Comptes Rendus

Sommaire du Fascicule no. 1-2

Editorial Board - french
p. CO2
Advanced nanomaterials: A domain where chemistry, physics and biology meet
[Nanomatériaux avancés : un domaine où la chimie, la physique et la biologie se rencontrent]
p. 1-2
Account/Revue
“Chimie douce”: A land of opportunities for the designed construction of functional inorganic and hybrid organic-inorganic nanomaterials
p. 3-39
Account / Revue
Design of metal oxide nanoparticles: Control of size, shape, crystalline structure and functionalization by aqueous chemistry
p. 40-51
Bacteria encapsulation in colloidal inorganic matrices: Is it a general method?
p. 52-57
Solid-state nuclear magnetic resonance: A valuable tool to explore organic-inorganic interfaces in silica-based hybrid materials
p. 58-68
Full spectroscopic characterization of an hydrolytically stable and colored Ti(IV)-precursor in solution
p. 69-96
Functional coatings: The sol-gel approach
p. 97-105
Novel low temperature approaches for the eco-efficient synthesis of electrode materials for secondary Li-ion batteries
p. 106-116
Detection and use of small J couplings in solid state NMR experiments
p. 117-129
Account/Revue
Vanadium oxide aerogels: Nanostructured materials for enhanced energy storage
p. 130-141
Account/Revue
Vanadium pentoxide gels: From “chimie douce” to “matière molle”
p. 142-153
Integrative chemistry portfolio toward designing and tuning vanadium oxide macroscopic fibers sensing and mechanical properties
p. 154-166
Coal from carbohydrates: The “chimie douce” of carbon
p. 167-173
Account/Revue
Evolution of bioceramics within the field of biomaterials
p. 174-185
Account/Revue
Synthesis and sol–gel assembly of nanophosphors
p. 186-198
Epoxy-functionalized large-pore SBA-15 and KIT-6 as affinity chromatography supports
p. 199-206
Macro- and microporous carbon monoliths with high surface areas pyrolyzed from poly(divinylbenzene) networks
p. 207-211
Account / Revue
Thin film photochromic materials: Effect of the sol-gel ormosil matrix on the photochromic properties of naphthopyrans
p. 212-226
Silacrown modified xerogels as functional hybrid materials for carbon composite electrodes
p. 227-236
Pattern recognition in oxides thin-film electrodeposition: Printed circuits
p. 237-241
Account/Revue
Use of ionic liquids in sol-gel; ionogels and applications
p. 242-255
Large-pore mesoporous titania-silica thin films (Ti1−xSixO2, 0.1 ≤ x ≤ 0.9) with highly interdispersed mixed oxide frameworks
p. 256-269
Synthesis, functionalization and properties of incompletely condensed “half cube” silsesquioxanes as a potential route to nanoscale Janus particles
p. 270-281
Behaviour of sonogels under isotropic pressure
p. 282-289
Editorial Board - english
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Sommaire du Fascicule no. 3

gecom-concoord 2009 (albé, alsace, france, 24–29 may 2009)

Editorial Board - French
p. CO2
Gecom-Concoord 2009
p. 291
Account/Revue
Cp*RuCl(COD) in catalysis: A unique role in the addition of diazoalkane carbene to alkynes
p. 292-303
Account/Revue
Organometallic catalysis: From concepts to selected applications
p. 304-314
Account/Revue
From chemical topology to molecular machines
p. 315-328
Characterization of tetra, dodeca and tetradeca MoV polyoxometalate wheels structured by etidronate ligands
p. 329-335
Synthesis, structure and solid state NMR analysis of a new templated titanium(III/IV) fluorophosphate
p. 336-342
Cobalt complexes supported by salicylichydrazono derivative ligands and various coordination solvents
p. 343-352
Enantioselective hydrosilylation of prochiral ketones catalyzed by chiral BINAP-copper(I) complexes
p. 353-357
Transformations de N-acylaziridines catalysées par des supports à base de silice et d’alumine : une élucidation mécanistique
p. 358-364
Phosphated ceria, selective catalysts for oxidative dehydrogenation of isobutane
p. 365-371
Poly(vinylalcohol)/poly(ethyleneglycol)/poly(ethyleneimine) blend membranes - structure and CO2 facilitated transport
p. 372-379
Antimicrobial and antioxidant activities of Artemisia herba-alba essential oil cultivated in Tunisian arid zone
p. 380-386
Editorial Board - English
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Sommaire du Fascicule no. 4

Editorial Board - French
p. CO2
GERM 2009
p. 387
Design, fabrication and evaluation of a low-cost homogeneous portable permanent magnet for NMR and MRI
[Conception, fabrication et évaluation d’un aimant permanent portable à bas coût pour la RMN et l’IRM]
p. 388-393
Brownian dynamics of water confined in AOT reverse micelles: A field-cycling deuteron NMR relaxometry study
p. 394-398
Self-diffusion coefficient measurements at high temperature by PFG NMR
p. 399-404
NMR control of aging and durability of hardened cement pastes
p. 405-408
Multiscale dynamics of 1H and 19F in confined ionogels for lithium batteries
p. 409-411
Validation of molecular mass measurements by means of diffusion-ordered NMR spectroscopy: Application to oligosaccharides
p. 412-415
Account / Revue
Study of the residual dipolar coupling by 1H NMR MAS technique. Effect of the grafting ratio on interface polymer grafted on silica
p. 416-422
Account/Revue
Protein 3D structure determination by high-resolution solid-state NMR
p. 423-430
Account/Revue
Perspectives in 1H, 14N and 81Br solid-state NMR studies of interfaces in materials textured by self-assembled amphiphiles
p. 431-442
Interactions between polysaccharides uronic acid sequences and lipid molecules
p. 443-448
NMR of human saliva protein/wine tannin complexes. Towards deciphering astringency with physico-chemical tools
p. 449-452
Use of 1H-NMR metabolomics to precise the function of the third glutamate dehydrogenase gene in Arabidopsis thaliana
p. 453-458
Manganèse et imagerie de résonance magnétique du développement cérébral
p. 459-465
Comparative Baeyer-Villiger oxidation of cyclohexanone on Fe-pillared clays and iron tetrasulfophthalocyanine covalently supported on silica
p. 466-472
Chemical composition and biological potential of seed oil and leaf extracts of Henophyton deserti Coss. & Durieu
p. 473-480
Attachment of trianglamines to silicon wafers, chiral recognition by chemical force microscopy
p. 481-485
Editorial Board - English
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Sommaire du Fascicule no. 5

GECat 2009

Numéro thématique coordonné par : Catherine Batiot ; Vincent Lecocq ; Laurent Piccolo ; Juliette Blanchard

Editorial Board - French
p. CO2
GECat 2009
p. 487
Depollution: A matter of catalyst and reactor design
p. 488-493
Co–Mg–Al oxides issued of hydrotalcite precursors for total oxidation of volatile organic compounds. Identification and toxicological impact of the by-products
p. 494-501
Dégradation photocatalytique des ions ammonium en présence de TiO2 dopé
p. 502-507
Nature du dépôt formé au cours de l’oxydation en voie humide catalysée du phénol
p. 508-514
VOCs and carbonaceous particles removal assisted by NOx on alkali0.15/ZrO2 and Csx–M0.1/ZrO2 catalysts (M = Cu or Co)
p. 515-526
Performances catalytiques de faujasites Y échangées par des cations de Ce3+, La3+, UO22+, Co2+, Sr2+, Pb2+, Tl+ et NH4+ dans la réaction de dismutation du toluène
p. 527-537
Utilisation de matériaux à base d’argiles modifiées dans la conversion du toluène
p. 538-543
Protic ionic liquid [TMG][Ac] as an efficient, homogeneous and recyclable catalyst for Boc protection of amines
p. 544-547
Pyrolysis of asphaltenes and biomarkers for the fingerprinting of the Amoco-Cadiz oil spill after 23 years
p. 548-552
How to drive imine–enamine tautomerism of pyronic derivatives of biological interest – A theoretical and experimental study of substituent and solvent effects
p. 553-560
Colloidal behavior of wine galloylated tannins
p. 561-565
Valorization of by-products of the sugar industry: New nanostructured hybrid materials containing sugar derived structures
p. 566-574
Editorial Board - English
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Sommaire du Fascicule no. 6-7

La vitalité de la chimie de coordination des éléments f

Numéro thématique coordonné par : Michel Ephritikhine

Editorial Board - French
p. CO2
The vitality of the coordination chemistry of the f elements
p. 575-576
New lanthanide(III) disiloxanediolates: Syntheses and structures
p. 577-583
Anionic and neutral bis(diimine)lanthanide complexes
p. 584-592
Reactions of alkali metal and yttrium alkyls with a sterically demanding bis(aryloxysilyl)methane: Formation of aryloxide complexes by Si-O bond cleavage
p. 593-602
Mixed borohydride-chloride complexes of the rare earth elements
p. 603-607
Account/Revue
Discrete allyl complexes of group 3 metals and lanthanides
p. 608-625
Ortho-metalation of pyridines by cationic yttrium methyl complexes
p. 626-632
Account/Revue
Recent advances in reaction of organolanthanides containing the N−H bonds with unsaturated organic small molecules
p. 633-650
Tetramethylcyclopentadienyl-supported rare-earth metal bis(tetramethyl)aluminate complexes: Synthesis, structural chemistry, cation formation, and isoprene polymerization
p. 651-660
CuLn complexes with a single μ-oximato bridge
p. 661-667
Account/Revue
Novel antennae for the sensitization of near infrared luminescent lanthanide cations
p. 668-680
Sensitization of Eu(III) luminescence by donor-phenylethynyl-functionalized DTPA and DO3A macrocycles
p. 681-690
An oxazoline derivatized Pybox ligand for Eu(III) and Tb(III) sensitization
p. 691-699
Account/Revue
Towards highly efficient, intelligent and bimodal imaging probes: Novel approaches provided by lanthanide coordination chemistry
p. 700-714
Lanthanide-based hexanuclear complexes usable as molecular precursors for new hybrid materials
p. 715-730
Lanthanide-doped LiYF4 nanoparticles: Synthesis and multicolor upconversion tuning
p. 731-736
Account/Revue
From extended solids to nano-scale actinide clusters
p. 737-746
Supramolecular chemistry with uranyl tetrahalide ([UO2X4]2−) anions
p. 747-754
Unusual case of a polar copper(II) uranyl phosphonate that fluoresces
p. 755-757
Uranium(VI) bis(imido) disulfonamide and dihalide complexes: Synthesis density functional theory analysis
p. 758-766
Synthesis and structure determination of a stable organometallic uranium(v) imine complex and its isolobal anionic U(IV)-ate complex
p. 767-774
Reactivity of the tethered alkyl uranium bonds of (η5:κ1-C5Me4SiMe2CH2)2U
p. 775-780
Six-coordinate uranium complexes featuring a bidentate anilide ligand
p. 781-789
Synthesis, structure, spectroscopy and redox energetics of a series of uranium(IV) mixed-ligand metallocene complexes
p. 790-802
A new diamantane functionalized tris(aryloxide) ligand system for small molecule activation chemistry at reactive uranium complexes
p. 803-811
Tris(pyrazolyl)borate half-sandwich complexes of trivalent uranium incorporating the [C8H6{SiiPr3-1,4}2]2− and [C8H4{SiiPr3-1,4}2]2− ligands
p. 812-820
Recent developments in nonaqueous plutonium coordination chemistry
p. 821-831
The unusual stability of [NpO2Cl4]2−: Synthesis and characterisation of [NpO2(DPPMO2)2Cl]2[NpO2Cl4] and [Ph3PNH2]2[NpO2Cl4]
p. 832-838
Americium(III) coordination chemistry: An unexplored diversity of structure and bonding
p. 839-848
Curvature of the lanthanide contraction: An explanation
p. 849-852
All-electron CASPT2 study of Ce(η8–C8H6)2
p. 853-859
Electron affinities of biscyclopentadienyl and phospholyl uranium(IV) borohydride complexes: Experimental and DFT studies
p. 860-869
A DFT study of the reactivity of Cp2AnMe2 with pyridine N-oxide: Towards a predicted different reactivity of U/Pu and Np
p. 870-875
Modulation of the unpaired spin localization in Pentavalent Uranyl Complexes
p. 876-883
Chemical properties of the predicted 32-electron systems Pu@Sn12 and Pu@Pb12
p. 884-888
Editorial Board - English
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Sommaire du Fascicule no. 8-9

Editorial Board - French
p. CO2
Un panorama des recherches actuelles en chimie du phosphore – un hommage à la mémoire de Pascal Le Floch
p. 889
New ferrocenyl P,O ligands with polar substituents
p. 890-899
Account/Revue
1,3-phosphorus zwitterions with cyano-group at anion center
p. 900-911
Electronic structure and properties of some oligomers based on fluorinated 1H-phospholes: n- versus p-type materials
p. 912-922
Computational and experimental approaches to the molecular structure of the HCl adduct of Me3PO
p. 923-928
An easy and direct synthetic route to phosphamido niobocenes through nucleophilic attack of phosphide niobocene complexes on acyl halides
p. 929-934
Account/Revue
d6 metal systems for white phosphorus activation
p. 935-942
Platinum complexes with diamino-substituted phosphorus ligands: Synthesis, characterization, and their reactivity with a Lewis acid
p. 943-953
Account/Revue
Phosphasilaallenes >Si = C = P− and phosphagermaallenes >Ge = C = P−
[Phosphasilaallènes >Si=C=P- et phosphagermaallènes >Ge=C=P]
p. 954-963
A practical and efficient green synthesis of β-aminophosphoryl compounds via the aza-Michael reaction in water
p. 964-970
Structure–property relationships of acylated asymmetric dithienophospholes
p. 971-979
A Cu(I) cluster bearing a bridging phosphane ligand
p. 980-984
Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry
p. 985-997
Unsymmetrically substituted N-heterocyclic phosphenium ions
p. 998-1005
Account/Revue
Phosphorus dendrimers as viewed by 31P NMR spectroscopy; synthesis and characterization
[Les dendrimères phosphorés observés par spectroscopie de RMN 31P ; leur synthèse et leur caractérisation]
p. 1006-1027
Advanced approaches in radiation-chemical synthesis of phosphorus-containing polymers
p. 1028-1034
Synthesis, structures, optical and electrochemical properties, and complexation of 2,5-bis(pyrrol-2-yl)phospholes
p. 1035-1047
Phosphinidene generation from phosphorus heterocycles and cages – A theoretical study
p. 1048-1053
Account/Revue
Chiral diphosphines and diphosphinites derived from 2,2-biphosphole: Stereodynamic ligands for asymmetric catalysis
p. 1054-1062
Structural and bonding aspects of molybdenum tricarbonyl complexes of 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3But3 and some λ3,λ3,λ5- and λ3,λ5,λ5-alkylated derivatives
p. 1063-1072
Facile preparation of trimethylsilylphosphaalkyne and its conversion to polyphospholide anions
p. 1073-1081
Thiophene-fused phospholo[3,2-b]phospholes and their dichalcogenides: Synthesis and structure–photophysical properties relationships
p. 1082-1090
Towards the stability limit of cyclic diphosphonium bis-ylides
p. 1091-1098
First study on the enantioselective palladium-catalyzed C-P cross-coupling reaction between an alkenyltriflate and a phosphine-borane
p. 1099-1103
Account/Revue
π-conjugated phosphasilenes stabilized by fused-ring bulky “Rind” groups
p. 1104-1110
Account/Revue
Nitrogen- and oxygen-bridged bidentate phosphaalkene ligands
p. 1111-1126
Account/Revue
Recent developments in the chemistry of donor-functionalized phosphinines
p. 1127-1143
Synthesis and characterisation of the water soluble bis-phosphine complex [Ru(η6-cymene)(PPh2(o-C6H4O)-κ2-P,O)(pta)]+ and an investigation of its cytotoxic effects
p. 1144-1150
Account/Revue
An effective strategy of P,N-containing macrocycle design
p. 1151-1167
Dative P→Sn interactions in ortho-phenylene phosphine-stannanes
p. 1168-1172
Phosphaethyne polymers are analogues of cis-polyacetylene and graphane
p. 1173-1179
Synthesis and physicochemical properties of stable 1,3-diphosphacyclobutane-2,4-diyls bearing sulfanyl groups
p. 1180-1184
[Li(tmeda)2][cyclo-(P5But4)]: An unusual ion-separated lithium oligophosphanide
p. 1185-1190
Account/Revue
Phosphorus based inhibitors of matrix metalloproteinases
p. 1191-1202
Account/Revue
Unprecedented triphosphinine iron interactions: Intramolecular electron transfer, reactivity round a corner, and a low-activated ring element exchange reaction

Présenté par : Dedicated to Professor Rolf Saalfrank on the occasion of his 70th birthday.

Karin Eggers ; Frank W. Heinemann ; Matthias Hennemann ; Timothy Clark ; Paul Binger ; Ulrich Zenneck
p. 1203-1212
Enantiodivergent synthesis of P-chirogenic phosphines
p. 1213-1226
Bis(dithiomethyl-tetrathiafulvalene) with two phenyl-phosphino bridges
p. 1227-1232
N-phosphonio formamidine derivatives: Synthesis, characterization, X-ray crystal structures, and deprotonation reactions
p. 1233-1240
Coordination chemistry of [Cp*Fe(η5-P3C2tBu2)] (Cp* = η5-C5Me5) with copper(I) halides – Formation of oligomeric and polymeric compounds
p. 1241-1248
Account/Revue
Chemistry of pentacoordinated anti-apicophilic phosphorus compounds
p. 1249-1259
Editorial Board - English
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Sommaire du Fascicule no. 10

Editorial Board - French
p. CO2
Expedious synthesis for α, β-unsaturated coumarin derivatives using boran chelates: A novel class of potential antibacterial and antioxidant agents
p. 1261-1268
Synthesis, structure, spectral and coordination properties of a crown ether derivative of 1,3-indandione. A new structural evidence for the versatile reactivity of 2-acetyl-1,3-indandione
p. 1269-1277
Synthesis, antibacterial and antifungal activities of new chiral 5-alkyl-3-(1′-benzenesulfonylpyrrolidin-2′-yl)-4,5-dihydro-1,2,4-oxadiazin-6-ones
p. 1278-1283
Synthesis of non glycosidic nucleobase-sugar mimetics
p. 1284-1300
Polymer-supported titanate as catalyst for the transesterification of acrylic monomers
p. 1301-1307
InCl3-catalyzed efficient synthesis of spiro-perimidine derivatives
p. 1308-1312
Stockage de l’hydrogène dans les nanotubes de carbone à paroi unique : nouvelle méthode de préparation par excitation laser
p. 1313-1318
Toluene steam reforming as tar model molecule produced during biomass gasification with an iron/olivine catalyst
p. 1319-1325
Influence of the extracted solute on the aggregation of malonamide extractant in organic phases: Consequences for phase stability
p. 1326-1334
Liquid chromatography and characterization of ether-functionalized imidazolium ionic liquids on mixed-mode reversed-phase/cation exchange stationary phase
p. 1335-1340
Editorial Board - English
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Sommaire du Fascicule no. 11

Editorial Board - French
p. CO2
Account/Revue
Functions of polymers in composite electrodes of lithium ion batteries
p. 1341-1350
La3TaO7 derivatives with Weberite structure type: Possible electrolytes for solid oxide fuel cells and high temperature electrolysers
p. 1351-1358
Removal of Cu(II) and Zn(II) from industrial wastewater by acid-activated montmorillonite-illite type of clay
p. 1359-1363
Optimization of the synthesis and characterizations of chemical bath deposited Cu2S thin films
p. 1364-1369
Elaboration and characterisation of a plasticized cellulose triacetate membrane containing trioctylphosphine oxyde (TOPO): Application to the transport of uranium and molybdenum ions
p. 1370-1376
Étude structurale de britholite au césium Sr7La2Cs(PO4)5(SiO4)F2
p. 1377-1383
Manganese-promoted Rh supported on a modified SBA-15 molecular sieve for ethanol synthesis from syngas. Effect of manganese loading
p. 1384-1390
Synthesis, characterization, and crystal structure of several novel acidic ionic liquids based on the corresponding 1-alkylbenzimidazole with tetrafluoroboric acid
p. 1391-1396
Antifungal effects of secondary metabolites isolated from marine organisms collected from the Tunisian coast
p. 1397-1400
Quasi-solid-state dye-sensitized solar cell based on a polymer gel electrolyte with in situ synthesized ionic conductors
p. 1401-1405
Synthèse et propriétés photochimiques de modèles imides et amides contenant des structures norbornadiènes pentaméthylés
p. 1406-1415
An excellent arsenic(V) sorption behavior of p-tert-butylcalix[8]areneoctamide impregnated resin
p. 1416-1423
Synthesis and characterization of novel dipeptide mimetics with hydantoin moiety
p. 1424-1428
Editorial Board - English
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Sommaire du Fascicule no. 12

Editorial Board - French
p. CO2
A green protocol for catalyst-free synthesis of 1-oxo-hexahydroxanthenes in aqueous medium
p. 1429-1432
Silica supported nanopalladium prepared by hydrazine reduction
p. 1433-1439
Regiospecific synthesis of 1,2-aminoalcohol by ring-opening of racemic styrene oxide in presence of Lewis acids
p. 1440-1442
Synthesis of piperidinones incorporating an amino acid moiety as potential SP antagonists
p. 1443-1449
2-(7-methyl-1H-benzoimidazol-2-yl)-6-(1-aryliminoethyl)pyridinylnickel complexes: Synthesis, characterization and their ethylene oligomerization
p. 1450-1459
Synthèse et caractérisation de fluorbritholites strontiques dopées au néodyme
p. 1460-1467
H3PW12O40–[bmim][FeCl4]: A novel and green catalyst-medium system for microwave-promoted selective interconversion of alkoxymethyl ethers into their corresponding nitriles, bromides and iodides
p. 1468-1473
Account/Revue
Cycloaddition reactions in aqueous systems: A two-decade trend endeavor
p. 1474-1511
Index des auteurs / Authors index
p. 1514-1518
Index des mots-clés
p. 1519-1522
Keyword index
p. 1523-1530
Editorial Board - English
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