845-854
From gel to glass
p. 855-863
Clustering of rare earths in GeAs sulfide glass
p. 865-872
Applications of chalcogenide glass optical fibers
p. 873-883
Frequency upconversion in rare-earth doped fluoroindate glasses
p. 885-898
Preparation of zinc sodium polyphosphates glasses from coacervates precursors. Characterisation of the obtained glasses, and their applications
p. 899-906
Infrared glass fibers for in-situ sensing, chemical and biochemical reactions
p. 907-913
Scandium fluorophosphate glasses: a structural approach
p. 915-920
Compositional effects and spectroscopy of rare earths (Er3+, Tm3+, and Nd3+) in tellurite glasses
p. 921-938
L’importance des phénomènes d’oxydo-réduction dans le verre
[Importance of oxidoreduction phenomena in glass.]
p. 939-949