Comptes Rendus

Issue no. 1 Table of Contents

The first organized GLEN meeting (GlycoLipid European Network)

Guest editor: Arnaud Haudrechy; Eric Hénon

Editorial Board
p. CO2
The first organized GLEN meeting (GlycoLipid European Network)
p. 1-2
Expression of GD3 synthase modifies ganglioside profile and increases migration of MCF-7 breast cancer cells
p. 3-14
Account/Revue
From elastin peptides to neuraminidase-1-dependent lactosylceramide generation
p. 15-17
Account/Revue
New perspectives for microbial glycolipid fractionation and purification processes
p. 18-28
Account/Revue
Glycoside nucleoside lipids (GNLs): An intrusion into the glycolipids’ world?
p. 29-36
The mammalian sulfated glycolipid sulfatide: Synthesis and biological implications
p. 37-45
C-galactosylceramide: Synthesis and immunology
p. 46-56
Account/Revue
Synthetic efforts towards the synthesis of fluorinated C-glycosidic analogues of α-galactosylceramides
p. 57-67
d-xylose-based bolaamphiphiles: Synthesis and influence of the spacer nature on their interfacial and membrane properties
p. 68-74
Activity of trioxaquine PA1259 in mice infected by Schistosoma mansoni
p. 75-78
A thienoquinoxaline and a styryl-quinoxaline as new fluorescent probes for amyloid-β fibrils
p. 79-85
Structural properties of the trimetallic acetylide complex [{Ru(CO)2(η5C5H5)}3(η1:η1:η2:-CC)]+
p. 86-90
PEG-SO3H: A mild and efficient recyclable catalyst for the synthesis of coumarin derivatives
p. 91-95
Hydrothermal alkylation of phenols with alcohols in diluted acids
p. 96-101
Editorial Board
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Issue no. 2-3 Table of Contents

Polyoxometalates, metal wires and other “polymetallic” complexes: structure, properties, theoretical modelling

Guest editor: Marc Bénard

Editorial Board - French
p. CO2
Polyoxometalates, metal wires and other “polymetallic” complexes: Structure, properties, theoretical modelling. A tribute to Marie-Madeleine Rohmer
p. 103-106
Do Keggin anions repulse each other in solution? The effect of solvent, counterions and ion representation investigated by free energy (PMF) simulations
p. 107-117
Counterion effects on the 183W NMR spectra of the lacunary Keggin polyoxotungstate [PW11O39]7–. Relativistic DFT calculations
p. 118-123
{Mo2O2S2}2+-directed synthesis of a polyoxotungstoarsenate(III). Structure and 183W NMR studies of the [(α–AsW9O33)3(WO(OH2))3(Mo2O2S2(H2O)4)]13− anion
p. 124-129
Trimeric, cyclic Ti10-containing 27-tungsto-3-germanate [(α-Ti3GeW9O37OH)3(TiO3(OH2)3)]17−
p. 130-134
Connecting ruthenium substituted Keggin-type tungstophosphates by oxotungstic bridges: Evidence for the steric effect of {RuL3}2+ (L3 = η6-arene, (DMSO)3) fragments
p. 135-142
Theoretical study of the four isomers of [Siw11o39]8−: Structure, stability and physical properties
p. 143-151
Electronic structure of IPR and non-IPR endohedral metallofullerenes: Connecting orbital and topological rules
p. 152-158
Further studies of [Ni4(DAniDANy)4] (DAniDANy2− = N,N’-bis-p-anisyl-2,7-diamido-1,8-naphthyridine) and its one-electron oxidation product: Metal-metal sigma bonding in Ni49+ complex
p. 159-162
Simple versus composite nature of the magnetic coupling in copper and nickel-based metallic chains. Over- and underestimation of J
p. 163-169
Ferromagnetic coupling induced by spin-orbit coupling in dipyridylamide linear trinuclear Cu-Pd-Cu and Cu-Pt-Cu complexes
p. 170-175
Electron transport through molecular wires based on a face-shared bioctahedral motif
p. 176-183
Magnetic exchange coupling in imido bimetallic uranium(V) complexes. A relativistic DFT study
p. 184-191
Jahn-Teller distortion, ferromagnetic coupling, and electron delocalization in a high-spin Fe–Fe bonded dimer
p. 192-201
First principles investigation of the atomic structure and magnetic properties of copper hydroxide acetate
p. 202-208
Account/Revue
Unconstrained magnetism in nanostructures at zero temperature: An ultimate goal
p. 209-213
Models for the trinuclear copper(II) cluster in the particulate methane monooxygenase from methanotrophic bacteria: Synthesis, spectroscopic and theoretical characterization of trinuclear copper(II) complexes
p. 214-224
Large electron correlation effect leading to Be─Be bond
p. 225-228
Intramolecular d10–d10 interactions in neutral, dinuclear Au(I) complexes supported by amino-thiazoline- and -thiazole-based P,N-phosphine ligands
p. 229-236
Charge density studies on [(NO)Fe(S2C6H4)2][PPN] and [(NO)3Fe(S2C6H4)3] complexes
p. 237-249
Electronic fine structure calculation of [Gd(DOTA)(H2O)]– using LF-DFT: The zero field splitting
p. 250-254
Structures and spectral properties of heteroleptic copper (I) complexes: A theoretical study based on density functional theory
p. 255-266
Editorial Board - English
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Issue no. 4 Table of Contents

Editorial Board
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A catalyst free convenient one-pot synthesis of multisubstituted chromeno-thiazolones
p. 267-272
One-pot three-component reaction: Synthesis of substituted β-cyanocarbonyls in aqueous media
p. 273-277
Catalytic stereoselective Mannich reaction under solvent-free conditions
p. 278-282
Zirconium oxide (NP) - ionic liquid as an efficient media for the domino Knoevenagel hetero Diels-Alder reaction with unactivated alkynes
p. 283-289
Calix[4]arene-modified silica nanoparticles for the potentiometric detection of iron (III) in aqueous solution
p. 290-297
Synthesis, characterization, magnetic, thermal and electrochemical studies of oxidovanadium (IV) picolyl hydrazones as functional catechol oxidase models
p. 298-310
Photocyclisation of 3-alkoxy-6-chloro-2-(3-methylthiophen-2-yl)-4H-chromen-4-ones
p. 311-316
Characterization and catalytic properties of nickel-substituted hexagonal mesoporous silica prepared by microwave-hydrothermal method
p. 317-323
A novel method for the synthesis of tetrahydrobenzo[a]-xanthen-11-one derivatives using cerium(III) chloride as a highly efficient catalyst
p. 324-330
Eco-friendly elastomeric composites containing Sencha and Gun Powder green tea extracts
p. 331-335
Solution studies of tris(2-benzylaminoethyl)amine complexes of zinc(II) and copper(II): The catalytic hydrolysis of toxic organophosphate
p. 336-345
Microwave-assisted efficient synthesis of azlactone derivatives using TsCl/DMF under solvent-free conditions
p. 346-349
Three structural modifications in the series of layered solids T(H2O)2[Ni(CN)4]·xH2O with T = Mn, Co, Ni: Their nature and crystal structures
p. 350-355
Palladium(II) complex taken as a model of an antitumour agent: Synthesis and equilibrium investigation involving biologically relevant ligands
p. 356-364
Eco-friendly and efficient multi-component method for preparation of 1-amidoalkyl-2-naphthols under solvent-free conditions by dodecylphosphonic acid (DPA)
p. 365-369
Editorial Board
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Issue no. 5 Table of Contents

Editorial Board
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A theoretical study on the inclusion complexation of doxycycline with Crysmeb
p. 371-377
Catalyst-free sonochemical synthesis of 1,8-dioxo-octahydroxanthene derivatives in carboxy functionalized ionic liquid
p. 378-383
Efficient BOP-mediated synthesis of fulgimides
p. 384-388
Polyvinylpolypyrrolidone-bound boron trifluoride: A highly efficient catalyst for acylation of alcohols, phenols and trimethylsilyl ethers by acetic anhydride
p. 389-393
Phenylboronic acid as an efficient and convenient catalyst for a three-component synthesis of tetrahydrobenzo[b]pyrans
p. 394-397
Simultaneous removal of copper(II), lead(II), zinc(II) and cadmium(II) from aqueous solutions by multi-walled carbon nanotubes
p. 398-408
A facile and efficient ultrasound-assisted stereospecific synthesis of novel bicyclo-cyclopropanes
p. 409-413
Mineral oxides and layered minerals in combination with itaconic acid as coagents for peroxide crosslinking of hydrogenated acrylonitrile-butadiene elastomer
p. 414-423
Antioxidant activity determination in Sencha and Gun Powder green tea extracts with the application of voltammetry and UV-VIS spectrophotometry
p. 424-427
Highly selective oxidation of alcohols using MnO2/TiO2-ZrO2 as a novel heterogeneous catalyst
p. 428-436
Étude de l’activité catalytique des argiles pontées aluminium, zirconium et cérium dans la synthèse du 2,2-diméthyl-1,3-dioxolane
[Study of the catalytic activity of aluminum, zirconium and cerium pillared clays in the synthesis of 2,2-dimethyl-1,3-dioxolane]
p. 437-443
An appropriate one-pot synthesis of dihydropyrimidinones catalyzed by heteropoly acid supported on zeolite: An efficient and reusable catalyst for the Biginelli reaction
p. 444-447
l-Proline-catalysed one-pot synthesis of tetrahydrobenzo[c]acridin-8(7H)-ones at room temperature
p. 448-453
Synthesis, spectroscopic characterization and photophysical study of dicyanomethylene-substituted squaraine dyes
p. 454-462
Synthesis of new substituted benzaldazine derivatives, hydrogen bonding-induced supramolecular structures and luminescent properties
p. 463-470
Editorial Board
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Issue no. 6 Table of Contents

Editorial Board
p. CO2
Synthesis of α–amino nitriles through Strecker-type reaction using SO3H -functionalized ionic liquid as a homogeneous and water tolerant-acidic catalyst
p. 471-473
Determination of the heat effects involved during toluene vapor adsorption and desorption from microporous activated carbon
p. 474-481
Le phosphate naturel modifié au vanadium : un nouveau catalyseur pour l’oxydation des cycloalcanones et des α-cétols en présence de l’oxygène moléculaire
[Natural phosphate modified by vanadium: A new catalyst for oxidation of cycloalkanones and α-ketols with oxygen molecular]
p. 482-492
Étude mécanistique et structurale des résines R/F
[Mechanistic and structural study of R/F resins]
p. 493-498
Stereoselective synthesis of 3,4-dihydro-7-nitrocoumarins via isocyanide-based multicomponent reaction
p. 499-503
Ionic liquid catalyzed synthesis of 7-phenyl-1,4,6,7-tetrahydro-thiazolo[5,4-d]pyrimidine-2,5-diones
p. 504-510
Room-temperature sulfidation of copper nanoparticles with sulfur yielding covellite nanoparticles
p. 511-516
H3PW12O40/MCM-41 nanoparticles as efficient and reusable solid acid catalyst for the synthesis of quinoxalines
p. 517-523
Characterisation of the antioxidant acitivity of riboflavin in an elastomeric composite
p. 524-529
Polyvinylpolypyrrolidone-bound boron trifluoride (PVPP-BF3); a mild and efficient catalyst for synthesis of 4-metyl coumarins via the Pechmann reaction
p. 530-532
Synthesis and spectroscopic characterization of Ag-Cu alloy nanoparticles prepared in various ratios
p. 533-538
Synthesis of colloidal silver nanoparticles for printed electronics
p. 539-544
Editorial Board
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Issue no. 7 Table of Contents

Histoire de la Chimie / The History of Chemistry

Guest editor: Yves Jeannin

Editorial Board
p. CO2
Histoire de la Chimie
[The History of Chemistry]
p. 545
Le système périodique en perspective historique
[The periodic system in historical perspective]
p. 546-552
Les origines de la chimie organique au-delà du mythe fondateur
[The origins of organic chemistry beyond the founding myth]
p. 553-568
La chimie parisienne entre artisanat et industrie (1760–1830)
[Parisian chemistry between crafts and industry (1760–1830)]
p. 569-579
Some new documents illuminating the controversy about the vestium-ruthenium discovery
p. 580-584
De Réaumur à la Première Guerre Mondiale : les étapes de la maîtrise de l’acier, l’essor des aciers spéciaux
[From the time of Réaumur to World War One: Successive stages in the mastery of steel-making, emergence of special steels]
p. 585-594
Limit values and the boundaries of science and technology
p. 595-602
Crystal structure and ionic conductivity of AgCr2(PO4)(P2O7)
p. 603-608
Étude par spectrométrie Mössbauer de la polarisation de spin et de l’environnement local des cations d’étain introduits comme dopants dans le volume et à la surface des cristallites de GdCrO3
[Mössbauer spectroscopy investigation of the spin polarization and the local surroundings of tin dopant cations in the bulk and on the surface of GdCrO3 microcrystals]
p. 609-616
Synthesis and voltammetric study of some new macrocyclic sulfur compounds for use as chelating agents for separation of arsenic (III) in wastewater and as molluscicidal agents against Biomophalaria Alexandrina Snails
p. 617-626
Covalent hydration of nitrobenzofuroxans compounds: Kinetic and theoretical study using reactivity–selectivity descriptor
p. 627-632
Synthesis of silver tin oxide nanocomposite powders via chemical coprecipitation method
p. 633-638
A family of dodecanuclear Mn11Ln single-molecule magnets
p. 639-646
Editorial Board
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Issue no. 8 Table of Contents

Editorial Board
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One-pot synthesis of 2-alkyl-7-amino-5-aryl-pyrazolo[1,5-a]pyrimidine-6-carbonitriles via a domino three-component condensation-oxidation reaction
p. 647-652
An unexpected transformation by reduction of isoxazolines
p. 653-657
Préparation, caractérisation et réactivité de l’acide 1-vanado-11-molybdo-phosphorique supporté sur des matériaux silicatés mésoporeux dans l’oxydation du propène
[Preparation, characterization and reactivity of 1-vanado-11-molybdo-phosphoric acid supported on mesoporous silicate materials in the propene oxidation]
p. 658-668
Synthesis, characterization and microbiocidal studies of novel ionic liquid tagged Schiff bases
p. 669-674
Microwave-assisted green synthesis of dibenzo[a,j]xanthenes using p-dodecylbenzenesulfonic acid as an efficient Bronsted acid catalyst under solvent-free conditions
p. 675-678
Pronounced catalytic activity of oxo-vanadium(IV) Schiff base complexes in the oxidation of cyclooctene and styrene by tert-butyl hydroperoxide
p. 679-687
Catalyst-free Vicinal bromoazidation of olefins using TMSN3 and NBS
p. 688-692
Data selection and estimation of the normal melting temperature of ionic liquids using a method based on homologous cations
p. 693-699
New structures of hydronium cation clusters
p. 700-707
Synthesis and characterization of glycyrrhizin-decorated graphene oxide for hepatocyte-targeted delivery
p. 708-713
A simplistic one-pot method to produce magnetic graphene-CdS nanocomposites
p. 714-718
Preparation of various xanthene derivatives over sulfonic acid functionalized imidazolium salts (SAFIS) as novel, highly efficient and reusable catalysts
p. 719-736
Account/Revue
The story of clopidogrel and its predecessor, ticlopidine: Could these major antiplatelet and antithrombotic drugs be discovered and developed today?
p. 737-743
Editorial Board
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Issue no. 9 Table of Contents

Editorial Board
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A practical and highly efficient protocol for multicomponent synthesis of β-phosphonomalononitriles and 2-amino-4H-chromen-4-yl phosphonates using diethylamine as a novel organocatalyst
p. 745-752
Crystal structure of [2]benzopyrano[3,4-b]quinoxalin-5-one through spontaneous air oxidation rearrangement of 6-Chloro-isoindolo[2,1-a]quinoxaline
p. 753-757
Efficient and suitable preparation of N-sulfonyl-1,2,3,4-tetrahydroisoquinolines and ring analogues using recyclable H6P2W18O62·24H2O/SiO2 catalyst
p. 758-763
Sustainable approach to tandem catalysis: Expedient access to quinoxalines and pyrido[2,3-b]pyrazines from α-hydroxyketones via microwave-induced [(NH4)6Mo7O24·4H2O – PEG 300] polar paste catalyst system
p. 764-767
Deep eutectic solvent promoted highly efficient synthesis of N, N’-diarylamidines and formamides
p. 768-773
Réactivité de l’acide déhydroacétique hydrogené en c5-c6 : obtention des pyrano-1,5-benzodiazépines différemment substituées et de la structure enaminone
[Reactivity of the dehydroacetic acid hydrogenated at c5-c6: Synthesis of the substituted pyrano-1,5-benzodiazepines and the enaminone structure]
p. 774-778
Three-component one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-one derivatives in 2,2,2-trifluoroethanol
p. 779-783
Facile synthesis of trisubstituted imidazoles from 1,2-di(furan-2-yl)-2-oxoethyl carboxylates and their chemiluminescence
p. 784-792
Esterification of acetic acid with n-Butanol using vanadium oxides supported on γ-alumina
p. 793-798
Synthesis, characterization and catalytic activity studies on cordierite honeycomb coated with ZrO2 based solid super acids
p. 799-807
A theoretical investigation on the densities and detonation properties of polynitrotetraazabenzimidazoles
p. 808-814
Account/Revue
The molybdenum and rhenium octahedral cluster chalcohalides in solid state chemistry: From condensed to discrete cluster units
p. 815-836
Editorial Board
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Issue no. 10 Table of Contents

Inorganic molecular materials

Guest editor: Marius Andruh

Editorial Board
p. CO2
Inorganic molecular materials
p. 837
Tetrathiafulvalene-based lanthanide coordination complexes: Synthesis, crystal structure, optical and electrochemical characterization
p. 838-844
Dithiolene complexes as metalloligands: [Cu(en)2][Cu(mnt)2], an S = ½ spin chain
p. 845-848
Magnetic ordering of NiII4 Cubane complexes through hydrogen bonds
p. 849-855
Synthesis, crystal structure and magnetic properties of the helical oxalate-bridged copper(II) chain {[(CH3)4N]2[Cu(C2O4)2] · H2O}n
p. 856-865
Influence of sterically non-hindering methyl groups on adsorption properties of two classical zinc and copper MOF types
p. 866-877
CoIILnIII dinuclear complexes (LnIII = Gd, Tb, Dy, Ho and Er) as platforms for 1,5-dicyanamide-bridged tetranuclear CoII2LnIII2 complexes: A magneto-structural and theoretical study
p. 878-888
Hexanuclear manganese(III) single-molecule magnets from derivatized salicylamidoximes
p. 889-894
Coinage metal complexes with N’NN’ and SeNSe ligands – Pincer vs bridging coordination pattern
p. 895-903
Bimetallic neutral palladium (II) bis(dithiolene) complex: Unusual synthesis, structural and theoretical study
p. 904-910
Synthesis, structural analysis, and thermal and spectroscopic studies of methylmalonate-containing zinc(II) complexes
p. 911-923
K2Re(NCS)6: A weak ferromagnet
p. 924-928
Slow magnetic relaxation in mononuclear tetrahedral cobalt(II) complexes with 2-(1H-imidazol-2-yl)phenol based ligands
p. 929-936
Chiral single-molecule magnet with a 35 K energy barrier for relaxation of the magnetization
p. 937-942
Editorial Board
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Issue no. 11-12 Table of Contents

Editorial Board
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Phosphine-free polystyrene-supported palladium(II) complex as an efficient catalyst for the Heck and Suzuki coupling reactions in water
p. 945-949
TTF[Ni(dmit)2]2: Now as nanoparticles
p. 950-954
Synthesis of 4,4′-(arylmethylene)bis(3-methyl-1H-pyrazol-5-ol) derivatives in water
p. 955-961
A novel catalyst for alkylation of benzene
p. 962-968
Fe3O4 nanoparticles: As an efficient, green and magnetically reusable catalyst for the one-pot synthesis of 1,8-dioxo-decahydroacridine derivatives under solvent-free conditions
p. 969-974
[PZnMo2W9O39]5− immobilized on ionic liquid-modified silica as a heterogeneous catalyst for epoxidation of olefins with hydrogen peroxide
p. 975-979
Synthesis of N-formylated β-lactams using nano-sulfated TiO2 as catalyst under solvent-free conditions
p. 980-987
Pd-poly(N-vinyl-2-pyrrolidone)/KIT-6 nanocomposite: Preparation, structural study, and catalytic activity
p. 988-995
ROMP of norbornene catalyzed by polyoxometalates
p. 996-1000
Substituent effects on the voltammetric studies of 2-oxo-1,2,3,4-tetrahydropyrimidines
p. 1001-1011
Synthesis of gold nanoparticles by microemulsion assisted photoreduction method
p. 1012-1021
Inclusion complex of N-nitroso, N-(2-chloroethyl), N′, N′-dibenzylsulfamid with β-Cyclodextrin: Fluorescence and molecular modeling
p. 1022-1036
Synthèse enzymatique d’esters de fructose
[Enzymatic synthesis of fructose esters]
p. 1037-1047
Polystyrene-supported GaCl3: A new, highly efficient and recyclable heterogeneous Lewis acid catalyst for acetylation and benzoylation of alcohols and phenols
p. 1048-1054
Nano copper(II) oxide catalyzed four-component synthesis of functionalized benzo[a]pyrano[2,3-c]phenazine derivatives
p. 1055-1059
Four-component synthesis of 2H-indazolo[2,1-b]phthalazine-1,6,11(13H)-trione derivatives
p. 1060-1064
Synthesis and characterization of novel polythiourethane hardeners for epoxy resins
p. 1065-1071
A rapid, convenient and chemoselective synthesis of acylals from aldehydes catalyzed by reusable nano-ordered MCM-41-SO3H
p. 1072-1076
A facile and efficient [bmim]N3 catalyzed direct oxidative esterification of arylaldehydes with alcohols
p. 1077-1080
Account/Revue
On the selectivity in some Rh(III) catalyzed CH activation cross-couplings
p. 1081-1085
Editorial Board
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